Class 9 Science Chapter 9 Atomic Foundations NCERT Solutions | Boundless Maths
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Class 9 Science Chapter 9:
Atomic Foundations of Matter

NCERT Class 9 Science Chapter 9 question answers for Atomic Foundations of Matter (CBSE 2026-27), with every Think It Over, Activity, Pause & Ponder, Think as a Scientist, What If, Revise Reflect Refine and Journey Beyond question solved step by step. Read your Class 9 Science chapter 9 notes first, then check your answers and numericals here.

Atomic Foundations of Matter explains how atoms combine, and these Class 9 Science Chapter 9 NCERT solutions cover the law of conservation of mass and law of constant proportions numericals, Dalton's atomic theory, valency, ionic and covalent bonds, writing chemical formulae by the criss-cross method, and molecular mass and formula unit mass calculations, with every numerical worked step by step.

Last updated 20 October 2026 · Reviewed by Suchita Arora, 13+ years teaching CBSE Maths & Science

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Overview

What Chapter 9 Is Really About

Atomic Foundations of Matter moves from atoms to the substances they build. It establishes the law of conservation of mass and the law of constant proportions through hands-on activities, uses them to justify Dalton's atomic theory, and then explains how atoms combine — by sharing electrons in a covalent bond or transferring them in an ionic bond — to form molecules and ionic compounds. It closes with writing chemical formulae and calculating molecular mass and formula unit mass. Every question is solved here, section by section, as complete Class 9 Science Chapter 9 NCERT solutions with answers.

⚖️

Conservation of Mass & Constant Proportions

Verifying with weighing-balance activities that mass is conserved in reactions, and that compounds always combine in fixed ratios.

🔗

Covalent & Ionic Bonding

How atoms share electrons to form molecules like H₂, O₂ and H₂O, or transfer electrons to form ions like Na⁺ and Cl⁻.

🧮

Formulae & Molecular Mass

Criss-cross method for writing chemical formulae, and calculating molecular mass and formula unit mass.

Section A

Think It Over (Chapter Opener)

3 Questions
Q1Water can be obtained from various sources. Are all these samples of water chemically identical?▾

Water from different sources (rivers, borewells, the ocean) contains different dissolved impurities.

When the water is purified and analysed, it is always found to contain hydrogen and oxygen in the mass ratio 1:8.

For example, 9 g of purified water from any source gives 1 g of hydrogen and 8 g of oxygen.

This is the Law of Constant Proportions (Law of Definite Proportions) proposed by Proust.

Answer
Yes. Pure water from every source is chemically identical, because it always contains hydrogen and oxygen in the fixed mass ratio 1:8.
Q2Oxygen is sometimes represented as O and sometimes as O₂. What is the difference between these symbols?▾

O represents one atom of oxygen.

O₂ represents a molecule of oxygen, which is made of two oxygen atoms.

Each oxygen atom has 6 valence electrons and needs 2 more to complete its octet.

So two oxygen atoms share two electrons each, and are joined by a double bond (O=O) to form the O₂ molecule.

Answer
O stands for a single oxygen atom, while O₂ stands for a molecule containing two oxygen atoms joined by a double covalent bond.
Q3Why does dissolved salt in water conduct electricity, but sugar does not?▾

Common salt (NaCl) is an ionic compound. It is made of Na⁺ and Cl⁻ ions.

When salt dissolves in water, the ions become free to move, and the moving ions carry the electric current.

Sugar is a covalent compound. It dissolves in water as neutral molecules and does not form ions.

So there are no charged particles to carry the current.

Answer
A salt solution has free ions, so it conducts electricity. A sugar solution has only neutral molecules, so it does not.
Section B

Activities 9.1 – 9.4

5 Questions
A9.1Activity 9.1: Let us investigate a physical change1.Place a clean and dry 100 mL beaker on a digital weighing balance.2.Set the balance reading to zero by pressing the tare or reset button.3.Pour about 50 mL of water into the beaker.4.Add a spatula full of common salt to the water contained in the beaker.5.Record the reading on the weighing balance (Fig. 9.1a).6.Swirl until the added salt dissolves and record your observations (Fig. 9.1b).What do you observe? You may repeat the activity by weighing a piece of paper before and after tearing it into pieces.▾
A beaker of water with undissolved salt on a digital weighing balance reading 55.010 g
(a) Weight of water and undissolved salt
A beaker with the salt dissolved on a digital weighing balance reading 55.011 g
(b) Weight of solution of salt and water
Fig. 9.1 — Activity 9.1: mass before and after dissolving salt

Observation (sample readings):

Mass of water (50 mL) ≈ 50 g, and mass of salt ≈ 2 g.

Reading before the salt dissolves (Fig. 9.1a) ≈ 52 g.

On swirling, the salt dissolves and a clear solution is formed.

Reading after the salt dissolves (Fig. 9.1b) ≈ 52 g.

Torn paper: the mass of the paper pieces is equal to the mass of the whole paper.

Mass of the solution = mass of water + mass of salt, so there is practically no change in mass.

Conclusion
The mass does not change during a physical change, such as the formation of a solution or the tearing of paper.
A9.2 (Set-up 1)Activity 9.2: Let us investigate a chemical change
Vinegar + Baking soda (Sodium hydrogencarbonate) → Carbon dioxide + Other substances
Experimental set-up 11.Place a clean, dry 100 mL conical flask and a medium-sized balloon on a weighing balance.2.Set the balance reading to zero by pressing the tare or reset button.3.Pour about 20 mL of vinegar or lemon juice into the conical flask.4.Take about 2 g of baking soda (sodium hydrogencarbonate) and put it into the balloon.5.Keep the balloon filled with baking soda on the weighing balance next to the conical flask. Record the initial reading (Fig. 9.2a).6.Carefully transfer the baking soda (sodium hydrogencarbonate) from the balloon into the conical flask containing vinegar (Fig. 9.2b).7.Place the conical flask and balloon back on the weighing balance, and record the final reading (Fig. 9.2c).8.What do you observe?9.Are the initial and the final readings same?A brisk effervescence is observed. The final reading does not match the initial reading. What can be the reason for this?
▾
A conical flask with vinegar and a balloon with baking soda on a digital balance reading 22.140 g
(a) Weight of vinegar and baking soda
Baking soda being poured from the balloon into the flask of vinegar, and the final reaction mixture on the balance
(b) Pouring baking soda into the flask (c) Weight of the final reaction mixture
Fig. 9.2 — Activity 9.2, experimental set-up 1 (open flask)

Step 8: A brisk effervescence (bubbles of carbon dioxide gas) is seen when baking soda mixes with vinegar.

Step 9: No. The final reading is slightly less than the initial reading.

Reason: The flask is open, so the carbon dioxide gas produced escapes into the air.

The mass of the escaped gas is not weighed, so the reading falls.

The mass is not destroyed. Only the gas has left the system.

Answer
The final reading is less because the gas (carbon dioxide) formed in the reaction escapes into the surroundings from the open flask.
A9.2 (Set-up 2)Experimental set-up 21.Place a clean, dry 100 mL conical flask and a medium-sized balloon on a weighing balance.2.Set the balance reading to zero by pressing the tare or reset button.3.Pour about 20 mL of vinegar or lemon juice into the conical flask.4.Place about 2 g of baking soda (sodium hydrogencarbonate) in the balloon.5.Fix the balloon to the mouth of the conical flask using a thread, without allowing the baking soda to mix with the vinegar.6.Weigh the conical flask containing vinegar and the balloon containing baking soda, and record the reading (Fig. 9.3a).7.Lift the other end of the balloon upwards, allowing the baking soda (sodium hydrogencarbonate) to fall into the vinegar (Fig. 9.3b).8.What do you observe?9.As in experimental set-up 1, a brisk effervescence occurs, which inflates the balloon during the reaction.10.Record the final reading (Fig. 9.3c).11.Are the initial and the final readings same in this case?▾
A conical flask of vinegar with the balloon of baking soda fixed to its mouth, on a balance reading 22.512 g
(a) Weight of vinegar and baking soda
The balloon lifted so baking soda falls into the vinegar in the flask
(b) Pouring baking soda into the flask
The inflated balloon on the flask after the reaction, on a balance reading 22.510 g
(c) Weight of the final reaction mixture
Fig. 9.3 — Activity 9.2, experimental set-up 2 (balloon fixed to the flask)

Step 8: A brisk effervescence occurs and the balloon gets inflated.

Step 11: Yes. The final reading is the same as the initial reading.

Reason: The flask and balloon form a closed system, so the carbon dioxide gas cannot escape. It is collected in the balloon.

Total mass of vinegar and baking soda before the reaction = total mass of carbon dioxide and other substances after the reaction.

Answer
The initial and final readings are the same. In a closed system, mass is conserved during a chemical change.
A9.3Activity 9.3: Let us verify the law — Group activity1.Place two clean and dry 100 mL conical flasks on a weighing balance, and mark them A and B.2.Set the balance reading to zero by pressing the tare or reset button.3.Pour about 10 mL of 1 % m/v sodium sulfate solution into the Conical Flask marked A.4.In the Conical Flask B, pour about 10 mL of 1 % m/v barium chloride solution.5.Leave both Conical Flasks A and B on the weighing balance undisturbed, and record the total mass of both the solutions (Fig. 9.4a).6.Transfer the solution from Conical Flask B to Conical Flask A and mix the two solutions carefully.7.What do you observe?8.Now, place both the Conical Flasks A and B on the weighing balance again as shown in Fig. 9.4b, and note the reading.9.Do you observe any change in the reading after mixing the solutions?▾
Two conical flasks A and B with barium chloride and sodium sulfate solutions on a balance reading 20.218 g
(a) Weight of solutions (reactants) before mixing
Flasks A and B after mixing, with the reaction mixture, on a balance reading 20.217 g
(b) Weight of products after mixing
Fig. 9.4 — Activity 9.3: mass before and after mixing sodium sulfate and barium chloride

Step 7: A white precipitate is formed on mixing the two solutions.

\[\text{Sodium sulfate} + \text{Barium chloride}\] \[\rightarrow \text{Barium sulfate (white ppt.)}\] \[\quad + \text{Sodium chloride}\]

Step 9: No. The reading after mixing is the same as the reading before mixing.

No gas is formed in this reaction, so nothing escapes from the open flasks.

Mass of reactants (before mixing) = mass of products (after mixing).

Answer
There is no change in the reading, so the total mass is the same before and after the reaction. This verifies the Law of Conservation of Mass.
A9.4Activity 9.4: Let us experiment1.Collect the samples of some compounds, such as camphor, sodium chloride, copper sulfate, sugar and naphthalene.
(A) Solubility in (i) water, (ii) kerosene, and (iii) petrol
2.Try dissolving each sample separately in the water, kerosene and petrol.3.Record your observations in Table 9.2.
(B) Electrical conductivity in the water
4.Take two carbon or metal electrodes and insert them into a piece of cardboard by drilling two holes.5.Connect one end of each electrode to the terminals of the 9 V battery and to the light bulb.6.Test the electrical conductivity of each solid sample and observe whether the bulb glows. Record your observations.7.Test the electrical conductivity of each sample dissolved in water by transferring the solution to the beaker one at a time and observing whether the bulb glows (Fig. 9.15).8.Record your observations with other samples given in Table 9.2.9.Group the compounds showing similar properties listed in Table 9.2.
▾
Circuit with a 9 V battery, a bulb and two electrodes in a beaker of sample solution
Fig. 9.15 — Experimental set-up for electrical conductivity of a solution
Activity 9.4: testing electrical conductivity

Table 9.2 (observations):

CompoundWaterKerosenePetrolSolid state conducts?In water conducts?
CamphorInsolubleSolubleSolubleNoNo
Sodium chlorideSolubleInsolubleInsolubleNoYes
Copper sulfateSolubleInsolubleInsolubleNoYes
SugarSolubleInsolubleInsolubleNoNo
NaphthaleneInsolubleSolubleSolubleNoNo

Step 9: Grouping the compounds

Group 1 (sodium chloride, copper sulfate): soluble in water, insoluble in kerosene and petrol, conduct electricity in water. These are ionic compounds.

Group 2 (camphor, naphthalene): insoluble in water, soluble in kerosene and petrol, do not conduct electricity. These are covalent compounds.

Sugar: it is a covalent compound, soluble in water, but it does not form ions, so its solution does not conduct electricity.

Answer
Ionic compounds (NaCl, CuSO₄) dissolve in water and conduct electricity in solution. Covalent compounds (camphor, naphthalene) dissolve in kerosene and petrol and do not conduct electricity. No compound conducts electricity in the solid state.
Section C

Pause and Ponder

24 Questions
P1A student burns 10 g of ethanol in an open beaker. After the reaction, no residue is left in the beaker. Does this mean the Law of Conservation of Mass is violated? Explain.▾

No, the law is not violated.

Ethanol burns in the oxygen of the air to form carbon dioxide and water vapour.

\[\text{Ethanol} + \text{Oxygen}\] \[\rightarrow \text{Carbon dioxide} + \text{Water vapour}\]

Both products are gases, so they escape into the air from the open beaker and no residue is left.

Mass of ethanol + mass of oxygen used = mass of carbon dioxide + mass of water vapour formed.

The mass of the products is not lost. It is just not collected in the beaker.

Answer
The law is not violated. The gaseous products escape into the air, and the oxygen used came from the air, so mass is conserved overall.
P2When 20 g of hydrogen reacts completely with 160 g of oxygen, how much water is formed according to the Law of Conservation of Mass?▾

Given: mass of hydrogen = 20 g, mass of oxygen = 160 g

To find: mass of water formed

According to the Law of Conservation of Mass, the mass of the product = the total mass of the reactants.

\[\text{mass of water} = 20\text{ g} + 160\text{ g} = 180\text{ g}\]
Answer
180 g of water is formed.
P3A compound consists of 40% sulfur and 60% oxygen by mass. In a sample of the same compound containing 20 g of sulfur, what mass of oxygen must be present to satisfy the Law of Constant Proportions?▾

Given: sulfur : oxygen = 40 : 60 by mass; mass of sulfur in the sample = 20 g

To find: mass of oxygen in the sample

The ratio of the masses of the elements in a compound is fixed.

Sulfur : oxygen = 40 : 60 = 2 : 3

\[\dfrac{\text{mass of oxygen}}{20\text{ g}} = \dfrac{60}{40}\] \[\text{mass of oxygen} = 20 \times \dfrac{60}{40} = 30\text{ g}\]

Check: the sample has 20 g + 30 g = 50 g of the compound. Sulfur = 20/50 = 40% and oxygen = 30/50 = 60%.

Answer
The sample must contain 30 g of oxygen.
P4Carbon monoxide (CO) contains carbon and oxygen in the mass ratio of 3:4. How much oxygen will combine with 9 g of carbon to form carbon monoxide?▾

Given: carbon : oxygen = 3 : 4; mass of carbon = 9 g

To find: mass of oxygen

3 g of carbon combines with 4 g of oxygen.

So 1 g of carbon combines with 4/3 g of oxygen.

\[\text{mass of oxygen} = \dfrac{4}{3} \times 9 = 12\text{ g}\]
Answer
12 g of oxygen will combine with 9 g of carbon.
P5The Law of Definite Proportions holds true for compounds but not for mixtures. Give reason.▾

In a compound, the elements are combined chemically in a fixed ratio by mass. For example, water always has hydrogen and oxygen in the mass ratio 1:8.

In a mixture, the components are only mixed physically and are not chemically combined.

They can be mixed in any proportion. For example, sugar and salt can be mixed in any ratio, and the composition of air varies from place to place.

Answer
A compound has a fixed composition by mass, but the components of a mixture can be present in any proportion.
P6Students X and Y, both prepared an oxide of copper by combining copper and oxygen in the ratios of 4:1 and 8:2, respectively. Do their results justify the Law of Constant Proportions? Explain.▾

Ratio of copper to oxygen for student X = 4 : 1

Ratio of copper to oxygen for student Y = 8 : 2

\[8 : 2 = \dfrac{8}{2} : \dfrac{2}{2} = 4 : 1\]

Both students obtained the same ratio, 4 : 1.

Answer
Yes. Both oxides have copper and oxygen in the same ratio of 4:1, so the results justify the Law of Constant Proportions.
P7Assertion (A): 2 g of hydrogen combines with 16 g of oxygen to form 18 g of water.
Reason (R): According to Dalton’s Atomic Theory, atoms combine in a simple whole number ratio by mass to form compounds.
Choose the correct option:
▾

Assertion (A): It is true. The mass of water = 2 g + 16 g = 18 g, which obeys the Law of Conservation of Mass. Also H : O = 2 : 16 = 1 : 8.

Reason (R): It is false. Dalton's postulate says that atoms combine in the ratio of simple whole numbers, i.e., in terms of the number of atoms and not their masses.

The ratio by mass is generally not a simple whole number ratio. For example, in NaCl the mass ratio of Na to Cl is 23 : 35.5.

Answer
Option (iii): A is true, but R is false.
P8Nitrogen has five valence electrons. Draw the structure of the nitrogen molecule (N₂).▾

Nitrogen has 5 valence electrons (electronic configuration 2, 5).

Each nitrogen atom needs 3 more electrons to complete its octet.

So two nitrogen atoms share three pairs of electrons (each atom gives 3 electrons).

The two atoms are joined by a triple bond, N≡N. Each atom also has one lone pair.

N N + www.boundlessmaths.com
N N www.boundlessmaths.com
Two nitrogen atoms (top) share three pairs of electrons to form N₂ (bottom): N≡N, a triple bond. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom
Answer
The nitrogen molecule N₂ has a triple covalent bond (N≡N) with three shared pairs of electrons and one lone pair on each atom.
P9The atomic number of fluorine is 9. Explain the formation of the fluorine molecule (F₂).▾

Electronic configuration of fluorine (Z = 9) = 2, 7. It has 7 valence electrons.

Each fluorine atom needs one more electron to complete its octet.

So two fluorine atoms share one pair of electrons (each gives 1 electron).

They are joined by a single covalent bond, F—F. Each atom has three lone pairs.

F F + www.boundlessmaths.com
F F www.boundlessmaths.com
Two fluorine atoms (top) share one pair of electrons to form F₂ (bottom): F—F, a single bond. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom
Answer
Two fluorine atoms share one pair of electrons and form the F₂ molecule with a single covalent bond, F—F.
P10Show the formation of the following molecules:(i)Carbon dioxide (CO₂)(ii)Hydrogen sulfide (H₂S)(iii)Ammonia (NH₃)▾
(i)Carbon dioxide (CO₂)

Carbon (2, 4) has 4 valence electrons and needs 4 more.

Oxygen (2, 6) has 6 valence electrons and needs 2 more.

Carbon shares two electrons with each oxygen atom, so there are two double bonds: O=C=O.

O C O + + www.boundlessmaths.com
O C O www.boundlessmaths.com
Carbon (4 valence electrons) shares two electrons with each oxygen atom: O=C=O, two double bonds. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom
Ans.O=C=O (two double bonds)
(ii)Hydrogen sulfide (H₂S)

Sulfur (2, 8, 6) needs 2 more electrons. Hydrogen (1) needs 1 more electron.

Sulfur shares one electron with each of two hydrogen atoms: H—S—H.

H S H + + www.boundlessmaths.com
H S H www.boundlessmaths.com
Sulfur (6 valence electrons) shares one electron with each of two hydrogen atoms: H—S—H. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom
Ans.H—S—H (two single bonds)
(iii)Ammonia (NH₃)

Nitrogen (2, 5) needs 3 more electrons. Hydrogen needs 1 more electron.

Nitrogen shares one electron with each of three hydrogen atoms (three single bonds), and has one lone pair.

N H H H + + + www.boundlessmaths.com
N H H H www.boundlessmaths.com
Nitrogen (5 valence electrons) shares one electron with each of three hydrogen atoms; one lone pair remains on N. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom
Ans.Three N—H single bonds and one lone pair on N
P11Neon (atomic number 10) neither transfers nor shares its valence electrons. Explain.▾

Electronic configuration of neon (Z = 10) = 2, 8.

Its valence shell (L shell) already has 8 electrons, which is a complete octet.

An atom with a complete octet is stable, so it has no tendency to lose, gain or share electrons.

Answer
Neon has a complete octet (2, 8), so it is already stable and does not need to transfer or share electrons. It exists as single atoms.
P12What kind of ion will oxygen (O) form?▾

Oxygen (Z = 8) has the electronic configuration 2, 6.

It needs 2 more electrons to complete its octet, so it gains 2 electrons.

Number of protons = 8 and number of electrons = 8 + 2 = 10.

\[\text{O} + 2e^{-} \rightarrow \text{O}^{2-}\]
Answer
Oxygen forms the oxide ion, O²⁻, which is an anion (negatively charged ion) with the configuration 2, 8.
P13Fill in the blanks.
Among magnesium and chlorine, magnesium atom can give two electrons to become Mg²⁺. However, chlorine can take only one electron to become ____________. Now, __________ ion of magnesium and __________ ions of chlorine combine to give magnesium chloride.
▾

Chlorine (2, 8, 7) takes one electron and becomes Cl⁻ (2, 8, 8).

One Mg²⁺ ion gives 2 positive charges, and each Cl⁻ ion carries 1 negative charge.

So 2 Cl⁻ ions are needed to balance the charge of one Mg²⁺ ion.

1st blank

Chlorine takes one electron.

Ans.Cl⁻ (chloride ion)
2nd blank

One Mg²⁺ ion has a charge of 2+.

Ans.one
3rd blank

Two Cl⁻ ions have a total charge of 2–.

Ans.two
Answer
Chlorine can take only one electron to become Cl⁻. Now, one ion of magnesium and two ions of chlorine combine to give magnesium chloride (MgCl₂).
P14Show the formation of cations of potassium (K) and calcium (Ca) atoms, and the formation of their corresponding chlorides using diagrams.▾

Potassium (Z = 19): configuration 2, 8, 8, 1. It loses 1 electron and becomes K⁺ (2, 8, 8).

Calcium (Z = 20): configuration 2, 8, 8, 2. It loses 2 electrons and becomes Ca²⁺ (2, 8, 8).

K K + → + e⁻ www.boundlessmaths.com
Ca Ca 2+ → + 2e⁻ www.boundlessmaths.com
Formation of the cations K⁺ and Ca²⁺ by loss of valence electrons. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom

Chlorine (Z = 17): configuration 2, 8, 7. It gains 1 electron and becomes Cl⁻ (2, 8, 8).

Potassium chloride: K⁺ + Cl⁻ → KCl (one K⁺ for one Cl⁻).

Calcium chloride: Ca²⁺ + 2 Cl⁻ → CaCl₂ (one Ca²⁺ for two Cl⁻).

K Cl + – + KCl www.boundlessmaths.com
Cl Ca Cl – 2+ – www.boundlessmaths.com
Formation of KCl (top) and CaCl₂ (bottom: Cl⁻, Ca²⁺, Cl⁻): the oppositely charged ions are held together by an ionic bond. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom
Answer
K loses 1 electron to form K⁺, and Ca loses 2 electrons to form Ca²⁺. They combine with Cl⁻ to form KCl and CaCl₂ respectively.
P15Illustrate how sodium sulfide (Na₂S) is formed.▾

Sodium (2, 8, 1) has 1 valence electron. It loses it and becomes Na⁺.

Sulfur (2, 8, 6) has 6 valence electrons. It needs 2 electrons, so it gains 2 electrons and becomes S²⁻.

One S²⁻ ion needs two Na⁺ ions, each giving 1 electron.

\[2\,\text{Na}^{+} + \text{S}^{2-} \rightarrow \text{Na}_2\text{S}\]
Na S Na + + www.boundlessmaths.com
Na S Na + 2– + www.boundlessmaths.com
Each sodium atom gives its one valence electron to the sulfur atom. Sulfur gains two electrons and becomes S²⁻. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom
Answer
Two sodium atoms transfer one electron each to a sulfur atom. The 2 Na⁺ ions and one S²⁻ ion are held by ionic bonds in Na₂S.
P16Name the following:(i)CO₂ _______________________________(ii)NO₂ _______________________________(iii)SF₆ _______________________________(iv)PCl₃ _______________________________▾

Prefixes show the number of atoms: mono (1), di (2), tri (3), tetra (4), penta (5), hexa (6).

(i)CO₂

1 carbon atom and 2 oxygen atoms. Mono is omitted for the first element.

Ans.Carbon dioxide
(ii)NO₂

1 nitrogen atom and 2 oxygen atoms.

Ans.Nitrogen dioxide
(iii)SF₆

1 sulfur atom and 6 fluorine atoms.

Ans.Sulfur hexafluoride
(iv)PCl₃

1 phosphorus atom and 3 chlorine atoms.

Ans.Phosphorus trichloride
P17Write the formula for the following:(i)Sodium hydrogencarbonate _____________________(ii)Sulfur dioxide ____________________________________(iii)Ferric chloride ___________________________________(iv)Cuprous oxide ___________________________________▾
(i)Sodium hydrogencarbonate

Na⁺ (charge 1+) and HCO₃⁻ (charge 1–). The charges are equal, so one of each combines.

Ans.NaHCO₃
(ii)Sulfur dioxide

It is a covalent compound. The prefix 'di' means 2 oxygen atoms and one sulfur atom.

Ans.SO₂
(iii)Ferric chloride

Ferric is Fe³⁺ and chloride is Cl⁻.

Criss-cross the charges: Fe₁Cl₃, so the formula is FeCl₃.

Ans.FeCl₃
(iv)Cuprous oxide

Cuprous is Cu⁺ and oxide is O²⁻.

Criss-cross the charges: Cu₂O₁, so the formula is Cu₂O.

Ans.Cu₂O
P18Write the formulae for the compounds formed from the following pairs of ions:(i)Fe³⁺ and OH‒(ii)K⁺ and CO₃²⁻▾
(i)Fe³⁺ and OH⁻

Symbols: Fe and OH. Charges: 3+ and 1–.

Criss-cross the charges (only the numbers): Fe has 1 and OH has 3.

Brackets are used for the polyatomic ion OH when it occurs more than once.

Ans.Fe(OH)₃
(ii)K⁺ and CO₃²⁻

Symbols: K and CO₃. Charges: 1+ and 2–.

Criss-cross the charges: K has 2 and CO₃ has 1.

Brackets are not required when only one polyatomic ion is present.

Ans.K₂CO₃
P19What type of chemical bond is present in a solid compound that does not conduct electricity in the solid state but conducts electricity when dissolved in water?▾

In the solid state, the ions of an ionic compound are held in fixed positions, so the compound does not conduct electricity.

When it is dissolved in water, the ions become free to move, so the solution conducts electricity.

Covalent compounds do not give ions in water.

Answer
The compound has an ionic bond.
P20Metal M, with two electrons in its valence shell (M shell), reacts with oxygen to form a compound that is slightly soluble in water. Predict its:▾

The valence shell is the M shell (third shell), so the configuration of M is 2, 8, 2 (atomic number 12, magnesium).

M loses 2 electrons to form M²⁺. Oxygen gains 2 electrons to form O²⁻.

(i)Formula

Charges: M is 2+ and O is 2–.

Criss-cross: M₂O₂, which is simplified to MO.

Ans.MO (for example, MgO)
(ii)Type of bond

A metal transfers electrons to a non-metal.

Ans.Ionic bond
(iii)Electrical conductivity of its aqueous solution

The dissolved part gives free M²⁺ and O²⁻-derived ions in the solution.

Free ions can carry current.

Ans.It conducts electricity
P21Find the molecular mass of nitric acid (HNO₃).
Atomic mass — H = 1 u; N = 14 u; O = 16 u.
▾

Given: H = 1 u, N = 14 u, O = 16 u

HNO₃ has 1 hydrogen atom, 1 nitrogen atom and 3 oxygen atoms.

Molecular mass of HNO₃:

\[(1 \times 1) + (14 \times 1) + (16 \times 3)\] \[= 1 + 14 + 48\] \[= 63\text{ u}\]
Answer
The molecular mass of nitric acid is 63 u.
P22Find the molecular mass of methane (CH₄).
Atomic mass — C = 12 u; H = 1 u.
▾

Given: C = 12 u, H = 1 u

CH₄ has 1 carbon atom and 4 hydrogen atoms.

\[\begin{aligned}\text{molecular mass of CH}_4 &= (12 \times 1) + (1 \times 4) \\ &= 12 + 4 \\ &= 16\text{ u}\end{aligned}\]
Answer
The molecular mass of methane is 16 u.
P23Find the formula unit mass of potassium chloride (KCl).
Atomic mass — K = 39 u; Cl = 35.5 u.
▾

Given: K = 39 u, Cl = 35.5 u

KCl has 1 potassium and 1 chlorine in its formula unit.

Formula unit mass of KCl:

\[(39 \times 1) + (35.5 \times 1)\] \[= 74.5\text{ u}\]
Answer
The formula unit mass of KCl is 74.5 u.
P24Find the formula unit mass of magnesium hydroxide, Mg(OH)₂.
Atomic mass — Mg = 24 u; O = 16 u; H = 1 u.
▾

Given: Mg = 24 u, O = 16 u, H = 1 u

Mg(OH)₂ has 1 magnesium atom and 2 OH groups (2 oxygen and 2 hydrogen atoms).

\[\text{formula unit mass} = 24 + 2 \times (16 + 1)\] \[= 24 + 34 = 58\text{ u}\]
Answer
The formula unit mass of Mg(OH)₂ is 58 u.
Section D

Think as a Scientist

1 Question
TaS1You are given a chemical reaction in which zinc reacts with dilute hydrochloric acid to form zinc chloride and hydrogen gas.
Zinc + Hydrochloric acid (dilute) → Zinc chloride + Hydrogen
Design and perform an experiment to test the hypothesis that mass is conserved during the chemical reaction. You may use a set-up different from the one shown in Activity 9.2.
▾

Hypothesis: The mass of the reactants (zinc and dilute hydrochloric acid) = the mass of the products (zinc chloride and hydrogen).

Problem: Hydrogen gas is formed and can escape from an open flask. So a closed set-up is needed.

Procedure:

1. Take a clean, dry conical flask and pour about 20 mL of dilute hydrochloric acid into it.

2. Put a few small pieces of zinc granules in a small balloon, and fix the balloon to the mouth of the flask with a thread, so that the zinc does not fall into the acid.

3. Place the whole set-up on a digital weighing balance and record the initial reading.

4. Lift the balloon upwards so that the zinc falls into the acid.

5. Hydrogen gas is formed with brisk bubbling and it inflates the balloon.

6. When the reaction is over, place the whole set-up on the balance again and record the final reading.

Expected observation: The final reading is the same as the initial reading.

The hydrogen gas is collected in the balloon and cannot escape, so the whole mass is accounted for.

Precaution: Keep flames away, as hydrogen is combustible. Do not close the flask with a rigid stopper, as the gas pressure may build up.

Conclusion
The initial mass is equal to the final mass, so mass is conserved in the reaction of zinc with dilute hydrochloric acid.
Section E

What If

2 Questions
WI1What if ...
atoms could combine in any ratio and not in a fixed ratio? How would this affect the substances around us?
▾

A compound would not have a fixed composition, so the Law of Constant Proportions would not hold.

For example, water from different sources could contain different amounts of hydrogen and oxygen.

A substance with the same name could then have different properties each time it is made.

A compound like sodium chloride could differ from sample to sample, and chemical formulae would lose their meaning.

It would be difficult to make reliable medicines, foods, fertilisers and other materials.

Answer
Substances would not have fixed compositions or properties, and chemistry would be unpredictable. The fixed ratios of atoms are what make each compound the same everywhere.
WI2What if ...
we could see atoms directly? How would it help scientists and what challenges would it cause?
▾

How it would help:

Scientists could see how atoms are arranged in molecules and crystals, and how bonds form and break during a reaction.

They could test atomic models directly, and design better medicines, batteries and materials.

Challenges:

An atom is only about 10⁻¹⁰ m in size, so it would need very powerful instruments (like electron microscopes).

Even a tiny sample has a huge number of atoms, so the picture would be very complicated to understand.

Atoms are always in motion, and electrons do not move in well-defined paths, so a clear picture would be hard to get.

Answer
Seeing atoms would help in understanding structure and reactions directly, but their tiny size, huge numbers and constant motion would make this very difficult.
Section F

Questions from the Text

4 Questions
IN1Identify four such elements among the first 18 elements by using their electronic configurations given in Table 8.4 of the Chapter 8, Journey Inside the Atom.
(Atoms with less than four electrons in the valence shell donate electrons.)
▾

From Table 8.4, elements with fewer than four valence electrons are:

ElementConfigurationValence electrons
Lithium (Li)2, 11
Beryllium (Be)2, 22
Sodium (Na)2, 8, 11
Magnesium (Mg)2, 8, 22
Aluminium (Al)2, 8, 33
Answer
Four such elements are lithium, sodium, magnesium and aluminium. Each has fewer than 4 valence electrons and tends to donate them.
IN2Will it still be neutral after losing one electron? If not, what charge would it carry and why?
(The sodium atom, atomic number 11, loses its one valence electron.)
▾

A sodium atom has 11 protons and 11 electrons, so it is neutral.

After losing one electron, it has 11 protons and 10 electrons.

Positive charge = +11 and negative charge = –10, so the net charge = +1.

\[\text{Na} \rightarrow \text{Na}^{+} + e^{-}\]
Answer
No. It becomes a positively charged sodium cation, Na⁺, because it has one proton more than the number of electrons.
IN3Predict whether ionic and covalent compounds would conduct electricity in the molten state (the melted state of a substance).▾

Ionic compounds: in the molten state, the ions are free to move, so they conduct electricity.

Covalent compounds: they are made of neutral molecules, which have no free ions or electrons, so they do not conduct electricity even in the molten state.

Answer
Ionic compounds conduct electricity in the molten state, but covalent compounds do not.
IN4Other covalent compounds, such as camphor and naphthalene, also do not conduct electricity. Can you give a reason?▾

Camphor and naphthalene are covalent compounds made of neutral molecules.

They are insoluble in water, so no ions are formed in water.

They do not have free ions or free electrons to carry the electric charge.

Answer
Camphor and naphthalene consist of neutral molecules and do not form ions, so they do not conduct electricity.
Section G

Worked Examples 9.1 – 9.7

7 Questions
Ex 9.1Example 9.1: In a group activity, students place 4.0 g of calcium carbonate with 2.92 g of hydrochloric acid in a closed container. After the reaction is over, they measured 1.76 g of carbon dioxide, 0.72 g of water, and 4.44 g of calcium chloride. Verify whether the Law of Conservation of Mass is obeyed or not.▾

Given: calcium carbonate = 4.0 g; hydrochloric acid = 2.92 g; carbon dioxide = 1.76 g; water = 0.72 g; calcium chloride = 4.44 g

Total mass of the reactants:

\[4.0\text{ g} + 2.92\text{ g} = 6.92\text{ g}\]

Total mass of the products:

\[1.76\text{ g} + 0.72\text{ g} + 4.44\text{ g} = 6.92\text{ g}\]

Mass of reactants = mass of products.

Answer
The total mass of the reactants (6.92 g) is equal to the total mass of the products (6.92 g), so the Law of Conservation of Mass is obeyed.
Ex 9.2Example 9.2: 12 g of carbon combines with 32 g of oxygen to form 44 g of carbon dioxide as per the given equation.
Carbon + Oxygen → Carbon dioxide
If 2.4 g of carbon reacts completely with oxygen, how much carbon dioxide will be produced?
▾

Given: 12 g of carbon gives 44 g of carbon dioxide

To find: carbon dioxide formed from 2.4 g of carbon

12 g of carbon gives 44 g of carbon dioxide.

So 1 g of carbon gives 44/12 g of carbon dioxide.

So 2.4 g of carbon gives

\[\dfrac{44}{12} \times 2.4 = 8.8\text{ g}\]
Answer
8.8 g of carbon dioxide will be produced.
Ex 9.3Example 9.3: Sodium chloride (NaCl) contains sodium and chlorine in the mass ratio of 23:35.5. If 46 g of sodium reacts completely, how much chlorine is needed to form NaCl?▾

Given: Na : Cl = 23 : 35.5; mass of sodium = 46 g

To find: mass of chlorine needed

23 g of sodium combines with 35.5 g of chlorine.

So 1 g of sodium combines with 35.5/23 g of chlorine.

\[\text{mass of chlorine} = \dfrac{35.5}{23} \times 46 = 71\text{ g}\]
Answer
71 g of chlorine is needed.
Ex 9.4Example 9.4
Molecular mass of water (H₂O)
Atomic mass — H = 1 u; O = 16 u
▾

H₂O has 2 hydrogen atoms and 1 oxygen atom.

\[\begin{aligned}\text{molecular mass of H}_2\text{O} &= (1 \times 2) + (16 \times 1) \\ &= 18\text{ u}\end{aligned}\]
Answer
The molecular mass of water is 18 u.
Ex 9.5Example 9.5
Molecular mass of carbon dioxide (CO₂)
Atomic mass — C = 12 u; O = 16 u
▾

CO₂ has 1 carbon atom and 2 oxygen atoms.

\[\begin{aligned}\text{molecular mass of CO}_2 &= (12 \times 1) + (16 \times 2) \\ &= 44\text{ u}\end{aligned}\]
Answer
The molecular mass of carbon dioxide is 44 u.
Ex 9.6Example 9.6
Formula unit mass of sodium oxide (Na₂O)
Atomic mass — Na = 23 u; O = 16 u
▾

Na₂O has 2 sodium atoms and 1 oxygen atom in its formula unit.

Formula unit mass of Na₂O:

\[(23 \times 2) + (16 \times 1)\] \[= 46 + 16\] \[= 62\text{ u}\]
Answer
The formula unit mass of sodium oxide is 62 u.
Ex 9.7Example 9.7
Formula unit mass of calcium nitrate, Ca(NO₃)₂
Atomic mass — Ca = 40 u; N = 14 u; O = 16 u
▾

Ca(NO₃)₂ has 1 calcium atom and 2 nitrate (NO₃) groups.

Mass of one NO₃ group = 14 + (16 × 3) = 62 u.

\[\text{formula unit mass} = 40 + (62 \times 2)\] \[= 40 + 124 = 164\text{ u}\]
Answer
The formula unit mass of calcium nitrate is 164 u.
Section H

Revise, Reflect, Refine (Back Exercise)

15 Questions
Q1A particular element (A) has one electron in its third shell. There is another element (B) with six electrons in its second shell.(i)How many electrons does A tend to give or take to become stable?(ii)What kind of ion would it form?(iii)How many electrons does B tend to give or take to become stable?(iv)What kind of ion would it form?(v)If A and B were to combine, what kind of bond would be formed?(vi)What would be the formula for the compound thus formed?▾

Element A has 1 electron in the third shell, so its configuration is 2, 8, 1 (atomic number 11, sodium).

Element B has 6 electrons in the second shell, so its configuration is 2, 6 (atomic number 8, oxygen).

(i)A: electrons given or taken

A has 1 valence electron. It gives away 1 electron to get the stable configuration 2, 8.

Ans.It gives 1 electron
(ii)Ion formed by A

After losing 1 electron, it has 11 protons and 10 electrons.

Ans.Cation, A⁺ (Na⁺)
(iii)B: electrons given or taken

B has 6 valence electrons. It takes 2 electrons to complete its octet.

Ans.It takes 2 electrons
(iv)Ion formed by B

After gaining 2 electrons, it has 8 protons and 10 electrons.

Ans.Anion, B²⁻ (O²⁻)
(v)Bond between A and B

A transfers electrons and B accepts them.

Ans.Ionic bond
(vi)Formula of the compound

Charges: A is 1+ and B is 2–.

Criss-cross: A₂B₁, so the formula is A₂B.

Ans.A₂B (Na₂O)
Q2An element X has six electrons in its outer shell and forms a diatomic molecule.(i)Why would that be so?(ii)What kind of bond would it form?(iii)Draw the structure of the molecule it would form.(iv)A certain other element Y has two electrons in its second shell. Draw the structure of the molecule that X would form with Y.▾

X has 6 valence electrons, so it needs 2 more electrons to complete its octet. X is oxygen if it has two shells (configuration 2, 6).

(i)Why a diatomic molecule?

Each atom of X needs 2 electrons for an octet.

Two atoms of X share two electrons each, and both get 8 electrons in the outer shell.

Ans.Two atoms share electrons to complete their octets
(ii)Kind of bond

The atoms share two pairs of electrons.

Ans.Covalent bond (a double bond, X=X)
(iii)Structure of X₂

Two shared pairs and two lone pairs on each atom (with X = O):

O O www.boundlessmaths.com
Oxygen molecule O₂: two shared pairs, O=O (double bond), and two lone pairs on each atom. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom
Ans.X=X
(iv)Molecule of X with Y

Y has two electrons in its second shell, so its configuration is 2, 2 (atomic number 4, beryllium).

Y has 2 valence electrons. It loses them, and X (needing 2 electrons) accepts them.

So X and Y do not share electrons. Y²⁺ and X²⁻ ions are formed and held by an ionic bond.

The formula is YX (BeO). It is an ionic compound and exists as a crystal, not as a separate molecule.

Be O + www.boundlessmaths.com
Be O 2+ 2– → BeO www.boundlessmaths.com
Beryllium gives two electrons to oxygen: Be²⁺ and O²⁻ are held by an ionic bond. Dots (•) are the electrons of one atom and crosses (×) are the electrons of the other atom
Ans.YX (BeO) with Y²⁺ and X²⁻ ions
Q3You want to design a new ionic compound, where the total positive charge is 6+ and the total negative charge is 6–. Which of the following combinations gives the correct number of ions?
(i) 2 Al³⁺ and 3 Cl⁻
(ii) 3 Mg²⁺ and 1 PO₄³⁻
(iii) 2 Fe³⁺ and 3 O²⁻
(iv) 3 Ca²⁺ and 2 SO₄²⁻
▾

Total charge = number of ions × charge on each ion.

(i)2 Al³⁺ and 3 Cl⁻Incorrect

Positive charge = 2 × 3 = 6+

Negative charge = 3 × 1 = 3–

Ans.Not balanced (6+ and 3–)
(ii)3 Mg²⁺ and 1 PO₄³⁻Incorrect

Positive charge = 3 × 2 = 6+

Negative charge = 1 × 3 = 3–

Ans.Not balanced (6+ and 3–)
(iii)2 Fe³⁺ and 3 O²⁻Correct

Positive charge = 2 × 3 = 6+

Negative charge = 3 × 2 = 6–

Ans.Balanced (6+ and 6–)
(iv)3 Ca²⁺ and 2 SO₄²⁻Incorrect

Positive charge = 3 × 2 = 6+

Negative charge = 2 × 2 = 4–

Ans.Not balanced (6+ and 4–)
Answer
Combination (iii), 2 Fe³⁺ and 3 O²⁻, gives 6+ and 6–. The compound is Fe₂O₃.
Q4Choose the correct statement(s) and correct the false statement(s).(i)Elements are made up of molecules and compounds are made up of atoms.(ii)The molecule of a compound is always made up of two or more atoms of the same kind.(iii)One molecule of nitrogen gas contains three nitrogen atoms.(iv)Water is made of two hydrogen atoms, covalently bonded with one oxygen atom.▾
(i)Elements and compoundsFalse

Elements are made up of only one kind of atom (some exist as molecules of the same atoms). Compounds are made up of atoms of different elements, combined as molecules or ions.

Ans.False. Correct statement: elements are made up of atoms of one kind, and compounds are made up of molecules (or ions) formed by atoms of different kinds.
(ii)Molecule of a compoundFalse

A molecule of a compound is made from atoms of different elements (for example, H₂O). A molecule with atoms of the same kind is a molecule of an element.

Ans.False. Correct statement: the molecule of a compound is always made up of two or more atoms of different kinds.
(iii)Nitrogen moleculeFalse

Nitrogen is N₂, with two nitrogen atoms joined by a triple bond.

Ans.False. Correct statement: one molecule of nitrogen gas contains two nitrogen atoms.
(iv)WaterTrue

The formula of water is H₂O. Hydrogen and oxygen share electrons, so the bonds are covalent.

Ans.True
Answer
Only statement (iv) is correct. Statements (i), (ii) and (iii) are false, and they are corrected above.
Q5Write the chemical formulae for the following compounds.(i)Aluminium nitrate(ii)Calcium oxide(iii)Ferric oxide▾
(i)Aluminium nitrate

Ions: Al³⁺ and NO₃⁻.

Criss-cross: Al has 1 and NO₃ has 3.

Brackets are needed for NO₃.

Ans.Al(NO₃)₃
(ii)Calcium oxide

Ions: Ca²⁺ and O²⁻.

Criss-cross: Ca₂O₂, which is simplified to CaO.

Ans.CaO
(iii)Ferric oxide

Ions: Fe³⁺ and O²⁻.

Criss-cross: Fe₂O₃.

Ans.Fe₂O₃
Q6Write the formulae of the compounds formed from the following pairs of ions.(i)Ca²⁺ and Br⁻(ii)Al³⁺ and CO₃²⁻(iii)K⁺ and SO₄²⁻(iv)NH₄⁺ and Cl⁻▾
(i)Ca²⁺ and Br⁻

Charges: 2+ and 1–.

Criss-cross: Ca₁Br₂.

Ans.CaBr₂
(ii)Al³⁺ and CO₃²⁻

Charges: 3+ and 2–.

Criss-cross: Al₂(CO₃)₃.

Ans.Al₂(CO₃)₃
(iii)K⁺ and SO₄²⁻

Charges: 1+ and 2–.

Criss-cross: K₂(SO₄)₁. Brackets are not needed for one polyatomic ion.

Ans.K₂SO₄
(iv)NH₄⁺ and Cl⁻

Charges: 1+ and 1–. One ion of each combines.

Ans.NH₄Cl
Q7Which of the following, in Fig. 9.18, correctly represents Cl⁻ ion (Atomic number of chlorine = 17).▾

A chlorine atom has 17 electrons (2, 8, 7).

The Cl⁻ ion has gained one electron, so it has 17 + 1 = 18 electrons, with the configuration 2, 8, 8.

Counting the electrons in each diagram of Fig. 9.18:

17+ (i) 2, 7, 8 www.boundlessmaths.com
17+ (ii) 2, 8, 8 www.boundlessmaths.com
17+ (iii) 2, 8, 9 www.boundlessmaths.com
17+ (iv) 2, 8, 7 www.boundlessmaths.com
Fig. 9.18 (redrawn): the electrons in each shell are counted from the figure
DiagramKLMTotal electrons
(i)27817
(ii)28818
(iii)28919
(iv)28717

(i) has 17 electrons with a wrong arrangement (2, 7, 8). (iii) has 19 electrons. (iv) is a neutral chlorine atom.

Answer
Diagram (ii) correctly represents the Cl⁻ ion. It has 18 electrons arranged as 2, 8, 8.
Q8Determine the formula unit mass of the following substances.(i)Ammonium nitrate (NH₄NO₃), used as a nitrogen fertiliser, which is essential for plant growth.(ii)Phosphoric acid (H₃PO₄), used to make phosphate fertiliser and detergents.(iii)Sodium hydrogencarbonate (NaHCO₃), used to relieve acidity and helps in digestion.▾

Atomic masses used: H = 1 u, C = 12 u, N = 14 u, O = 16 u, Na = 23 u, P = 31 u.

(i)NH₄NO₃

It has 2 N, 4 H and 3 O atoms.

\[(14 \times 2) + (1 \times 4) + (16 \times 3)\] \[= 28 + 4 + 48\] \[= 80\text{ u}\]
Ans.80 u
(ii)H₃PO₄

It has 3 H, 1 P and 4 O atoms.

\[(1 \times 3) + (31 \times 1) + (16 \times 4)\] \[= 3 + 31 + 64\] \[= 98\text{ u}\]
Ans.98 u
(iii)NaHCO₃

It has 1 Na, 1 H, 1 C and 3 O atoms.

\[23 + 1 + 12 + (16 \times 3)\] \[= 23 + 1 + 12 + 48\] \[= 84\text{ u}\]
Ans.84 u
Q9Write the formulae for the compounds formed by the reaction of:(i)Magnesium and nitrogen(ii)Lithium and nitrogen(iii)Sodium and sulfur(iv)Aluminium and oxygen▾
(i)Magnesium and nitrogen

Mg gives Mg²⁺ and nitrogen gives N³⁻.

Criss-cross: Mg₃N₂.

Ans.Mg₃N₂
(ii)Lithium and nitrogen

Li gives Li⁺ and nitrogen gives N³⁻.

Criss-cross: Li₃N.

Ans.Li₃N
(iii)Sodium and sulfur

Na gives Na⁺ and sulfur gives S²⁻.

Criss-cross: Na₂S.

Ans.Na₂S
(iv)Aluminium and oxygen

Al gives Al³⁺ and oxygen gives O²⁻.

Criss-cross: Al₂O₃.

Ans.Al₂O₃
Q10Complete the Table 9.3 by writing the formulae of the compounds formed by the cations on the left and the anions at the top. LiNO₃ is given as an example.
NO₃⁻SO₄²⁻PO₄³⁻
NH₄⁺
Li⁺LiNO₃
Al³⁺
Cu²⁺
▾

Write the cation first and then the anion, and criss-cross the charges. Use brackets for a polyatomic ion that occurs more than once.

NH₄⁺: NH₄NO₃, (NH₄)₂SO₄, (NH₄)₃PO₄

Li⁺: LiNO₃ (given), Li₂SO₄, Li₃PO₄

Al³⁺: Al(NO₃)₃, Al₂(SO₄)₃. For Al³⁺ and PO₄³⁻, the charges are equal, so the formula is AlPO₄.

Cu²⁺: Cu(NO₃)₂. For Cu²⁺ and SO₄²⁻, the charges are equal, so the formula is CuSO₄. For PO₄³⁻, Cu₃(PO₄)₂.

NO₃⁻SO₄²⁻PO₄³⁻
NH₄⁺NH₄NO₃(NH₄)₂SO₄(NH₄)₃PO₄
Li⁺LiNO₃Li₂SO₄Li₃PO₄
Al³⁺Al(NO₃)₃Al₂(SO₄)₃AlPO₄
Cu²⁺Cu(NO₃)₂CuSO₄Cu₃(PO₄)₂
Answer
Table 9.3 is completed as shown above.
Q115.3 g of sodium carbonate and 6.0 g of acetic acid react to produce 2.2 g of carbon dioxide, 0.9 g of water, and 8.2 g of sodium acetate. Verify whether the law of conservation of mass is valid.▾

Given: sodium carbonate = 5.3 g; acetic acid = 6.0 g; carbon dioxide = 2.2 g; water = 0.9 g; sodium acetate = 8.2 g

Total mass of the reactants:

\[5.3\text{ g} + 6.0\text{ g} = 11.3\text{ g}\]

Total mass of the products:

\[2.2\text{ g} + 0.9\text{ g} + 8.2\text{ g} = 11.3\text{ g}\]
Answer
The mass of the reactants (11.3 g) is equal to the mass of the products (11.3 g), so the law of conservation of mass is valid.
Q12If a species has 11 protons, 12 neutrons and 10 electrons then(i)what is its atomic number and mass number?(ii)is it neutral, a cation or an anion? Explain.(iii)write its electronic configuration.(iv)name the species.▾

Given: protons = 11, neutrons = 12, electrons = 10

(i)Atomic number and mass number

Atomic number = number of protons = 11.

Mass number = protons + neutrons = 11 + 12 = 23.

Ans.Atomic number = 11, mass number = 23
(ii)Neutral, cation or anion?

Positive charge = +11 and negative charge = –10.

Net charge = +1, because protons are more than electrons.

Ans.It is a cation (charge +1)
(iii)Electronic configuration

It has 10 electrons: K = 2, L = 8.

Ans.2, 8
(iv)Name of the species

Atomic number 11 is sodium, and the charge is +1.

Ans.Sodium ion, Na⁺
Q13Two elements, A and B, have the following configurations —
A: 2, 8, 5    B: 2, 8, 7(i)Which element is more reactive?(ii)Will A and B form ionic or covalent bonds when they combine? Explain using electron transfer or sharing.(iii)Predict the formula of the compound they would form.
▾

A has 15 electrons (phosphorus). A needs 3 more electrons for an octet, so its valency is 3.

B has 17 electrons (chlorine). B needs 1 more electron for an octet, so its valency is 1.

(i)More reactive element

B needs only 1 electron to complete its octet, so it gains the electron very easily.

A needs 3 electrons, which is harder.

Ans.B is more reactive
(ii)Type of bond

Both A and B are non-metals and both need electrons.

Neither can lose electrons easily, so they share electrons.

A shares 3 electrons, one with each of three B atoms.

Ans.Covalent bond
(iii)Formula of the compound

Valency of A = 3 and valency of B = 1.

Criss-cross: A₁B₃, so the formula is AB₃.

Ans.AB₃ (PCl₃)
Q14Assertion (A): Copper sulfate conducts electricity in the molten state but not in the solid state.
Reason (R): Copper and sulfate ions are fixed in the lattice in molten state, while in solid state they can move freely.
Choose the correct option:
▾

Assertion (A): It is true. Copper sulfate is an ionic compound. In the molten state its ions are free to move, but in the solid state they are not.

Reason (R): It is false. It states the opposite. In the solid state, the ions are fixed in the lattice, and in the molten state they can move freely.

Answer
Option (iii): A is true, but R is false.
Q15The species ²⁷Al, ⁸⁰Br⁻ and ²⁰¹Hg²⁺ have 13, 35 and 80 protons, respectively. How many electrons and neutrons do they have?▾

Number of neutrons = mass number − number of protons.

Number of electrons = number of protons − charge on the species (a positive charge means electrons are lost, and a negative charge means electrons are gained).

SpeciesProtonsElectronsNeutrons
\({}^{27}_{13}\text{Al}\)1313 (neutral atom)27 − 13 = 14
\({}^{80}_{35}\text{Br}\)⁻3535 + 1 = 3680 − 35 = 45
\({}^{201}_{80}\text{Hg}\)²⁺8080 − 2 = 78201 − 80 = 121
Answer
Al: 13 electrons and 14 neutrons. Br⁻: 36 electrons and 45 neutrons. Hg²⁺: 78 electrons and 121 neutrons.
Section I

The Journey Beyond

4 Questions
JB1Design and perform an experiment to show and compare that water always contains hydrogen and oxygen in the same ratio, regardless of its source.▾

Aim: To show that water from different sources has hydrogen and oxygen in the same ratio.

Procedure (electrolysis of water):

1. Collect water samples from different sources, such as tap water, rainwater and river water.

2. Purify each sample by distillation.

3. Take a Hofmann voltameter (or two inverted test tubes over electrodes) and fill it with the water sample, adding a few drops of dilute sulfuric acid to make it conduct.

4. Pass an electric current through the water.

5. Collect hydrogen at the negative electrode (cathode) and oxygen at the positive electrode (anode).

6. Note the volumes of the two gases, and repeat with each water sample.

Expected observation: The volume of hydrogen is twice the volume of oxygen for every sample (2 : 1).

The mass ratio is then (2 × 2) : (1 × 32) = 4 : 32 = 1 : 8 for every sample.

Conclusion
Water from all sources contains hydrogen and oxygen in the same mass ratio, 1:8. This verifies the Law of Constant Proportions.
JB2Compare atoms and ions of any three elements. Show the number of electrons before and after ion formation using bar graphs.▾

Take sodium, magnesium and chlorine.

The number of electrons is counted before (atom) and after (ion) the formation of the ion.

ElementIon formedElectrons in atomElectrons in ion
Sodium (Z = 11)Na⁺1111 − 1 = 10
Magnesium (Z = 12)Mg²⁺1212 − 2 = 10
Chlorine (Z = 17)Cl⁻1717 + 1 = 18

Sodium and magnesium lose electrons (cations), so the bar for the ion is shorter.

Chlorine gains an electron (anion), so the bar for the ion is taller.

5 10 15 20 0 Na → Na⁺ 11 10 Mg → Mg²⁺ 12 10 Cl → Cl⁻ 17 18 Atom and its ion Number of electrons Atom (before) Ion (after) www.boundlessmaths.com
Number of electrons before (atom) and after (ion) ion formation for sodium, magnesium and chlorine
Answer
Na loses 1 electron (11 to 10), Mg loses 2 electrons (12 to 10), and Cl gains 1 electron (17 to 18), as shown in the bar graph.
JB3Make a card game with cations and anions. Possible ideas may include —
Pick cards from the pile or from open cards and match them with cards in your hand to form compounds. You may discard any unwanted cards.
Ask other players for cards and form compounds using the cards they already have.
▾

Making the cards: Make one card for each ion, showing its symbol and charge. Make 3 or 4 copies of each card.

Cation cardsAnion cards
Na⁺, K⁺, Li⁺, Ag⁺, NH₄⁺Cl⁻, Br⁻, OH⁻, NO₃⁻
Mg²⁺, Ca²⁺, Zn²⁺, Cu²⁺O²⁻, S²⁻, SO₄²⁻, CO₃²⁻
Al³⁺, Fe³⁺PO₄³⁻

Rules:

1. Deal 5 cards to each player and keep the rest as the pile.

2. On your turn, pick a card from the pile or from the open cards, or ask another player for a card.

3. Match cations and anions so that the total positive charge = the total negative charge, and write the formula of the compound.

4. Discard one unwanted card at the end of your turn.

5. The player who forms the most correct compounds (with correct formulae) wins.

Examples of correct matches:

Mg²⁺ + 2 Cl⁻ → MgCl₂

Al³⁺ + 3 OH⁻ → Al(OH)₃

2 Na⁺ + SO₄²⁻ → Na₂SO₄

2 Al³⁺ + 3 O²⁻ → Al₂O₃

Answer
The game helps to practise writing formulae by balancing positive and negative charges. Any game with these ideas is acceptable.
QC1Are there any chemical changes that do not obey the Law of Conservation of Mass?▾

No chemical change violates the Law of Conservation of Mass. It applies to every chemical reaction.

Sometimes it looks as if mass is lost, as in Activity 9.2 (set-up 1), but this happens because a gas escapes from an open system.

In a closed system, the mass of the reactants is always equal to the mass of the products.

In nuclear reactions (nuclear energy), a very small amount of mass changes into energy. But these are nuclear changes and not chemical changes.

Answer
No. In every chemical change, the total mass is conserved. Apparent differences are due to gases entering or leaving an open system.
💡 Chapter 9's core idea, in one line

Mass is conserved and elements combine in fixed ratios in every chemical reaction — and these two experimentally-verified laws are exactly why Dalton's picture of atoms simply rearranging, never being created or destroyed, works, and why atoms combine by sharing electrons (covalent bonds) or transferring them (ionic bonds) in the same fixed whole-number ratios every single time.

Extra Practice

The Practice Continues

7 Questions

Seven extra questions in the style of the textbook's own activities and examples, for independent practice once you've gone through everything above. Attempt each one on paper first, then tap to check.

EP13 g of carbon is burnt completely in oxygen to form 11 g of carbon dioxide.(i)Find the mass of oxygen that combined with the carbon.(ii)How much carbon dioxide will be formed when 6 g of carbon is burnt completely?▾

Given: mass of carbon = 3 g; mass of carbon dioxide = 11 g

(i)Mass of oxygen

By the Law of Conservation of Mass, mass of reactants = mass of products.

\[3 + \text{mass of oxygen} = 11\] \[\text{mass of oxygen} = 11 - 3 = 8\text{ g}\]
Ans.8 g
(ii)Carbon dioxide from 6 g of carbon

3 g of carbon gives 11 g of carbon dioxide.

So 6 g of carbon (twice as much) gives

\[\dfrac{11}{3} \times 6 = 22\text{ g}\]
Ans.22 g
EP2Sample A of water contains 2 g of hydrogen combined with 16 g of oxygen. Sample B of water contains 3 g of hydrogen combined with 24 g of oxygen. Do these samples obey the Law of Constant Proportions? Explain.▾

Ratio of hydrogen to oxygen in sample A = 2 : 16 = 1 : 8

Ratio of hydrogen to oxygen in sample B = 3 : 24 = 1 : 8

Both samples have hydrogen and oxygen in the same mass ratio, 1 : 8.

Answer
Yes. Both samples have the same ratio of 1:8, so they obey the Law of Constant Proportions. This also shows that water has a fixed composition irrespective of its source.
EP3Find the number of protons, neutrons and electrons in the ion ²⁷Al³⁺ (atomic number of aluminium = 13).▾

Given: atomic number \(Z = 13\), mass number \(A = 27\), charge = 3+

Number of protons = atomic number = 13.

Number of neutrons = mass number − atomic number = 27 − 13 = 14.

A neutral atom has 13 electrons. The ion has lost 3 electrons, so the number of electrons = 13 − 3 = 10.

Answer
The ion has 13 protons, 14 neutrons and 10 electrons.
EP4Find the formula unit mass of calcium chloride, CaCl₂. (Atomic masses: Ca = 40 u, Cl = 35.5 u)▾

Given: Ca = 40 u, Cl = 35.5 u

CaCl₂ has 1 calcium atom and 2 chlorine atoms.

\[\begin{aligned}\text{formula unit mass} &= 40 + (35.5 \times 2) \\ &= 40 + 71 \\ &= 111\text{ u}\end{aligned}\]
Answer
The formula unit mass of CaCl₂ is 111 u.
EP5Calcium phosphate is used in fertilisers. It is formed from the ions Ca²⁺ and PO₄³⁻.(i)Write its formula.(ii)Find its formula unit mass. (Ca = 40 u, P = 31 u, O = 16 u)▾
(i)Formula

Charges: Ca is 2+ and PO₄ is 3–.

Criss-cross: Ca has 3 and PO₄ has 2.

Brackets are needed for PO₄ because there are two of them.

Ans.Ca₃(PO₄)₂
(ii)Formula unit mass

Ca₃(PO₄)₂ has 3 Ca atoms and 2 PO₄ groups.

Mass of one PO₄ group = 31 + (16 × 4) = 95 u.

\[\text{formula unit mass} = (40 \times 3) + (95 \times 2)\] \[= 120 + 190 = 310\text{ u}\]
Ans.310 u
EP610 g of hydrogen and 40 g of oxygen are mixed and made to react completely to form water. Hydrogen and oxygen combine in the mass ratio 1:8.(i)Which reactant is in excess, and by how much?(ii)What mass of water is formed?▾
(i)Reactant in excess

1 g of hydrogen needs 8 g of oxygen.

So 40 g of oxygen needs

\[\dfrac{40}{8} = 5\text{ g of hydrogen}\]

Hydrogen available = 10 g, so hydrogen left over = 10 − 5 = 5 g.

Ans.Hydrogen is in excess by 5 g
(ii)Mass of water

The water formed uses all the oxygen (40 g) and 5 g of hydrogen.

\[\text{mass of water} = 5 + 40 = 45\text{ g}\]
Ans.45 g
EP7Element P has atomic number 12 and element Q has atomic number 17. They combine to form a compound X.(i)Write the electronic configurations of P and Q.(ii)Name the type of bond in X and write its formula.(iii)Find the formula unit mass of X. (P = 24 u, Q = 35.5 u)(iv)Will X conduct electricity in the solid state? Will its aqueous solution conduct electricity? Give reasons.▾
(i)Electronic configurations

P (Z = 12): K = 2, L = 8, M = 2.

Q (Z = 17): K = 2, L = 8, M = 7.

Ans.P: 2, 8, 2 and Q: 2, 8, 7
(ii)Bond and formula

P has 2 valence electrons and loses them to form P²⁺.

Q needs 1 electron and forms Q⁻.

Electrons are transferred, so the bond is ionic.

Criss-cross the charges: P₁Q₂.

Ans.Ionic bond; formula PQ₂ (MgCl₂)
(iii)Formula unit mass

PQ₂ has 1 P and 2 Q.

\[24 + (35.5 \times 2) = 24 + 71 = 95\text{ u}\]
Ans.95 u
(iv)Electrical conductivity

In the solid state, the ions are fixed in the lattice and cannot move, so X does not conduct.

In water, the ions become free to move, so the solution conducts electricity.

Ans.Solid: does not conduct. Aqueous solution: conducts
Common Questions

Frequently Asked Questions

Look at the number of electrons in the outermost shell. If there are 1, 2, or 3 electrons, the element tends to lose them, and valency equals that number. If there are 5, 6, or 7 electrons, the element tends to gain electrons to complete the octet, and valency equals 8 minus the number of outer electrons. Elements with a complete outer shell (8, or 2 for the first shell) have zero valency and don't readily form bonds.
An ionic bond forms when one atom completely transfers one or more electrons to another, creating oppositely charged ions that attract each other — this typically happens between a metal and a non-metal. A covalent bond forms when two atoms, usually both non-metals, share one or more pairs of electrons instead of transferring them, so that both atoms achieve a stable outer shell together.
The Law of Conservation of Mass (Lavoisier, 1789) states that mass is neither created nor destroyed in a chemical reaction — the total mass of reactants equals the total mass of products. The Law of Constant Proportions (Proust) states that a given compound always contains its constituent elements in the same fixed ratio by mass, regardless of its source or how it was prepared. Together, these two laws form the experimental basis of Dalton's Atomic Theory.
Write the symbols with their valencies, swap the valencies so each becomes the subscript of the other element, and divide by a common factor if there is one. Aluminium (3) and sulphate (2) give Al₂(SO₄)₃. Calcium (2) and chlorine (1) give CaCl₂. Magnesium (2) and oxygen (2) swap to Mg₂O₂, which reduces to MgO.
Ionic compounds such as NaCl do not exist as separate molecules; they form a repeating lattice of ions, so the smallest unit is a formula unit. Its mass is found the same way: NaCl = 23 + 35.5 = 58.5 u. Molecular mass is used for covalent substances that do exist as molecules, such as CO₂ = 12 + 2 × 16 = 44 u.
In water the ratio of hydrogen to oxygen by mass is always 1 : 8, whatever the source. So 9 g of water contains 1 g of hydrogen and 8 g of oxygen, and 18 g of water contains 2 g of hydrogen and 16 g of oxygen. Write the fixed ratio first, then scale both parts by the same factor.
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