Class 9 Science NCERT Solutions Chapter 8: Journey Inside the Atom | Boundless Maths
📗 CBSE 2026-27 Unit IV · Matter and Its Composition ✨ Free — No Sign-up 45 Questions

Chapter 8: Journey
Inside the Atom

Complete NCERT Solutions for Chapter 8 of the new Class 9 Science Exploration textbook (CBSE 2026-27) — every Think It Over, Pause & Ponder, Think as a Scientist, What If, Inline Question, Ready to Go Beyond, Revise Reflect Refine, and Quest Continues question on this one page, with full step-by-step working for every numerical.

This chapter traces the historical journey from Dalton's solid-sphere atom to Thomson's plum pudding model, Rutherford's nuclear model, and finally Bohr's model with defined electron shells — each revised because new experimental evidence demanded it. You'll also work through atomic number, mass number, isotopes, isobars, and electron distribution using the 2n² rule, all core, heavily-tested topics in CBSE Class 9 Science Chapter 8 exams.

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Overview

What Chapter 8 Is Really About

Journey Inside the Atom takes the atom apart, piece by piece — from Acharya Kanada's and Dalton's idea of an indivisible particle, through Thomson's plum pudding model, Rutherford's gold foil experiment and nuclear model, to Bohr's fixed energy shells. Along the way it introduces the electron, proton and neutron, and builds up to atomic number, mass number, isotopes and isobars. Every question is solved here, section by section, exactly as the textbook presents them, with full working for every numerical.

⚛️

From Dalton to Bohr

How each atomic model was built on — and eventually broke down against — new experimental evidence.

🔬

The Gold Foil Experiment

Why most alpha particles passed straight through gold foil, while a few bounced sharply back.

🧮

Atomic Number, Isotopes & Isobars

Working out protons, neutrons and electrons, and telling isotopes and isobars apart with numericals.

Quick Revision

Key Concepts & Formulae at a Glance

Subatomic particles

ParticleChargeMassLocation
Proton+11 uInside the nucleus
Neutron0 (neutral)1 uInside the nucleus
Electron−1Negligible (~1/1836 u)Orbiting the nucleus in shells

Key formulae

\[ \text{Atomic number}\ (Z) = \text{Number of protons} \] \[ \text{Mass number}\ (A) = \text{Number of protons} + \text{Number of neutrons} \] \[ \text{Number of neutrons} = A - Z \]

In a neutral atom, the number of electrons always equals the number of protons. Maximum electrons in a shell = \(2n^2\), where \(n\) is the shell number (K=1, L=2, M=3...) — so K holds up to 2, L up to 8, M up to 18.

Isotopes vs. isobars

PropertyIsotopesIsobars
Atomic number (Z)SameDifferent
Mass number (A)DifferentSame
ElementSame elementDifferent elements
Example¹H, ²H, ³H (protium, deuterium, tritium)¹⁴C and ¹⁴N

Rutherford's gold-foil experiment showed that an atom's mass and positive charge are concentrated in a tiny, dense nucleus, while most of the atom is empty space — leading to the nuclear model of the atom.

Section A

Think It Over (Chapter Opener)

3 Questions
T1Are atoms the smallest indivisible particles?

Answer: no. Although ancient thinkers (Acharya Kanada, Leucippus, Democritus) and later Dalton (1808) proposed atoms as the smallest indivisible units of matter, 19th and 20th century experiments proved otherwise. The discovery of electrons by J. J. Thomson (1897), the nucleus by Rutherford (1911), and neutrons by Chadwick (1932) showed that atoms are made of smaller subatomic particles: electrons, protons, and neutrons. The phenomenon of radioactivity also proved atoms are divisible. Today we know atoms consist of a nucleus containing protons and neutrons, with electrons orbiting outside.

T2Why do electrons not fall into the nucleus even though they are attracted to protons in it?

Answer: Rutherford's model could not explain this and was a key limitation. Niels Bohr resolved it in 1913 by proposing that electrons revolve in fixed circular paths called stationary states or shells (K, L, M, N…). In a stationary state, the electron has a definite constant energy and does not radiate or lose energy, even though it is moving. Therefore, it does not spiral inward into the nucleus. This is a postulate of Bohr's model — electrons can only exist in specific allowed orbits and nowhere in between.

Note

A more complete explanation came from quantum mechanics (studied in higher grades), which describes electrons as existing in probability "clouds" around the nucleus.

T3Why did scientists keep modifying atomic models?

Answer: scientists kept modifying atomic models because each new experiment revealed results that the existing model could not explain. This is how science progresses — through evidence-driven revision:

  • Dalton's model (1808): atom as indivisible particle. Could not explain why atoms emit radiation (radioactivity) or what they are made of.
  • Thomson's model (1897): plum pudding model — electrons embedded in a positive sphere. Could not explain the gold foil experiment results (large deflection of alpha particles).
  • Rutherford's model (1911): nuclear model — electrons orbit a dense nucleus. Could not explain why electrons don't lose energy and spiral into the nucleus (atomic stability).
  • Bohr's model (1913): fixed energy shells. Explained stability and many observations but still had limitations and was eventually replaced by the quantum mechanical model.
Note

The willingness to revise models when new evidence emerges is the hallmark of scientific thinking.

Section B

Pause and Ponder

18 Questions
P1Suppose you made your own 'atom' using clay for positive charge and beads for electrons. What happens if: (i) positive charge on clay is less than total negative charge of beads? (ii) the clay itself carries a bit of negative charge?

(i) The model would represent a negatively charged ion, not a neutral atom. For a neutral atom, the total positive charge must exactly equal the total negative charge. If the clay (positive) carries less charge than the total bead charge (negative), the model has a net negative charge — like an anion.

(ii) No, the model would no longer represent a neutral atom. If the clay carries negative charge, both components — clay and beads — would be negative, making the total model negatively charged. It would fail to represent the positive-negative balance required for neutrality. Thomson's model specifically requires the positive sphere to balance the negative electrons.

P2Could an orange or lemon (seeds in soft pulp) be a good comparison to Thomson's model? Where does it match and where does it fall short?

Where it matches: both have a soft, distributed medium (pulp = positive sphere) with small embedded particles (seeds = electrons) scattered throughout, just as Thomson proposed electrons are embedded in the positive charge distribution.

Where it falls short: (1) the seeds in a fruit are not evenly distributed — they cluster near the centre, whereas Thomson proposed electrons spread throughout; (2) seeds are neutral objects, but electrons carry specific negative charge; (3) the pulp of the fruit is not electrically charged; (4) the number of seeds has no electrical relationship to the pulp, whereas in Thomson's model the electron charge must exactly balance the positive charge.

P3Why did Thomson conclude that electrons are present in all atoms?

Answer: Thomson studied cathode rays in a cathode ray tube and found that (1) the rays were streams of negatively charged particles (electrons), and (2), crucially, the nature of cathode rays — their charge-to-mass ratio — was the same regardless of the material of the cathode used (iron, aluminium, copper, etc.) and regardless of the gas filled in the tube. Since identical particles were emitted from atoms of completely different elements under identical conditions, Thomson concluded that electrons must be a universal component present in every atom of every element — not specific to one material.

P4What do you think would happen if alpha particles were replaced with negatively charged particles in Rutherford's gold foil experiment?

Alpha particles are positively charged. If replaced with negatively charged particles:

  • Attracted to nucleus: instead of being repelled by the positively charged gold nuclei, negatively charged particles would be attracted toward them, bending toward the nucleus rather than away from it.
  • No back-scattering in the same way: negative particles would not bounce back due to electrostatic repulsion; instead they would curve toward and potentially be captured by gold nuclei.
  • Different deflection pattern: particles would curve inward rather than outward, and the experiment could not be used to establish the nuclear model in the same way.
Note

The key result of Rutherford's experiment (back-scattering) depended on electrostatic repulsion between like charges. With unlike charges, repulsion would become attraction and the experiment's logic would change completely.

P5Rutherford found that a few alpha particles bounced back sharply. How does this single surprising result completely rule out Thomson's plum pudding model?

Thomson's plum pudding model proposed that positive charge is spread uniformly throughout the atom like a diffuse cloud. In such a model, no small region of concentrated positive charge exists, so an alpha particle passing through would encounter only weak, distributed positive charge that could deflect it slightly at most — no point in the atom would be dense or strong enough to repel a fast, massive alpha particle backwards.

The back-scattering result completely rules this out because only a very small, extremely dense region of concentrated positive charge could exert a force strong enough to reverse the direction of a fast-moving, heavy, positively charged alpha particle. The very existence of even one bounced-back particle proves there must be a tiny, massive, positively charged nucleus — mathematically impossible under the Thomson model.

P6If you could ask Rutherford one question about his work, what would it be?

Answer: a strong scientific question would be: "Professor Rutherford, your experiment showed that the nucleus is extremely small and dense, but you could not explain why electrons don't spiral into it. Did you suspect at the time that the classical laws of physics might simply not apply inside the atom, or did you believe the answer would come from within classical mechanics?" This probes the conceptual leap from classical to quantum physics that Rutherford's work made necessary, and is the key unresolved question of his model.

Note

This question has no single "correct" answer — it is open-ended and should demonstrate scientific curiosity and critical thinking about the limitations of Rutherford's model.

P7Assertion (A): Rutherford concluded that most of the mass of an atom is concentrated in a small region at the centre called the nucleus. Reason (R): According to Thomson's model, electrons are embedded in a uniformly distributed positive charge sphere. Choose the correct option.

Correct answer: (ii) Both A and R are true, but R is not the correct explanation of A.

Assertion A is true — Rutherford did conclude from the gold foil experiment that most of an atom's mass and all its positive charge are concentrated in a small dense nucleus. Reason R is also true — Thomson's model does describe electrons embedded in a uniformly distributed positive sphere. However, R does not explain A: Rutherford's conclusion came from the gold foil scattering results (back-scattered alpha particles), not from Thomson's model — in fact, Rutherford's findings contradicted Thomson's model. The two statements are independently true but causally unrelated.

P8Imagine you are a scientist who has discovered a new element. Name this element after yourself and justify that the symbol you have chosen follows the IUPAC rules.

Example answer (student should use their own name): suppose the student's name is Arjun Sharma. The element could be named Arjunium (Aj). IUPAC rules followed: (1) first letter is capital — A is uppercase; (2) second letter is lowercase — j is lowercase; (3) symbol is derived from the English name of the element (Arjunium → Aj); (4) the symbol has two letters, which is standard.

Note

Any student name applied correctly following the rules is acceptable. IUPAC rules: first letter uppercase; second letter (if any) lowercase; symbol derived from the element name (English, Latin, or other language); symbol must be internationally unique.

P9What problems could arise if every scientist used different symbols for the same element?
  • Scientific papers and journals would be unreadable across different countries or languages — a formula like H₂O (water) might appear differently depending on the convention used.
  • Chemical equations, laboratory procedures, and safety data sheets could be misinterpreted, leading to dangerous mistakes in labs.
  • International trade in chemicals and pharmaceuticals would become error-prone — wrong substances could be supplied.
  • Periodic table organisation would be impossible — no standardised system for classifying elements.
  • Scientific databases, software, and instruments would be incompatible across nations.

Standardised IUPAC symbols solve this by creating one universally recognised symbol per element, transcending language barriers worldwide.

P10An atom with an atomic number of 26 has 56 nucleons. Find its number of electrons, protons, and neutrons.

Protons: atomic number (Z) = 26, so protons = 26. Electrons: atom is neutral, so electrons = protons = 26. Neutrons: mass number (A) = nucleons = 56, so neutrons = A − Z = 56 − 26 = 30.

Answer: Protons = 26, Electrons = 26, Neutrons = 30. This is Iron (Fe).

P11The nucleus of an atom contains 20 protons. If its mass number is 41, find the number of neutrons.
Neutrons = Mass number − Number of protons = 41 − 20 = 21

Answer: number of neutrons = 21. This element has Z = 20 (Calcium, Ca) with mass number 41.

P12An atom has 18 neutrons and an atomic number of 17. What is its mass number?
Mass number = Protons + Neutrons = 17 + 18 = 35

Answer: mass number = 35. This is Chlorine-35 (³⁵Cl).

P13An atom ²³A has 11 electrons. Find the number of neutrons in it.

Mass number A = 23. Since the atom is neutral: protons = electrons = 11.

Neutrons = Mass number − Protons = 23 − 11 = 12

Answer: number of neutrons = 12. This is Sodium (Na), atomic number 11, mass number 23.

P14Identify the number of electrons in the outermost shell of: (i) ¹²₆C (ii) ¹⁹₉F (iii) ²⁸₁₄Si
  • (i) Carbon (¹²₆C): Z = 6. Configuration: K=2, L=4. Outermost shell (L) has 4 electrons.
  • (ii) Fluorine (¹⁹₉F): Z = 9. Configuration: K=2, L=7. Outermost shell (L) has 7 electrons.
  • (iii) Silicon (²⁸₁₄Si): Z = 14. Configuration: K=2, L=8, M=4. Outermost shell (M) has 4 electrons.
P15Write the electronic configuration of elements with atomic numbers 12, 16, and 18.
  • Z = 12 (Magnesium, Mg): K=2, L=8, M=2. Configuration: 2, 8, 2
  • Z = 16 (Sulfur, S): K=2, L=8, M=6. Configuration: 2, 8, 6
  • Z = 18 (Argon, Ar): K=2, L=8, M=8. Configuration: 2, 8, 8
P16Riddle: I am an atom with a mass number of 23 and 11 protons. I am a soft metal and react vigorously with water. Who am I and how many neutrons do I have?

Answer: Sodium (Na). Z = 11 (protons = 11, electrons = 11). Mass number = 23.

Neutrons = Mass number − Protons = 23 − 11 = 12

Sodium has 12 neutrons. Its electronic configuration is 2, 8, 1. It is a soft silvery metal that reacts vigorously with water, releasing hydrogen gas and forming sodium hydroxide (NaOH).

P17Two different atoms both have 11 protons — one has 12 neutrons, the other has 13 neutrons. How do their atomic numbers and mass numbers compare? Are they the same element or different elements?

Atomic numbers: both atoms have 11 protons, so both have atomic number (Z) = 11 — they are the same element, Sodium (Na).

Mass numbers: atom 1: A = 11 + 12 = 23. Atom 2: A = 11 + 13 = 24.

Answer: they are isotopes of sodium: Na-23 (more abundant, stable) and Na-24 (radioactive). Same element (same Z), different mass numbers. Same chemical properties, different physical properties.

P18Bromine has two isotopes: ⁷⁹Br (49.7%) and ⁸¹Br (50.3%). Calculate the average atomic mass.
Average atomic mass \(= (79 \times 0.497) + (81 \times 0.503) = 39.263 + 40.743 = 79.906\,\text{u} \approx 80\,\text{u}\)

Answer: the average atomic mass of bromine is approximately 79.9 u (≈ 80 u). This is the weighted average, reflecting that both isotopes occur in nearly equal proportions (unlike chlorine, where 75:25 gives 35.5 u).

Section C

Think as a Scientist

1 Question
TAS1Predict what observations you would expect if the gold foil in Rutherford's experiment were made thicker. Draw a simple diagram.

With a thicker gold foil, there are more layers of gold atoms, so a beam of alpha particles encounters more nuclei in its path. Predicted observations:

  • More alpha particles deflected: the probability of an alpha particle passing close to a nucleus increases with foil thickness, so a greater fraction of alpha particles will be deflected at various angles.
  • More alpha particles bounced back: more opportunities to encounter a nucleus head-on, so the proportion bouncing back at ~180° increases.
  • Fewer particles passing straight through: fewer alpha particles will pass entirely undeflected, since the chance of passing through the mostly empty space without encountering a nucleus decreases as layers increase.
  • Broader scattering pattern: the overall spread of deflections increases.
Thin foil 1 atom layer(s) thick
Thick foil 4 atom layer(s) thick
Comparing scattering patterns: thin foil vs thick foil
Note

Comparison: Thin foil → most straight through, few deflected. Thick foil → fewer straight through, many more deflected, more bounced back.

Section D

What If

1 Question
WI1What if an atom had no empty space? How would this have affected the size of various objects?

Atoms are mostly empty space — Rutherford showed the nucleus is about 10⁵ times smaller than the atom. If atoms had no empty space (i.e., the nucleus filled the entire atom):

  • Objects would be incredibly smaller: the volume of matter would shrink by a factor of approximately (10⁵)³ = 10¹⁵. A human body (volume ~0.07 m³) would shrink to about 7 × 10⁻¹⁷ m³ — smaller than a single atomic nucleus.
  • The universe would be unimaginably compact: the entire Earth's mass packed without empty space would form an object about 10 km in diameter — similar to a neutron star, which is exactly what happens when stellar gravity crushes electrons into protons, eliminating the empty space.
  • Chemistry and life would be impossible: electrons would have no room to orbit, no shells would exist, no chemical bonds could form, and therefore no molecules, no biology, no life.
  • Objects would not be "solid" in the usual sense: the apparent solidity of matter comes from electromagnetic repulsion between electron clouds, not from atoms being packed. Without empty space, matter would behave completely differently.
Note

Neutron stars are real examples of matter with very little empty space — they have the mass of the Sun compressed into a radius of ~10 km, with densities of ~10¹⁷ kg/m³.

Section E

Inline Questions from the Text

5 Questions
IN1From Fig. 8.10: How many neutrons and protons are present in a lithium atom, and what is its atomic number?
3p 4n Lithium (Li) — K=2, L=1

From Table 8.4: Lithium (Li) has atomic number 3, 3 protons, 4 neutrons, and 3 electrons. Electronic configuration: K=2, L=1.

Atomic number (Z) = 3  |  Protons = 3  |  Neutrons = 4  |  Mass number = 3 + 4 = 7
IN2How many electrons do each of the three hydrogen isotopes — protium, deuterium, tritium — have?

All three are isotopes of hydrogen — same atomic number (Z = 1), so same number of protons = 1, and since atoms are neutral, same number of electrons = 1.

  • Protium (¹H): 1 electron, 1 proton, 0 neutrons
  • Deuterium (²H): 1 electron, 1 proton, 1 neutron
  • Tritium (³H): 1 electron, 1 proton, 2 neutrons
Note

Isotopes have the same atomic number (same electrons, same protons) but different numbers of neutrons.

IN3In NH₃ (ammonia) and MgCl₂ (magnesium chloride), what are the combining capacities of nitrogen and magnesium respectively?

Nitrogen in NH₃: nitrogen combines with 3 hydrogen atoms. Combining capacity of nitrogen = 3.

Magnesium in MgCl₂: magnesium combines with 2 chlorine atoms. Combining capacity of magnesium = 2.

Note

Combining capacity (valency) is expressed in terms of the number of hydrogen or chlorine atoms that combine with one atom of the element.

IN4What happens to atoms that already have 8 electrons in their outermost shell? Will they still try to lose or gain electrons?

Answer: no. Atoms with 8 electrons in the outermost shell (a complete octet) are already in a stable, lowest energy configuration. They have no tendency to gain, lose, or share electrons. These are the noble gases (He, Ne, Ar, Kr, Xe, Rn — except helium, which has 2 electrons filling its only shell). Noble gases are largely unreactive (inert) precisely because they already have a complete outer shell. This is why they exist as monoatomic gases and do not form compounds under normal conditions.

IN5Examine Table 8.4 — add a column for the common valency of each element.

For each element, count the valence electrons and apply the rule — fewer than 4 valence electrons: lose that many electrons (valency = valence electrons); more than 4: gain electrons to complete the octet (valency = 8 − valence electrons); exactly 4: share (valency = 4). For example, Li (1 valence electron) has valency 1; O (6 valence electrons) has valency 2; C (4 valence electrons) has valency 4; F (7 valence electrons) has valency 1; Ne (8 valence electrons, complete octet) has valency 0.

Section F

Ready to Go Beyond

1 Question
RTG1How many atoms would be needed to make a sheet of paper that is 0.1 mm thick?

Given: diameter of one atom ≈ 10⁻¹⁰ m. Thickness of paper = 0.1 mm = 10⁻⁴ m.

Number of atoms \(= \dfrac{\text{Thickness of paper}}{\text{Diameter of one atom}} = \dfrac{10^{-4}\,\text{m}}{10^{-10}\,\text{m}} = 10^6 = 1{,}000{,}000\)

Answer: about one million atoms stacked together are needed to make a sheet of paper 0.1 mm thick. This illustrates how unimaginably tiny atoms are — a seemingly simple everyday object is actually a vast assembly of microscopic building blocks.

Section G

Revise, Reflect, Refine (Back Exercise)

15 Questions
Q1Choose the correct options and explain reasons for the correct and incorrect options regarding Rutherford's gold foil experiment: (i)–(iv)
  • (i) INCORRECT: the experiment did NOT show existence of neutrons. Neutrons have no charge and were not detected in this experiment. Chadwick discovered neutrons in 1932 by a separate experiment. The gold foil experiment only involved alpha particle scattering.
  • (ii) CORRECT: the results disproved the plum pudding model and led to the nuclear model. The large deflections and back-scattering could only be explained by a tiny, dense, positively charged nucleus — incompatible with Thomson's uniformly distributed positive charge.
  • (iii) CORRECT: large deflection of a few alpha particles showed mass and positive charge are concentrated in a tiny centre (nucleus). If mass were spread throughout, no single encounter could reverse a fast, heavy alpha particle.
  • (iv) INCORRECT: the deflection pattern showed the existence of a dense nucleus, not the movement of electrons. Electron behaviour cannot be inferred from alpha particle scattering, since electrons are ~7,000 times lighter than alpha particles and would be negligibly affected.
Q2Which statements are correct or incorrect according to Bohr's atomic model? Give a reason for each.
  • (i) INCORRECT: Bohr's model specifically states electrons in fixed orbits do NOT lose energy. This was the key innovation — in stationary states, energy is constant. Losing energy and spiralling was the problem with Rutherford's model that Bohr solved.
  • (ii) INCORRECT: electrons cannot exist anywhere — Bohr stated electrons can only occupy specific allowed orbits (shells) with fixed energies. They cannot have arbitrary positions or energies.
  • (iii) CORRECT: this is exactly Bohr's postulate — electrons revolve in fixed-energy shells (stationary states) without losing energy.
  • (iv) INCORRECT: electrons cannot exist between energy levels. Bohr's model explicitly states electrons can only be in allowed shells (K, L, M, N…). They can jump between shells by absorbing or releasing energy, but cannot occupy the space between them.
Q3X has 18 protons, 19 neutrons. Y has 17 protons, 18 neutrons. Z has 17 protons, 20 neutrons. Explain the relation between (i) Y and Z, (ii) Z and X.

Mass numbers: X: 18+19=37, Y: 17+18=35, Z: 17+20=37

(i) Y and Z — isotopes: both Y and Z have the same atomic number (17) — they are both chlorine. But Y has mass number 35 and Z has mass number 37. Same element, different mass numbers → they are isotopes (³⁵Cl and ³⁷Cl).

(ii) Z and X — isobars: Z has mass number 37 (Z=17, Chlorine) and X has mass number 37 (Z=18, Argon). Same mass number but different atomic numbers → they are isobars.

Q4What conclusion did Rutherford draw about the atom's positively charged part based on alpha particles that bounced back or were deflected at large angles?

From the back-scattering and large-angle deflection of a small fraction of alpha particles, Rutherford concluded:

  • Concentration: the positive charge is not spread throughout the atom but is concentrated in an extremely small, dense region at the centre, which he named the nucleus.
  • Tiny size: since only a very few particles were deflected (about 1 in 20,000 hit the nucleus), the nucleus must be extremely small — about 10⁵ times smaller than the atom itself (nucleus ≈ 10⁻¹⁵ m, atom ≈ 10⁻¹⁰ m).
  • High density and mass: the nucleus contains most of the mass of the atom concentrated in this tiny volume, making it extraordinarily dense.
  • All positive charge: the large repulsive force on the alpha particle (positive) indicated the nucleus carries all the positive charge of the atom.
  • Mostly empty space: since most alpha particles passed straight through, the atom must be mostly empty space — electrons orbit far from the nucleus.
Q5Arrange the following statements in correct chronological order showing how atomic models evolved: (i) Bohr (ii) Thomson (iii) Rutherford (iv) Dalton

Correct chronological order: (iv) → (ii) → (iii) → (i)

  • (iv) Dalton (1808): atoms described as indivisible particles, fundamental building blocks of matter. All atoms of an element are identical. Based on laws of chemical combination.
  • (ii) Thomson (1897): discovered electrons — the first subatomic particle. Proposed the plum pudding model: electrons embedded in a uniformly distributed positive sphere. First model with internal structure.
  • (iii) Rutherford (1911): gold foil experiment. Disproved Thomson's model. Proposed the nuclear model — dense positive nucleus at the centre, electrons orbiting it, mostly empty space.
  • (i) Bohr (1913): solved the stability problem. Proposed that electrons move in fixed energy shells (stationary states) without losing energy. Shells named K, L, M, N. Could explain many experimental observations.
Note

After Bohr: the quantum mechanical model was proposed (electrons exist as probability clouds, not fixed paths). Still being refined today.

Q6Electrons move around the nucleus in orbits. Why do they not fly away from the atom? Explain what keeps them attracted to the nucleus.

Electrons do not fly away because of the electrostatic (Coulomb) force of attraction between the negatively charged electrons and the positively charged nucleus (protons). Opposite charges attract according to the fundamental law of electrostatics.

  • Electrostatic attraction: the negative electron is pulled toward the positive nucleus by Coulomb's law. This inward force acts as the centripetal force keeping the electron in orbit.
  • Balance of forces: in Rutherford's and Bohr's models, the centripetal force needed for circular motion equals the electrostatic attractive force. The electron's orbital speed is exactly right for this balance at each shell radius.
  • Bohr's shells: in Bohr's model, electrons can only exist at specific radii (energy levels) where this balance is maintained. They cannot "escape" the atom unless given enough energy to overcome the electrostatic attraction (ionisation energy).
Q7Assertion (A): The discovery of subatomic particles helped in understanding the atomic structure. Reason (R): The number of electrons is equal to the number of protons in an atom. Choose the correct option.

Correct answer: (ii) Both A and R are true, but R is not the correct explanation of A.

Assertion A is true — discovering electrons (Thomson, 1897), protons (Rutherford), and neutrons (Chadwick, 1932) was essential to understanding atomic structure — each discovery refined the atomic model. Reason R is also true — in a neutral atom, electrons = protons (equal opposite charges give neutrality). However, R does not explain A. The equality of electrons and protons is a property of neutral atoms derived from the discoveries, not the reason why those discoveries aided understanding.

Q8Magnesium: mass number 24, atomic number 12. Determine (i) protons, (ii) neutrons, (iii) electrons, and illustrate the electron arrangement.

(i) Protons: atomic number (Z) = 12, so protons = 12. (ii) Neutrons: Neutrons = Mass number − Protons = 24 − 12 = 12. (iii) Electrons: neutral atom, so electrons = protons = 12.

Electronic configuration (2, 8, 2): K-shell = 2, L-shell = 8, M-shell = 2.

Diagram: draw 3 concentric circles around a nucleus marked "+12". Place 2 electrons on the K-shell (innermost), 8 on the L-shell (middle), 2 on the M-shell (outermost). The M-shell with 2 electrons is the valence shell → valency of Mg = 2 (loses 2 electrons).

Q9Find for each of the four elements (a)(b)(c)(d) in Fig. 8.17: name, symbol, total electrons, valence electrons, valency, protons, atomic number.
2p 2n (a) Helium (He)
5p 6n (b) Boron (B)
15p 16n (c) Phosphorus (P)
12p 12n (d) Magnesium (Mg)

Read each diagram by counting the electrons in each shell, then work out identity and valency:

  • (a) 2 electrons, single shell: Helium (He), Z=2, protons=2, valence electrons=2 (full first shell), valency = 0 (inert).
  • (b) 2, 3 electrons (2 shells): Boron (B), Z=5, protons=5, valence electrons=3, valency = 3 (loses 3).
  • (c) 2, 8, 5 electrons (3 shells): Phosphorus (P), Z=15, protons=15, valence electrons=5, valency = 3 (gains 3 to complete octet).
  • (d) 2, 8, 2 electrons (3 shells): Magnesium (Mg), Z=12, protons=12, valence electrons=2, valency = 2 (loses 2).
Note

Valency: He has a full first shell (2 electrons) → inert, valency 0. B loses 3 → valency 3. P gains 3 → valency 3. Mg loses 2 → valency 2.

Q10Both Rutherford's and Bohr's models have electrons orbiting the nucleus. Why did Rutherford's model fail to explain atomic stability while Bohr's model succeeded?

Rutherford's failure: in classical physics (which Rutherford used), a charged particle moving in a circular path continuously accelerates (changes direction). An accelerating charged particle must radiate electromagnetic energy. So an orbiting electron should continuously lose energy, spiral inward, and collapse into the nucleus in a fraction of a second (~10⁻⁸ s). Rutherford's model had no mechanism to prevent this, so it predicted atoms should be unstable — contradicting observable reality.

Bohr's solution: Bohr introduced a radical new postulate — electrons in certain specific circular orbits (stationary states) do NOT radiate energy. In these allowed orbits, the electron's energy remains constant despite its motion. This was not explained by classical physics — it was a new quantum rule. Electrons can only jump between these fixed orbits by absorbing or emitting a specific quantum of energy equal to the energy difference between levels. Since electrons can only exist in these fixed states (not spiral continuously), atoms are stable.

Q11An atom ⁷⁰X has 31 electrons. How many neutrons are there in its nucleus?

Mass number (A) = 70. Since the atom is neutral: protons = electrons = 31.

Neutrons = A − protons = 70 − 31 = 39

Answer: neutrons = 39. This atom is Gallium (Ga), atomic number 31, mass number 70.

Q12An atom has 79 protons and a mass number of 197. Calculate (i) number of neutrons, (ii) number of electrons.

(i) Neutrons: Neutrons = Mass number − Protons = 197 − 79 = 118. (ii) Electrons: neutral atom, so electrons = protons = 79.

Answer: neutrons = 118, electrons = 79. This is Gold (Au), atomic number 79.

Q13Complete Table 8.5 (atomic number, mass number, number of neutrons, protons, electrons, name of the element for five rows).

Working:

  • Row 1: A = Z + n = 5+6 = 11. Protons = electrons = Z = 5. Element with Z=5 = Boron.
  • Row 2: Z = A − n = 14−7 = 7, electrons = 7 (given). Element = Nitrogen.
  • Row 3: Z = protons = 12, n = A−Z = 24−12 = 12. Element = Magnesium.
  • Row 4: Z=15, n=16, A=15+16=31. Element = Phosphorus.
  • Row 5: A=1, n=0, Z=1. Element = Hydrogen.
Q14Element X has mass number 35 and contains 18 neutrons. Answer (i)–(vii).

(i) Protons and electrons: Protons = Mass number − Neutrons = 35 − 18 = 17. Neutral atom → electrons = 17.

(ii) Atomic number: Z = number of protons = 17

(iii) Identify element X: Z = 17 → Chlorine (Cl)

(iv) Electronic configuration: Z = 17: K=2, L=8, M=7. Configuration: 2, 8, 7

(v) Valence electrons: outermost shell (M) has 7 electrons → 7 valence electrons

(vi) Mass number if 2 neutrons added: new neutrons = 18+2 = 20. New mass number = 17+20 = 37

(vii) Relation of X with the new atom: both have Z=17 (Chlorine) but different mass numbers (35 and 37) — they are isotopes, ³⁵Cl and ³⁷Cl, the two naturally occurring isotopes of chlorine.

Q15Atom has 12 protons and 12 neutrons. Electrons replaced by hypothetical particles with same charge but 500× heavier. Effect on: (i) atomic number, (ii) atomic mass, (iii) mass number, (iv) overall charge.

(i) Atomic number: atomic number = number of protons = 12. The hypothetical particles replace electrons (not protons), so the number of protons is unchanged. Atomic number remains 12.

(ii) Atomic mass: atomic mass includes protons + neutrons + electrons (though electrons are negligible normally). With 12 hypothetical particles each 500× heavier than an electron: added mass = 12 × 500 × electron mass ≈ 12 × 500 × 9.1×10⁻³¹ kg ≈ 5.46×10⁻²⁷ kg, which is comparable to a proton's mass (~1.67×10⁻²⁷ kg). Atomic mass increases noticeably — roughly by about 3–4 u compared to the original.

(iii) Mass number: mass number = total nucleons (protons + neutrons in the nucleus) = 12+12 = 24. Mass number is defined as nucleons only — the hypothetical particles are not nucleons. Mass number stays 24.

(iv) Overall charge: the hypothetical particles have the same charge as electrons (−1 each), and there are 12 of them, same as 12 protons (+1 each). The charges still balance → overall charge = 0. The atom remains electrically neutral.

Section H

The Quest Continues

1 Question
QC1Is it possible to completely understand everything that happens inside an atom?

This is one of the deepest questions in science, and the honest answer is: not yet, and possibly never completely. Here is why:

  • Quantum uncertainty: Heisenberg's Uncertainty Principle (higher grades) states that it is fundamentally impossible to know both the exact position and exact momentum of an electron simultaneously. This is not a limitation of instruments — it is a property of nature. So we can never know exactly what happens to every particle inside an atom at every instant.
  • Ongoing discoveries: even protons and neutrons are not fundamental — they are made of quarks, held by gluons (the strong nuclear force). Whether quarks have sub-structure is still being investigated at particle accelerators like CERN.
  • Quantum mechanics is probabilistic: the quantum mechanical model describes electrons as probability distributions (electron clouds), not definite paths. We can predict probabilities but not certainties of where electrons are.
  • New phenomena: phenomena like quantum entanglement, superposition, and particle-wave duality challenge classical understanding and are still not fully interpreted.

Conclusion: we have an extraordinarily powerful and accurate model (quantum mechanics), but complete understanding of everything inside an atom may be fundamentally limited by the nature of quantum reality itself. The journey of discovery continues — and that is what makes physics exciting.

💡 Chapter 8's core idea, in one line

Each atomic model — Dalton's indivisible sphere, Thomson's plum pudding, Rutherford's tiny nucleus, Bohr's fixed energy shells — was built to explain what the previous model could not, and the atom's true structure of protons, neutrons and electrons, arranged as atomic number, mass number, isotopes and isobars, is the product of that century-long chain of revision.

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Common Questions

Frequently Asked Questions

An atom is electrically neutral because it contains equal numbers of protons (positive charge) and electrons (negative charge), while neutrons carry no charge at all. The positive charge of the protons in the nucleus exactly balances the negative charge of the surrounding electrons, so the atom as a whole has zero net charge, even though it's built entirely from charged (and one neutral) particles.
Atomic number (Z) is simply the number of protons in an atom's nucleus, and it defines which element the atom is. Mass number (A) is the total number of protons and neutrons combined. Since the number of neutrons can vary between atoms of the same element (giving isotopes), two atoms can share the same atomic number but have different mass numbers.
Chemical properties are determined almost entirely by the number and arrangement of electrons around an atom, especially the outermost (valence) electrons — and isotopes of the same element have identical electron configurations, since they share the same atomic number. The extra neutrons in a heavier isotope add mass but don't change how the atom bonds or reacts, so isotopes behave chemically the same, even though their physical properties like mass and density can differ.
This was Rutherford's key discovery from the gold foil experiment: most alpha particles passed straight through the gold foil undeflected, showing that atoms are mostly empty space, while a small number bounced back sharply, revealing that all of the atom's positive charge and almost all of its mass is concentrated in an extremely tiny, dense central nucleus. The electrons occupy a comparatively vast region of space around this nucleus, which is why atoms — despite feeling solid — are overwhelmingly empty at the subatomic scale.
Each atomic model — Dalton's, Thomson's, Rutherford's, and Bohr's — was revised because new experimental evidence revealed results the older model could not explain, such as the discovery of electrons, the gold foil scattering experiment, and the question of why atoms are stable. This step-by-step revision in light of new evidence is a hallmark of how science progresses.
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