Class 9 Science Chapter 5 Mixtures NCERT Solutions | Boundless Maths
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Class 9 Science Chapter 5:
Exploring Mixtures and their Separation

NCERT Class 9 Science Chapter 5 question answers for Exploring Mixtures and their Separation (CBSE 2026-27), with every Think It Over, Activity, Pause & Ponder, Worked Example, Revise Reflect Refine and Journey Beyond question solved step by step. Use it alongside your Class 9 Science chapter 5 notes to check each answer and numerical.

This chapter returns to chemistry and sorts every mixture you meet into true solutions, colloids and suspensions, then builds the toolkit for separating them. These Class 9 Science Chapter 5 Exploring Mixtures and their Separation NCERT solutions cover the Tyndall effect, % m/m, % m/v and % v/v concentration numericals, solubility curves, chromatography, distillation and the separating funnel, with every numerical worked step by step.

Last updated 20 October 2026 · Reviewed by Suchita Arora, 13+ years teaching CBSE Maths & Science

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Overview

What Chapter 5 Is Really About

Exploring Mixtures and their Separation classifies mixtures — solutions, suspensions and colloids — by particle size and behaviour, including the Tyndall effect that tells them apart. It shows how to express concentration (% m/m, % m/v, % v/v), how solubility changes with temperature and drives crystallisation, and the full toolkit of separation techniques: evaporation, distillation, paper chromatography, the separating funnel, sublimation and centrifugation. Every question is solved here, section by section, as complete Class 9 Science Chapter 5 NCERT solutions with answers.

🧪

Solutions, Suspensions & Colloids

Particle size, settling behaviour, and the Tyndall effect — why milk scatters light but salt water doesn't.

🔢

Concentration & Solubility

% m/m, % m/v and % v/v calculations, plus how solubility curves predict how much solid crystallizes on cooling.

⚗️

Separation Techniques

Choosing the right method — distillation, chromatography, sublimation, or centrifugation — based on what the mixture actually is.

Quick Revision

Key Concepts & Formulae at a Glance

Types of mixtures

PropertySolutionColloidSuspension
Particle size< 1 nm1 – 1000 nm> 1000 nm
AppearanceClear, transparentOften clear or translucentOpaque, cloudy
SettlingNoNoYes (over time)
Tyndall effectNoYesYes
FiltrationPasses throughPasses throughRetained by filter
ExamplesSalt/water, brassMilk, blood, fogSand/water, muddy water

Key formulae

\[ \%\,m/m = \dfrac{\text{Mass of solute}}{\text{Mass of solution}}\times100 \] \[ \%\,m/v = \dfrac{\text{Mass of solute}}{\text{Volume of solution}}\times100 \] \[ \%\,v/v = \dfrac{\text{Volume of solute}}{\text{Volume of solution}}\times100 \]

Separation methods summary

MethodType of mixturePrincipleExample
CrystallizationHomogeneous (solid in liquid)Solubility decreases on coolingCuSO₄ from water, salt from brine
DistillationMiscible liquids or liquid + solidDifference in boiling points (≥25°C)Acetone-water, water from salt
Paper chromatographyHomogeneous (mixed dyes etc.)Different rates of movement in solventInk dyes, flower pigments
Separating funnelImmiscible liquidsDifference in densityOil and water, mustard oil
SublimationSolid + non-sublimable solidOne solid sublimes, the other doesn'tCamphor + sand, naphthalene + salt
CentrifugationSuspension/colloidCentrifugal force separates by densityBlood components, clay from water
CoagulationSuspension (fine particles)Coagulant makes particles clumpAlum + muddy water, cheese making
Section A

Think It Over (Chapter Opener)

3 Questions
Q1Why do suspended particles settle in muddy water over time but not in milk?▾

Muddy water is a suspension. Its particles are very large (more than 1000 nm) and heavy.

Gravity pulls these large particles down, so they settle at the bottom with time.

Milk is a colloid. Its particles are much smaller (1 – 1000 nm) and are spread evenly through the liquid.

These small particles do not settle over time.

Answer
The particles of muddy water are large and heavy, so they settle. The particles of milk are much smaller, so they stay dispersed.
Q2How is evaporation different from boiling?▾
EvaporationBoiling
Takes place at any temperatureTakes place only at the boiling point
Takes place only at the surface of the liquidTakes place throughout the liquid
Slow process. No bubbles are formedFast process. Bubbles are formed
Causes cooling of the remaining liquidHeat has to be supplied continuously
Answer
Evaporation is a slow surface process at any temperature. Boiling is a fast process in the whole liquid at its boiling point.
Q3Why do you see bright rays of sunlight when it passes through small gaps between the leaves of a dense tree?▾

The air contains tiny particles of dust, smoke and water droplets.

When sunlight passes through the small gaps, these particles scatter (spread) the light in all directions.

The scattered light enters our eyes, so the path of the light beam becomes visible as bright rays.

This scattering of light by particles is the Tyndall effect.

Answer
Dust and water droplets in the air scatter the sunlight (Tyndall effect), so the path of the light is visible.
Section B

Activities 5.1 – 5.9

9 Questions
5.1Activity 5.1: Let us experiment — Group activity. Divide the class into three groups — A, B and C. Each group prepares a mixture in a colourless, transparent glass tumbler or a 100 mL beaker by following these steps:1.Group A: Add one spatula of common salt to 50 mL of water in a beaker and stir it well. Label it A.2.Group B: Add one spatula of chalk powder to 50 mL of water in a beaker and stir it well. Label it B.3.Group C: Add a few drops of milk to 50 mL of water in a beaker and stir it well. Label it C.4.Are the particles visible in each mixture? Record your observations.5.Direct the light from a laser pointer through the beakers containing the mixtures (Fig. 5.3) and observe it from the side of the beaker in a direction perpendicular to the laser beam. Record your observations.6.Predict what you would observe in each of the beakers if you leave them undisturbed for a few minutes.7.Set up a filtration apparatus and filter each mixture separately. Is there any residue left on the filter paper?8.Based on your observations, do you think these are the same types of mixtures or are they different?▾
Laser beam passing through a beaker of salt water: the beam is not visible in the liquid
Laser beam passing through chalk powder in water: the beam is clearly visible
Laser beam passing through milk and water: the beam is clearly visible
Fig. 5.3 — Passing laser light through various mixtures: (a) salt and water, (b) chalk powder and water, (c) milk and water
StepA: salt + waterB: chalk + waterC: milk + water
4. Particles visible?No. Clear and transparentYes. Cloudy, particles can be seenNo. Looks uniform (milky)
5. Laser beamPath of the beam is not visiblePath of the beam is visiblePath of the beam is visible
6. On standingNothing settlesChalk particles settle at the bottomNothing settles
7. FiltrationNo residue on the filter paperWhite residue on the filter paperNo residue. Milk passes through

Step 8: the three mixtures are different types of mixtures.

A is a true solution, B is a suspension and C is a colloid.

Conclusion
Mixture A is a solution, B is a suspension and C is a colloid. They differ in particle size, settling, scattering of light and filtration.
5.2Activity 5.2: Let us represent solubility graphically. Consider water as the solvent, and compounds ‘A’ and ‘B’ as the solutes. Each substance has a different solubility. A graph of solubility versus temperature is called a solubility curve. The solubility curves for ‘A’ and ‘B’ as solutes are shown in Fig. 5.6. The x-axis shows temperature (°C), whereas the y-axis indicates the solubility of the solute in grams per 100 g of water. Based on the information from the above graph, predict which of the two compounds, ‘A’ or ‘B’, will dissolve more in a given amount of water at a given temperature? Observe Fig. 5.6 and fill in the blanks of the following statements:(i)The solubility of compound ‘A’ in water at 20 °C is ______ (less than/more than/similar to) its solubility at 60 °C.(ii)The solubility of compound ‘B’ at 20 °C is ______ (less than/more than/similar to) its solubility at 60 °C.(iii)The solubility of ______ increases more than that of ______ with an increase in the temperature.▾
0 20 40 60 80 100 200 300 400 Temperature (°C) Solubility (g/100 g) Compound B Compound A www.boundlessmaths.com
Fig. 5.6 (redrawn): solubility curves of compounds ‘A’ and ‘B’ in water. B = 241 g at 40 °C and 287 g at 60 °C (given); other values are read approximately

Prediction: the curve of B lies far above the curve of A at every temperature. So compound B dissolves more than A in a given amount of water at any given temperature.

(i)Compound A

A at 20 °C is about 34 g and at 60 °C is about 52 g per 100 g of water.

Ans.less than
(ii)Compound B

B at 20 °C is about 208 g and at 60 °C is 287 g per 100 g of water.

Ans.less than
(iii)Comparing the rise

From 20 °C to 60 °C, the solubility of B rises by about 79 g, while that of A rises by only about 18 g.

Ans.The solubility of B increases more than that of A
5.3Activity 5.3: Let us prepare1.Collect a sample of copper sulfate (blue vitriol). If copper sulfate is unavailable, you can use common salt as an alternative.2.Take 1 g of copper sulfate and place it in a 100 mL beaker. Add 25 mL of water to the beaker and add a drop of dilute sulfuric acid. Gently heat the mixture in a water bath while stirring constantly. Sulfuric acid helps in making pure crystals by preventing unwanted reactions.3.Gradually, add more copper sulfate until the solution becomes saturated (Fig. 5.8a).4.Filter the hot solution to remove insoluble impurities (Fig. 5.8b). Collect it in a clean beaker and cover it with a watch glass.5.Allow the solution to cool slowly without disturbing it (Fig. 5.8c). It gives enough time to the particles in the solution to come together, resulting in the formation of larger, shiny, well-shaped and blue-coloured crystals.6.Filter the crystals, rinse them with cold water and allow them to dry on a watch glass (Fig. 5.8d).You may also try: 1. Place 1 – 2 mL of the saturated copper sulfate solution on a small glass plate or a lamination sheet. 2. Leave it for some time. What do you observe? Did you get crystals? If yes, is this a good way to experiment? Explain.▾
Preparing a saturated copper sulfate solution in a beaker on a water bath over a burner
Filtering the hot saturated solution through a funnel into a beaker
Cooling the filtrate in a beaker covered with a watch glass
Blue crystals of copper sulfate on a watch glass
Fig. 5.8 — Steps involved in the process of crystallization

Observations:

1. Copper sulfate dissolves in hot water to give a blue solution. More is added until it is saturated.

2. Filtering the hot solution removes the insoluble impurities.

3. On slow cooling, shiny, blue, well-shaped crystals of copper sulfate separate out.

Why is the solution cooled slowly? Slow cooling gives the particles enough time to come together and arrange in a regular pattern. So larger, well-shaped crystals are formed.

Why are the crystals rinsed with cold water? Cold water removes the impurities sticking to them and dissolves very little of the crystals.

You may also try: on the glass plate, the water evaporates quickly and small, tiny crystals are seen.

This is not a good way to get large, well-shaped crystals, because quick evaporation does not give the particles time to arrange. It is useful only for a quick look.

Conclusion
Crystallization gives pure crystals from a saturated solution. Slow cooling gives large, well-formed crystals.
5.4Activity 5.4: Let us describe a process. Observe Fig. 5.9, it shows how salt crystals are obtained from seawater. Can you describe the process in your own words?▾
Flow chart: seawater to saturated solution to salt crystals
Fig. 5.9 — Steps followed in the salt manufacturing process

Step 1: Seawater is let into large, shallow pans (salt pans).

Step 2: The heat of the Sun and the wind make the water evaporate slowly. The solution becomes more and more concentrated.

Step 3: When the solution becomes saturated, the salt starts separating out.

Step 4: Crystals of salt are formed. They are collected, washed and dried.

The process is crystallization, and it works because water evaporates but salt does not.

Answer
Seawater → saturated solution (by evaporation of water) → salt crystals.
5.5Activity 5.5: Let us investigate1.Take a 3 cm wide strip of chromatographic paper and draw a straight, horizontal line, 2 cm from the bottom of the paper with a pencil (Fig. 5.15a). Alternatively, you can use a strip of filter paper.2.Mark a spot with a black sketch pen at the centre of the line (Fig. 5.15b).3.Take enough water to make a thin layer at the bottom of a gas jar, a measuring cylinder, or a beaker.4.Place the paper strip with the ink spot vertically into the container, so that its lower end dips into the water. The water level should be below the spot, as shown in Fig. 5.15c.5.Observe the paper as the water rises through the paper. What do you notice?6.As the water rises, the ink starts to separate into different colour spots. What can you infer from this?▾

Step 5: the water rises slowly up the paper and carries the ink with it.

Step 6: the black spot spreads and splits into different coloured spots (for example blue, pink and yellow) at different heights.

(a) Start(b) After some timePaper stripInk spot (black)Water belowthe spotSolvent frontYellowPinkBluewww.boundlessmaths.com
Fig. 5.15 (redrawn): the black ink spot splits into different coloured spots as the water rises (colours shown are an example)

Inference: black ink is not a single colour. It is a mixture of different dyes.

The dyes separate because they move up the paper at different speeds, depending on how they interact with the paper and the water.

The water level must be below the spot at the start. Otherwise, the ink would dissolve in the water.

Conclusion
Black ink is a mixture of dyes. Paper chromatography separates them on the basis of their different rates of movement.
5.6Activity 5.6: Let us separate1.Pour a mixture of 5 mL mustard oil and 20 mL water into a 50 mL separating funnel.2.Let it stand undisturbed. What do you observe?3.You will see the formation of two separate layers of mustard oil and water (Fig. 5.16). The yellow-coloured mustard oil forms the upper layer and water forms the lower layer. Can you explain why?4.Open the stopcock of the separating funnel slowly to collect the lower layer of water carefully into a container.5.Close the stopcock when the water is almost fully drained.6.Collect the next small portion that may contain both liquids and discard it.7.Collect the layer of oil separately by opening the stopcock again.▾

Step 2: the oil and water do not mix. They form two separate layers.

Step 3 (why the oil is on top): the two liquids are immiscible. Mustard oil is less dense than water, so it floats on water as the upper layer.

Glass stopperMustard oilWaterStopcockConical flaskStandwww.boundlessmaths.com
Fig. 5.16 (redrawn): the lighter mustard oil floats above the water. The stopcock is opened slowly to drain the lower layer

Steps 4 to 7: the water (lower layer) is drained slowly through the stopcock. The stopcock is closed just before the oil reaches it. The small middle portion with both liquids is discarded. The oil is then collected separately.

Conclusion
Two immiscible liquids can be separated with a separating funnel, because they form layers of different density.
5.7Activity 5.7: Let us explore1.Take a spatula full of the mixture containing crushed camphor and sand. Put it into a clean and dry china dish. Place it on the tripod stand using a wire gauze.2.Take a clean and dry glass funnel. Plug its nozzle with cotton.3.Keep this funnel inverted on the china dish and set up the apparatus as shown in Fig. 5.17.4.Light the burner and place it under the wire gauze.5.Heat the china dish gently for a few minutes.6.Observe the inner wall of the funnel carefully. Do you notice any solid deposits?7.You may find white, solid camphor deposits on the inner wall of the funnel while sand remains in the china dish.▾
Apparatus for sublimation: a china dish with camphor and sand on a tripod and wire gauze, with an inverted glass funnel plugged with cotton above it, and a burner below
Fig. 5.17 — Sublimation of camphor

Step 6: yes, white solid deposits are seen on the cooler inner wall of the funnel.

Step 7: the white deposit is camphor. The sand stays in the china dish.

Explanation: on heating, camphor changes directly from solid to vapour without becoming a liquid. This is sublimation.

The vapour touches the cool wall of the funnel and changes back directly into a solid. This is deposition.

Sand does not sublime, so it remains in the dish. The cotton plug stops the vapour from escaping.

Conclusion
Camphor sublimes and sand does not, so the mixture is separated by sublimation.
5.8Activity 5.8: Let us make a model. Make your own centrifuge with a cardboard disc and thick thread. You will be able to see how the heavier particles move outwards. It is a fun and hands-on way to understand the science behind separation. Which mixture would you like to separate using this mini centrifuge?▾

Making it: cut a disc of cardboard. Make two holes close to the centre and pass a thick thread through them. Tie the ends to make a loop on each side.

Using it: tape a small closed bottle or tube of the mixture on the disc. Hold the two loops and twist the disc by winding the thread. Then pull the thread apart and let go, so that the disc spins quickly.

Observation: the heavier particles are thrown outwards and settle at the outer end of the tube. The lighter liquid stays near the centre.

Mixture to separate: muddy water, or chalk powder in water. Each has heavy particles that settle faster on spinning.

This is the idea behind the centrifuge and the paperfuge, used to separate the parts of blood.

Answer
Heavier particles move outwards when the disc spins. Muddy water (or chalk in water) can be separated.
5.9Activity 5.9: Complete Table 5.1 and review what you have learnt about solutions, suspensions and colloids.▾
S. No.PropertySolutionSuspensionColloid
1.Nature (homogeneous / heterogeneous)HomogeneousHeterogeneousHeterogeneous (looks homogeneous)
2.Particle sizeLess than 1 nmMore than 1000 nm1 – 1000 nm
3.VisibilityParticles cannot be seenParticles are visible to the naked eyeParticles cannot be seen by the naked eye
4.Separation by filtrationCannot be separatedCan be separated (residue is left)Cannot be separated
5.SettlingDo not settleSettle on standingDo not settle
6.Tyndall effectNot shownShownShown
Answer
Solution: small particles, no scattering. Suspension: large particles that settle. Colloid: medium particles that scatter light but do not settle.
Section C

Pause and Ponder

10 Questions
P1A common talcum powder contains 4 % m/m zinc oxide, which acts as an antiseptic. How much zinc oxide is present in 300 g of the talcum powder?▾

Given: concentration = 4 % m/m, mass of talcum powder = 300 g

To find: mass of zinc oxide

4 % m/m means 4 g of zinc oxide in every 100 g of the powder.

\[\text{Mass of zinc oxide} = \dfrac{4}{100} \times 300 = 12\text{ g}\]
Answer
12 g of zinc oxide is present.
P2Your mother gives you a bottle of orange juice concentrate to mix with water and serve it to your visiting friends. She asks you to mix two tablespoons of the concentrate with water in a glass tumbler. If each tablespoon measures 15 mL and you make 150 mL of juice per person, what is the % v/v of orange juice concentrate in the mixture you prepared?▾

Given: 2 tablespoons of 15 mL each, volume of juice = 150 mL

To find: % v/v of the concentrate

Volume of concentrate (solute):

\[2 \times 15 = 30\text{ mL}\]

Volume of solution = 150 mL

\[\%\ v/v = \dfrac{30}{150} \times 100 = 20\%\]
Answer
The mixture is 20 % v/v orange juice concentrate.
P3Vinegar, used as a food preservative and additive, contains 5 % v/v acetic acid. Glacial acetic acid is a liquid, i.e., 100% acetic acid. If you want to make vinegar from glacial acetic acid, how would you proceed?▾

5 % v/v means 5 mL of acetic acid in every 100 mL of vinegar.

Step 1: measure 5 mL of glacial acetic acid with a measuring cylinder (use gloves, and do it with an adult or the teacher, as it is strong and corrosive).

Step 2: pour some water into a larger measuring cylinder or flask.

Step 3: add the 5 mL acid to the water and stir.

Step 4: add more water to make the total volume 100 mL. So, about 95 mL of water is used.

For larger quantities, keep the same ratio. For example, 50 mL of acid is made up to 1 litre.

\[\dfrac{5}{100} \times 100 = 5\%\ v/v\]
Answer
Dilute 5 mL of glacial acetic acid with water to make 100 mL of solution.
P4Refer to the solubility curves given in Activity 5.2. If equal masses of hot, saturated solutions of compounds ‘A’ and ‘B’ are cooled from 80 °C to 60 °C, which solution is likely to deposit more solid?▾
0 20 40 60 80 100 200 300 400 Temperature (°C) Solubility (g/100 g) Compound B Compound A www.boundlessmaths.com
Fig. 5.6 (redrawn): solubility curves of compounds ‘A’ and ‘B’ in water. B = 241 g at 40 °C and 287 g at 60 °C (given); other values are read approximately

From the graph, the solubility of compound B falls from about 360 g to 287 g per 100 g of water between 80 °C and 60 °C. That is a fall of about 73 g.

The solubility of compound A falls from about 63 g to about 52 g. That is a fall of only about 11 g.

\[\text{B: } 360 - 287 \approx 73\text{ g} \qquad \text{A: } 63 - 52 \approx 11\text{ g}\]

The more the solubility falls on cooling, the more solid is deposited.

Answer
The solution of compound B will deposit more solid.
P5Will there be any change in the size of common salt crystals if the rate of evaporation is increased or decreased? Explain.▾

Crystals form when the particles come together and arrange in a regular pattern.

Faster evaporation: the particles get less time to arrange. Many small crystals form quickly.

Slower evaporation: the particles get more time to join the growing crystals. Fewer, larger and better-shaped crystals form.

Answer
Yes. Faster evaporation gives smaller crystals and slower evaporation gives larger crystals.
P6State whether the following statements are True or False. Also, correct the False statements.(i)Salt can be separated from a salt solution by evaporation or distillation.(ii)Distillation can be used for separation of two liquids even when these have the same boiling point.(iii)In paper chromatography, the solvent level should be above the sample spot at the beginning of the experiment.(iv)Evaporation and crystallization are the same processes.▾
(i)True

Evaporation removes the water and leaves the salt. Distillation can also recover water from the salt solution, leaving the salt in the flask.

Ans.True
(ii)False

Distillation separates liquids because their boiling points are different (by at least about 25 °C).

Ans.False. Distillation can be used for two liquids only when their boiling points are different.
(iii)False

If the solvent is above the spot, the ink dissolves in the solvent and is not carried up the paper.

Ans.False. The solvent level should be below the sample spot at the beginning.
(iv)False

Evaporation removes the solvent completely, and the solid left can be impure. Crystallization forms pure crystals from a saturated solution on cooling, based on the change in solubility.

Ans.False. They are different processes.
P7Why do immiscible liquids form two separate layers in a separating funnel?▾

Immiscible liquids do not mix with each other.

They have different densities. The liquid with lower density floats on top, and the liquid with higher density stays at the bottom.

So the two liquids form two separate layers, and the lower layer can be drained through the stopcock.

Answer
They do not mix and have different densities, so the lighter liquid forms the upper layer.
P8Is sublimation different from evaporation? Justify.▾
SublimationEvaporation
A solid changes directly into vapourA liquid changes into vapour
The liquid state is not formedThe liquid state is present
Happens on heating, below the melting point of the solidHappens at the surface, at any temperature below the boiling point
Example: camphor, naphthalene, dry iceExample: water drying from wet clothes
Answer
Yes. In sublimation a solid becomes vapour without passing through the liquid state. In evaporation a liquid becomes vapour.
P9Clouds are made up of tiny water droplets or ice crystals floating in the air. Based on what you know about solutions, suspensions and colloids, what type of mixture do you think clouds are and why?▾

The water droplets or ice crystals are tiny. They are spread through the air and do not settle quickly.

Their size is between that of a solution and a suspension (1 – 1000 nm range for colloids).

They scatter the sunlight (Tyndall effect), which is why the beams of light are seen through clouds and why clouds look white.

Answer
Clouds are colloids, with tiny water droplets (dispersed phase) in air (dispersion medium). They do not settle and they scatter light.
P10Why do cities with a lot of smoke and dust in the air often look hazy?▾

Smoke and dust are tiny solid particles suspended in the air.

These particles scatter the light that passes through the air (Tyndall effect).

Because of the scattering, the light spreads in all directions, and distant objects look blurred and hazy.

Answer
Smoke and dust particles scatter the light, so the air looks hazy.
Section D

Worked Examples 5.1 – 5.3

3 Questions
Ex 5.1Example 5.1: If 10 g of salt is dissolved in 90 g of water, calculate the mass by mass percentage of the solution formed.▾

Given: mass of salt (solute) = 10 g, mass of water (solvent) = 90 g

To find: mass by mass percentage

Total mass of solution = mass of solute + mass of solvent

\[10 + 90 = 100\text{ g}\]
\[\%\ m/m = \dfrac{\text{Mass of solute}}{\text{Mass of solution}} \times 100\]
\[= \dfrac{10}{100} \times 100 = 10\%\ m/m\]
Answer
The solution is 10 % m/m.
Ex 5.2Example 5.2: If 5 g of glucose is dissolved in water to make 100 mL of solution, calculate its concentration in mass by volume percentage.▾

Given: mass of glucose (solute) = 5 g, volume of solution = 100 mL

To find: mass by volume percentage

\[\%\ m/v = \dfrac{\text{Mass of solute}}{\text{Volume of solution}} \times 100\]
\[= \dfrac{5}{100} \times 100 = 5\%\ m/v\]
Answer
The concentration is 5 % m/v.
Ex 5.3Example 5.3: If 1 mL of a liquid pesticide is mixed with a sufficient amount of water to form 100 mL of a pesticide spray for rice crop, calculate its volume by volume percentage.▾

Given: volume of pesticide (solute) = 1 mL, total volume of solution = 100 mL

To find: volume by volume percentage

\[\%\ v/v = \dfrac{\text{Volume of solute}}{\text{Volume of solution}} \times 100\]
\[= \dfrac{1}{100} \times 100 = 1\%\ v/v\]
Answer
The spray is 1 % v/v.
Section E

Questions from the Text

12 Questions
IN1Is the mixture of oil and water homogeneous or heterogeneous? Can you think of some other heterogeneous mixtures?▾

Oil and water do not mix. They form two separate layers, so the composition is not uniform.

Other heterogeneous mixtures: sand and water, iron filings and sulfur, muddy water, smoke, fog and dust in air, sawdust in water.

Answer
The mixture of oil and water is heterogeneous.
IN2When farmers spray pesticides on their crops, they must mix the right amount of pesticide with a fixed amount of water to prepare a solution. If they do not do so, what is likely to happen? Can you think of other such examples?▾

Too little pesticide: it may not protect the crops from pests.

Too much pesticide: it can damage the crops, the soil and the environment.

Other examples: ORS (oral rehydration solution), liquid medicines and syrups, saline (0.9 % m/v), fertiliser solutions, and even a cup of tea.

Answer
Too little pesticide does not protect the crop, and too much damages the crop, soil and environment. The right proportion is essential.
IN3What do you think will happen if you make a saturated solution at a higher temperature and cool it slowly?▾
0 20 40 60 80 100 200 300 400 Temperature (°C) Solubility (g/100 g) Compound B Compound A www.boundlessmaths.com
Fig. 5.6 (redrawn): solubility curves of compounds ‘A’ and ‘B’ in water. B = 241 g at 40 °C and 287 g at 60 °C (given); other values are read approximately

The solubility of a solid generally falls when the temperature falls. So the solution can no longer hold all the dissolved solute.

Example: a saturated solution of B at 60 °C has 287 g of B in 100 g of water. At 40 °C only 241 g can stay dissolved.

The rest separates out as a pure solid, often as crystals:

\[287 - 241 = 46\text{ g}\]
Answer
The excess solute separates out as crystals. Here, 46 g of B crystallises for every 100 g of water.
IN4How can we separate the two miscible liquids? Is it possible to separate the mixture of two miscible liquids by evaporation and obtain both the liquids?▾

In evaporation, the liquid that evaporates is lost to the air, so only the liquid that does not evaporate is left in the container.

For the mixture of acetone and water, if we heat the mixture, the acetone evaporates more easily (boiling point 56 °C) and escapes into air. We cannot get both liquids back.

Method: distillation. The liquid with the lower boiling point vaporises first. Its vapour is cooled in a condenser and is collected as a liquid. The other liquid stays in the flask.

Answer
No. Both liquids cannot be obtained by evaporation. Miscible liquids with different boiling points are separated by distillation.
IN5Can you think of any heterogeneous mixtures with a gas as one of the components?▾

Gases mix easily with other gases, so most gas mixtures are homogeneous.

Heterogeneous mixtures with a gas as one component: smoke (solid particles in air), fog (water droplets in air), dust in air, and clouds.

Answer
Smoke, fog and dust in the air.
IN6What if … two immiscible liquids of the same density are mixed in a separating funnel, how will the layers form?▾

Layers form because one liquid is lighter than the other and floats on it.

If both liquids have the same density, neither of them floats on the other.

So no clear upper and lower layer will form. The liquids stay mixed as droplets and look cloudy.

The mixture cannot be separated by a separating funnel.

Answer
No separate layers will form, so the separating funnel cannot separate them.
IN7Can you think of any other mixtures where sublimation can be used to separate the components?▾

Sublimation can be used when one component sublimes on heating and the other does not.

Examples: ammonium chloride and common salt, naphthalene and sand (or salt), iodine and sand, camphor and salt.

Answer
Ammonium chloride and salt, naphthalene and sand, iodine and sand.
IN8Is it possible to dissolve one metal in another?▾

Metals do not dissolve in each other at room temperature.

When metals are melted at a high temperature, they can be mixed to form a solution.

When the hot mixture cools, it solidifies into a new material that looks like a single metal. Such a homogeneous mixture is called an alloy.

Examples: brass (about 80% copper and 20% zinc), bronze (about 80% copper and 20% tin) and stainless steel.

Physical methods cannot separate the components of an alloy.

Answer
Yes, by melting the metals together. The solution formed on cooling is an alloy.
IN9If the muddy water is still not clear even after keeping for some time, how can it be cleaned?▾

The heavier mud settles at the bottom, but the water may still look cloudy. Filtration alone does not remove the tiny particles.

Centrifugation: spin the muddy water at a high speed. The centrifugal force throws the heavier particles outwards to the bottom of the tube, and the clear liquid stays at the top.

Coagulation: add a little powdered alum (fitkari). It makes the fine particles clump together. The larger clumps settle down (sedimentation).

The clear water is then separated by decantation or filtration.

Answer
By centrifugation or by coagulation with alum, followed by decantation or filtration.
IN10Can you think of any other coagulation processes used in everyday life?▾

1. Making paneer (cheese) from milk. Lemon juice or vinegar coagulates the milk proteins.

2. Making curd from milk is also a thickening of milk proteins.

3. Clotting of blood at a cut.

4. Purifying water by alum, in water treatment plants.

5. Setting of rubber latex with acid.

Answer
Paneer from milk, blood clotting, and purification of water with alum.
IN11If the components of blood can be separated by centrifugation and the blood coagulates, is it a suspension? However, we cannot see blood cells with the naked eye. Is it a solution?▾

Is it a suspension? A suspension has particles that are visible and settle on their own. Blood cells cannot be seen by the naked eye and do not settle on their own.

Is it a solution? A solution does not scatter light and cannot be separated by spinning. Blood can be separated by centrifugation, and its cells scatter light.

Blood is neither a solution nor a true suspension.

Answer
Blood is a colloid.
TS1Think as a Scientist: If a hot, saturated solution of copper sulfate is cooled rapidly in ice-cold water, smaller and less well-formed crystals will form than if it is cooled slowly at room temperature. How would you design and perform an experiment to test this hypothesis? Hint: Prepare a hot saturated solution of copper sulfate and divide it into two equal parts.▾

Hypothesis: rapid cooling gives smaller, less well-formed crystals than slow cooling.

Step 1: prepare a hot, saturated solution of copper sulfate (with a drop of dilute sulfuric acid, under adult supervision) and filter it.

Step 2: divide it into two equal parts in two identical beakers, A and B.

Step 3: keep beaker A in ice-cold water to cool it rapidly.

Step 4: keep beaker B at room temperature, covered and undisturbed, to cool it slowly.

Step 5: after the same time, filter the crystals from both, dry them and compare their size and shape with a magnifying glass.

Kept the same: amount and concentration of solution, type and size of beaker, starting temperature.

Changed: only the rate of cooling.

Expected result: beaker A gives small, poorly shaped crystals and beaker B gives larger, shiny, well-shaped crystals. This supports the hypothesis.

Answer
Cool two equal parts of the same saturated solution, one rapidly and one slowly, and compare the crystals.
Section F

Revise, Reflect, Refine

15 Questions
Q1Which of the following mixtures are correctly classified as homogeneous (Hm) and heterogeneous (Ht)? Choose the correct option.(i)Air — Hm, Milk — Ht, Sugar solution — Hm, Smoke — Hm(ii)Brass — Ht, Fog — Ht, Vinegar — Ht, Muddy water — Hm(iii)Copper sulfate solution — Hm, Salt solution — Hm, Milk — Hm, Bronze — Hm(iv)Muddy water — Ht, Milk — Ht, Blood — Ht, Brass — Hm▾

(i) wrong: smoke is solid particles in air. It is heterogeneous, not homogeneous.

(ii) wrong: brass is an alloy (homogeneous), vinegar is a solution (homogeneous) and muddy water is heterogeneous.

(iii) wrong: milk is a colloid, which is classed as heterogeneous.

(iv) correct: muddy water, milk and blood are heterogeneous, and brass is homogeneous.

Answer
Option (iv).
Q2Choose the correct options, and explain the reason for the correct and incorrect options. Which among the following mixtures show the Tyndall Effect? A mixture of:(a)air and dust particles(b)copper sulfate and water(c)starch and water(d)acetone and water(i)a and b(ii)b and d(iii)a and c(iv)c and d▾

The Tyndall effect is the scattering of light by particles. It happens in colloids and suspensions, but not in true solutions.

(a) Air and dust: dust particles are large enough to scatter light. Tyndall effect is shown.

(b) Copper sulfate and water: it is a true solution with very small particles. No scattering.

(c) Starch and water: starch forms a colloid with particles of 1 – 1000 nm. It scatters light.

(d) Acetone and water: it is a true solution. No scattering.

So (a) and (c) show the Tyndall effect. Options (i), (ii) and (iv) each include (b) or (d), which are solutions, so they are wrong.

Answer
Option (iii): a and c.
Q3A mixture can be categorised as a solution, a suspension, or a colloid, each possessing distinct properties. Utilise the words or phrases provided in the box to fill in the Table 5.2. Words and phrases may be used more than once. Words and Phrases: Large-sized particles; Particles remain evenly distributed; Small-sized particles (less than 1 nm diameter); Moderate-sized particles (1 – 1000 nm); Settles down when left undisturbed (more than 1000 nm in diameter); Does not settle down; Scatters light; Separates by filtration; Transparent; Salt solution; Milk; Sand in water; Smoke; Heterogeneous mixture; Cannot be separated by filtration; Mud; Butter; Brass.▾
SolutionSuspensionColloid
PropertiesSmall-sized particles (less than 1 nm diameter)
Particles remain evenly distributed
Transparent
Cannot be separated by filtration
Large-sized particles
Settles down when left undisturbed (more than 1000 nm in diameter)
Heterogeneous mixture
Separates by filtration
Scatters light
Moderate-sized particles (1 – 1000 nm)
Particles remain evenly distributed
Does not settle down
Scatters light
Cannot be separated by filtration
ExamplesSalt solution
Brass
Sand in water
Mud
Milk
Butter
Smoke
Answer
The table above is completed using the words from the box.
Q4Solve the following problems:(i)A cake recipe uses dry ingredients, namely 75 g of sugar for 420 g of all-purpose flour and 5 g of sodium hydrogencarbonate. Express the concentration of each component in the mixture using an appropriate method.(ii)A brass alloy contains 70% copper by mass. Calculate the quantities of copper and zinc present in 120 g of brass.▾
(i)Cake recipe

The ingredients are solids, so the mass by mass percentage (% m/m) is suitable.

Total mass of the mixture = 75 + 420 + 5 = 500 g

Sugar:

\[\dfrac{75}{500} \times 100 = 15\%\ m/m\]

Flour:

\[\dfrac{420}{500} \times 100 = 84\%\ m/m\]

Sodium hydrogencarbonate:

\[\dfrac{5}{500} \times 100 = 1\%\ m/m\]

Check: 15 + 84 + 1 = 100%

Ans.Sugar 15%, flour 84%, sodium hydrogencarbonate 1% (m/m)
(ii)Brass alloy

Copper:

\[\dfrac{70}{100} \times 120 = 84\text{ g}\]

Zinc: the rest of the brass is zinc.

\[120 - 84 = 36\text{ g}\]
Ans.Copper = 84 g, zinc = 36 g
Q5The label on a cooking oil pack says one litre (910 g). If this oil is mixed with water, will it form a separate layer? If so, which substance will be on top? How will you separate the two layers? Also, draw the diagram of the apparatus used.▾

Density of oil:

\[\dfrac{910\text{ g}}{1000\text{ mL}} = 0.91\text{ g/mL}\]

Water has a density of 1 g/mL. Oil is less dense than water and does not mix with it (immiscible).

Yes, the oil will form a separate layer, and it will be on top.

Separation: use a separating funnel. Open the stopcock slowly to drain the lower layer (water). Close it before the oil reaches the stopcock. Collect the oil separately.

Glass stopperMustard oilWaterStopcockConical flaskStandwww.boundlessmaths.com
Fig. 5.16 (redrawn): the lighter mustard oil floats above the water. The stopcock is opened slowly to drain the lower layer
Answer
Oil forms the upper layer. The two layers are separated using a separating funnel.
Q6Assertion (A): Solutions do not exhibit the Tyndall effect.
Reason (R): The particles in solutions are larger than 100 nm, so they cannot scatter light.
Choose the correct option:(i)Both A and R are true, and R is the correct explanation of A.(ii)Both A and R are true, but R is not the correct explanation of A.(iii)A is true, but R is false.(iv)A is false, but R is true.
▾

Assertion A: true. The particles of a solution are very small, so a solution does not scatter light and the beam is not visible.

Reason R: false. The particles in a solution are smaller than 1 nm, not larger than 100 nm. Larger particles would scatter light.

Answer
Option (iii): A is true, but R is false.
Q7How would you separate the mixtures given in Table 5.3? Mention the reason for choosing your method. If a mixture cannot be separated, explain why.▾
MixtureMethod of separationReason for selection
Mud from muddy waterSedimentation, decantation or filtration. Centrifugation or alum (coagulation) if it is still cloudyMud particles are large and heavy. They settle, or are removed by filtration
Plasma from other components in the blood sampleCentrifugationSpinning throws the heavier blood cells outwards. The lighter plasma stays at the top
Naphthalene and sandSublimationNaphthalene sublimes on heating, but sand does not
Chalk powder and common saltAdd water, then filter. Evaporate the filtrateSalt dissolves in water but chalk does not. Chalk stays on the filter paper, and salt is got by evaporation
Common salt and waterEvaporation (or crystallization). Distillation, to also get the waterWater evaporates, but salt does not
Oil from waterSeparating funnelThey are immiscible and have different densities
Pigments of the flowerPaper chromatographyThe pigments move at different rates on the paper. A solvent such as alcohol may be needed
Answer
All the mixtures can be separated by the methods in the table.
Q8Two miscible liquids, A and B, are present in a mixture. The boiling point of A is 60 °C and the boiling point of B is 90 °C. Suggest a method to separate them. Also, draw a labelled diagram of the method suggested.▾

The liquids are miscible, so they cannot be separated by a separating funnel or filtration.

The difference in their boiling points is:

\[90 - 60 = 30\,^{\circ}\text{C}\]

This is more than 25 °C, so they can be separated by distillation.

Procedure:

1. Put the mixture in the distillation flask and heat it slowly.

2. The thermometer shows 60 °C when A vaporises first, because it has the lower boiling point.

3. The vapour of A passes through the water condenser, where it cools and changes back into a liquid.

4. Liquid A is collected in the conical flask.

5. Liquid B, with the higher boiling point, stays in the distillation flask.

ThermometerDistillationflaskTripodstandBurnerWater outWater inCondenserConical flaskwww.boundlessmaths.com
Fig. 5.12 (redrawn): distillation set-up. The liquid of lower boiling point vaporises first, is cooled in the condenser and is collected in the conical flask
Answer
Distillation. Liquid A (boiling point 60 °C) distils first and B remains in the flask.
Q9Compare evaporation, crystallization and distillation. In which situation, would you prefer each of these over the others?▾
EvaporationCrystallizationDistillation
PrincipleThe liquid changes to vapour at the surface and the solid is leftThe solubility of a solid falls on cooling a saturated solution, so crystals formLiquids differ in boiling point. One vaporises first and is condensed
What is obtainedSolid (the solvent is lost)Pure crystals of the solidThe liquid (solvent) and the solid or other liquid left behind
Preferred whenWe want only the dissolved solid, and the solid does not break on heating (salt from sea water)We want a pure solid, or the solid breaks on strong heating (copper sulfate crystals)We want the liquid back, or to separate two miscible liquids (water from acetone)
Answer
Evaporation for a simple solid, crystallization for a pure solid, and distillation to get the liquid or separate miscible liquids.
Q10Blood is an example of a colloidal mixture.(i)What would happen if blood behaved like a true suspension inside the body?(ii)In a blood sample, identify the dispersed phase and the dispersion medium.▾
(i)If blood were a suspension

The particles of a suspension settle on standing. So the blood cells would settle down in the blood vessels.

They would not stay evenly spread, and the blood could not carry oxygen, nutrients and hormones to all parts of the body properly.

The cells would also block the narrow vessels.

Ans.The blood cells would settle and block, so blood could not do its work
(ii)Phases of blood

The blood cells (red cells, white cells and platelets) are the dispersed particles.

The liquid in which they are spread is the plasma.

Ans.Dispersed phase: blood cells. Dispersion medium: plasma
Q11You are given a mixture of sand, common salt and naphthalene (Fig. 5.25a). The Fig. 5.25b depicts various steps used to separate the components of this mixture. Identify and write down the correct sequence of separation techniques.▾
A china dish holding the mixture of sand, salt and naphthalene
Step 1: heating the mixture under an inverted funnel
Step 2: dissolving in water and heating
Step 3: filtering through a funnel into a beaker
Fig. 5.25 — (a) the mixture; (b) steps 1, 2 and 3 used to separate its components

Step 1 (figure 1) – Sublimation: the mixture is heated in a china dish covered with an inverted funnel. Naphthalene sublimes and is deposited on the funnel. Sand and salt are left.

Step 2 (figure 3) – Filtration: the left-over mixture is stirred in water. The salt dissolves, but the sand does not. On filtering, the sand is left on the filter paper and the salt solution is the filtrate.

Step 3 (figure 2) – Evaporation: the filtrate is heated in a china dish. The water evaporates and the salt is left.

Sublimation has to be done first, because the other steps need water or heating of the salt solution.

Answer
The correct sequence is 1 → 3 → 2: sublimation, then filtration, then evaporation.
Q12Why is distillation an effective method for separating a mixture of water and acetone?▾

Water and acetone are miscible, so they form a homogeneous mixture and cannot be separated by filtration or a separating funnel.

Their boiling points are very different: acetone boils at about 56 °C and water at 100 °C.

\[100 - 56 = 44\,^{\circ}\text{C}\]

This is more than 25 °C. On heating, acetone vaporises first, before water vapour forms in a large amount.

The acetone vapour is cooled in the condenser and collected as pure liquid acetone. The water remains in the flask.

Answer
Because the boiling points differ by 44 °C, acetone vaporises first and is condensed and collected separately.
Q13Answer the following questions with the help of the data given in Table 5.4. Table 5.4: Solubility of various salts (in g per 100 g of water) at different temperatures: potassium nitrate 21, 32, 45, 62, 106, 167; sodium chloride 36, 36, 36.3, 36.5, 37, 37; potassium chloride 35, 35, 37.4, 40, 46, 54; ammonium chloride 24, 37, 41, 41, 55, 66 (at 10 °C, 20 °C, 30 °C, 40 °C, 60 °C and 80 °C respectively). (i) What mass of potassium nitrate would be needed to prepare its saturated solution in 50 g of water at 40 °C? (ii) A student makes a saturated solution of potassium chloride in water at 80 °C and leaves the solution to cool at room temperature (25 °C). What would she observe as the solution cools? Explain. (iii) What is the effect of a change in temperature on the solubility of salts? Also, compare the changes in the solubility of the four given salts with increasing temperature from 10 °C to 80 °C.▾
10 20 40 60 80 50 100 150 Temperature (°C) Solubility (g/100 g) KNO₃ NH₄Cl KCl NaCl www.boundlessmaths.com
Table 5.4 as a graph: solubility (g per 100 g of water) against temperature
(i)KNO₃ in 50 g of water at 40 °C

At 40 °C, 62 g of KNO₃ dissolves in 100 g of water.

For 50 g of water, the mass needed is half of this.

\[\dfrac{62}{100} \times 50 = 31\text{ g}\]
Ans.31 g
(ii)Cooling KCl solution

At 80 °C, 54 g of KCl dissolves in 100 g of water.

At 25 °C the solubility is about 36 g (between 35 g at 20 °C and 37.4 g at 30 °C).

\[54 - 36 = 18\text{ g}\]

About 18 g of KCl cannot stay dissolved in every 100 g of water. The solution turns cloudy and crystals of potassium chloride settle at the bottom as it cools.

Ans.Crystals of KCl separate out, about 18 g per 100 g of water
(iii)Effect of temperature

The solubility of these solid salts increases as the temperature increases. The increase is different for different salts:

Salt10 °C80 °CRise in solubility
Potassium nitrate21167146 g (very large)
Ammonium chloride246642 g (large)
Potassium chloride355419 g (small)
Sodium chloride36371 g (almost no change)
Ans.Solubility of solids increases with temperature. KNO₃ shows the largest change and NaCl the least
Q14Three students, A, B and C, are preparing sugar solutions for an experiment:•Student A dissolves 20 g of sugar in 80 g of water.•Student B dissolves 20 g of sugar in 100 g of water.•Student C dissolves 30 g of sugar in 80 g of water.(i)Calculate the mass percentage (% m/m) concentration of sugar in each student’s solution.(ii)Whose solution is the most concentrated? Explain why.▾
(i)Mass percentage

Mass of solution = mass of sugar + mass of water.

\[A: \dfrac{20}{20 + 80} \times 100 = \dfrac{20}{100} \times 100 = 20\%\]
\[B: \dfrac{20}{20 + 100} \times 100 = \dfrac{20}{120} \times 100 = 16.7\%\]
\[C: \dfrac{30}{30 + 80} \times 100 = \dfrac{30}{110} \times 100 = 27.3\%\]
Ans.A = 20%, B ≈ 16.7%, C ≈ 27.3% (m/m)
(ii)Most concentrated

Concentration is the amount of solute in a given amount of solution.

Solution C has the highest percentage, 27.3%. It has the most sugar in every 100 g of solution.

Ans.Student C’s solution
Q15Examine Fig. 5.26.(i)Identify the separation technique marked as ‘S’.(ii)Label the apparatus A, B and C.(iii)Which of the following mixtures can be separated by the technique identified above? Use the data given in Table 5.5. Mixtures: (a) water — acetone (b) water — salt (c) acetone — alcohol (d) sand — salt (e) alcohol — chloroform (f) alcohol — benzeneTable 5.5: Boiling points of some compounds: water 100 °C, acetone 56 °C, alcohol 78 °C, chloroform 61 °C, benzene 80 °C.▾
ABCSwww.boundlessmaths.com
Fig. 5.26 (redrawn): the apparatus used for technique ‘S’, with parts A, B and C marked
(i)Technique S

The set-up has a flask, a condenser and a receiver.

Ans.Distillation
(ii)Labels
LetterApparatus
ADistillation flask (with the thermometer)
BWater condenser
CConical flask (receiver)
Ans.A: distillation flask, B: condenser, C: conical flask
(iii)Mixtures that can be separated

Distillation separates liquids whose boiling points differ by at least about 25 °C. It can also separate a liquid from a solution with a dissolved solid.

MixtureBoiling pointsDifferenceSeparable?
(a) water — acetone100 °C, 56 °C44 °CYes
(b) water — saltSalt does not boilWater distils, salt staysYes
(c) acetone — alcohol56 °C, 78 °C22 °CNo (less than 25 °C)
(d) sand — saltBoth are solids—No
(e) alcohol — chloroform78 °C, 61 °C17 °CNo
(f) alcohol — benzene78 °C, 80 °C2 °CNo
Ans.(a) and (b)
Section G

The Journey Beyond

8 Questions
JB1Demonstrate the Tyndall effect using different colloids. Create a series of experiments showcasing how light scatters in colloids making the beam visible. Use laser pointers (Safety first: Use it under the supervision of an adult), flashlights, or other light sources for your demonstrations.▾

Method: take clear glass tumblers with the samples given below. Darken the room and shine a laser pointer or a torch through each from the side. Look from the side, at right angles to the beam. Never look into the laser beam.

SampleType of mixtureBeam visible?
Salt or sugar in waterSolution (control)No
Few drops of milk in waterColloidYes
Starch or soap solution in waterColloidYes
Chalk powder in waterSuspensionYes
Incense (agarbatti) smoke in a jarColloid (smoke in air)Yes

The particles of colloids and suspensions scatter the light, so the path of the beam is seen. The particles of a solution are too small, so the beam is not seen.

Answer
The light beam is visible in colloids (and suspensions) but not in a true solution.
JB2Make crystals of different compounds (common salt, epsom salt, sugar, borax, nickel sulfate, etc.). Observe them under a magnifying glass or a microscope. Note down their colours and shapes.▾

Method: for each compound, make a hot saturated solution in water, filter it, and let it cool slowly and undisturbed in a covered beaker. Filter the crystals and dry them. Observe with a magnifying glass.

Sample observations (your own may differ):

CompoundColourShape of crystals
Common saltColourless / whiteSmall cubes
Epsom saltColourless / whiteLong, thin needles
SugarColourless / whiteShiny, glassy blocks
BoraxColourless / whiteSmall, short prisms
Nickel sulfateGreenSmall, regular crystals
Copper sulfateBlueWell-shaped, shiny blocks

Different compounds make crystals of different shapes and colours.

Answer
Each compound forms crystals with its own colour and shape.
JB3Do red leaves also contain green pigments? Investigate it using paper chromatography.▾

Method:

1. Crush a few red leaves (for example red amaranth or coleus) in a little alcohol to get a coloured extract.

2. Put a spot of the extract on the pencil line of a strip of chromatography (filter) paper, and let it dry. Repeat 3 to 4 times on the same spot.

3. Dip the lower end of the strip in alcohol. The level of alcohol must be below the spot.

4. Remove the strip when the solvent has risen near the top and mark the solvent front.

Observation: the spot separates into several coloured bands, including a green band, along with red, orange or yellow ones.

Inference: yes, red leaves also contain green pigment (chlorophyll). It is hidden by the red pigments.

Answer
Yes. Chromatography shows a green band, so red leaves also contain a green pigment.
JB4You can try chromatography to find the number of components present in a food colour (green, orange, yellow, etc.) or in coloured mouth fresheners (fennel seeds).▾

Method: put a spot of the food colour (or the colour dissolved from fennel seeds in a little water) on the pencil line of a filter paper strip, dip the lower end in water (or 2% salt solution) and let the liquid rise. Count the coloured spots.

Sample observation (your own may differ):

SampleSpots seenNumber of components
Green food colourBlue and yellow2
Orange food colourRed and yellow2
Yellow food colourOne yellow spot1
Coloured fennel seedsPink and blue2

The number of spots is the number of coloured components in the sample.

Answer
The number of coloured spots on the paper gives the number of components.
JB5Design an educational game where players identify and apply separation techniques to different mixtures through interactive challenges and hands-on activities.▾

Game: “Separation Snap” (for 2 to 4 players)

Cards: make two sets of cards. Set 1 has mixtures (sand + water, salt + water, iron + sulfur, camphor + sand, oil + water, black ink, muddy water, acetone + water). Set 2 has methods (filtration, evaporation, magnet, sublimation, separating funnel, chromatography, centrifugation, distillation).

Rules: a player draws a mixture card and must pick the right method card in 30 seconds and give one reason.

Scoring: 2 points for the right method and 1 more for the right reason. A hands-on challenge card asks the player to actually separate a real mixture, for 3 points.

The player with the most points wins.

Answer
A card game in which players match mixtures with correct separation methods and justify them.
JB6If you are camping outdoors and running short on clean water, you can obtain clean water by distillation. Can you think of a set-up with the items available to you?▾

Set-up using a pot:

1. Pour dirty water into a large pot. Place a small clean cup in the middle, so that it floats or stands on a stone (the cup should not touch the dirty water).

2. Cover the pot with a lid turned upside down, or a plate, with its centre lower than the edge.

3. Heat the pot on a fire. Water vaporises. Keep ice or a wet cloth on the lid so that it is cool.

4. The vapour touches the cool lid, condenses, and drips into the cup.

Result: clean water collects in the cup. The dirt stays in the pot.

Answer
Boil the dirty water and condense the vapour on a cool inverted lid. The drops fall into a clean cup.
JB7To learn more about the states of matter and concentration of solutions, you can explore the links given below: https://phet.colorado.edu/sims/html/states-of-matter-basics/latest/states-of-matter-basics_en.html and https://phet.colorado.edu/sims/html/concentration/latest/concentration_all.html▾

States of matter simulation: when the substance is heated, its particles move faster. A solid becomes a liquid and then a gas. When it is cooled, the particles slow down and come close together.

Concentration simulation: adding more solute to the same amount of solvent makes the colour deeper and the concentration higher. Adding more water makes the solution lighter, so it is diluted.

After a certain amount, no more solute dissolves. The solution is then saturated.

Answer
Heat changes the motion of particles and the state of matter. More solute gives a higher concentration, and more solvent a lower one.
QC1Can we create artificial blood that works just as real blood for all patients?▾

Blood does many jobs together: it carries oxygen (red cells), fights infections (white cells), clots at a wound (platelets) and carries nutrients, waste and hormones (plasma).

Scientists have made substances that can carry oxygen for a short time, and are trying to grow red cells in the laboratory.

So far, no artificial blood can do all the jobs of real blood safely for every patient. It is also difficult to match the types of the patients, and to keep it safe, store it and make it at a low cost.

So, donated blood is still needed. Blood donation saves lives.

Answer
Not yet. No artificial blood can do all the work of real blood for all patients, so blood donation is still essential.
💡 Chapter 5's core idea, in one line

Every mixture can be classified by particle size — solution, colloid, or suspension — and once you know which one you're dealing with, along with how its components differ in solubility, boiling point, density, or size, there's always a matching separation technique that can pull it apart cleanly.

Extra Practice

The Practice Continues

7 Questions

Seven extra questions in the style of the textbook, for independent practice. Attempt each one on paper first, then tap to check.

EP1A student prepares three mixtures: (a) sugar in water, (b) starch in water, (c) chalk powder in water. Classify each as a true solution, colloid or suspension, and state one observation that supports your answer.▾
MixtureTypeSupporting observation
(a) Sugar in waterTrue solutionClear and transparent. A laser beam is not visible and nothing settles
(b) Starch in waterColloidLooks uniform and does not settle. A laser beam is visible
(c) Chalk powder in waterSuspensionParticles settle on standing and are left on the filter paper
Answer
(a) solution, (b) colloid, (c) suspension.
EP2A saturated solution of compound B at 60 °C contains 574 g of B in 200 g of water. It is cooled to 40 °C. How many grams of B will separate out as crystals? (Solubility of B: 287 g per 100 g of water at 60 °C and 241 g per 100 g of water at 40 °C.)▾

Given: 200 g of water, solubility at 60 °C = 287 g/100 g, solubility at 40 °C = 241 g/100 g

To find: mass of crystals formed

Per 100 g of water:

\[287 - 241 = 46\text{ g}\]

For 200 g of water:

\[46 \times 2 = 92\text{ g}\]

Check: at 40 °C, 200 g of water can hold 482 g, and 574 − 482 = 92 g.

Answer
92 g of compound B separates out as crystals.
EP3A hospital needs 500 mL of normal saline, which is 0.9 % m/v sodium chloride in water. What mass of sodium chloride is needed, and how will the solution be prepared?▾

Given: concentration = 0.9 % m/v, volume of solution = 500 mL

To find: mass of sodium chloride

0.9 % m/v means 0.9 g of sodium chloride in every 100 mL of the solution.

\[\text{Mass} = \dfrac{0.9}{100} \times 500 = 4.5\text{ g}\]

Preparation: dissolve 4.5 g of sodium chloride in some water in a measuring flask, and then add water up to the 500 mL mark.

Answer
4.5 g of sodium chloride, dissolved in water to make 500 mL of solution.
EP4A mixture contains iron filings, ammonium chloride, sand and common salt. Plan the steps to separate all four components in the correct order, and justify why the order matters.▾

Step 1: Magnet. Iron is attracted by a magnet. It is taken out first, and it is not affected by heat or water.

Step 2: Sublimation. Heat the rest in a china dish with an inverted funnel. Ammonium chloride sublimes and is deposited on the funnel. Sand and salt remain.

Step 3: Dissolving and filtration. Add water to the left-over mixture and stir. The salt dissolves. The sand is left on the filter paper.

Step 4: Evaporation (or crystallization). Heat the filtrate to evaporate the water, and common salt is obtained.

Why the order matters: ammonium chloride dissolves in water, so sublimation must be done before adding water. If water is added first, ammonium chloride and salt would both dissolve together and be difficult to separate.

Answer
Magnet → sublimation → add water and filter → evaporate the filtrate.
EP5Three unlabelled beakers contain (i) sugar dissolved in water, (ii) a few drops of milk in water, and (iii) chalk powder in water. All three are shaken. Design simple tests to identify each one, and give reasons.▾

Test 1: Leave them undisturbed for a few minutes. The chalk powder settles at the bottom, so that beaker is the suspension (iii).

Test 2: Shine a laser or torch beam through the other two. The beam is visible in milk (colloid) but not in the sugar solution.

Test 3 (to confirm): filter each. Chalk leaves a residue. Sugar solution and milk pass through the filter paper without leaving a residue.

Reasoning: the particles of a suspension are large, so they settle and are filtered out. The particles of a colloid are medium-sized, so they scatter light. The particles of a solution are very small, so they do not scatter light.

BeakerSettles?Beam visible?Residue on filter?
Sugar solutionNoNoNo
Milk in waterNoYesNo
Chalk in waterYesYesYes
Answer
Chalk settles and leaves a residue. Milk shows the beam, and the sugar solution does not.
EP6Can a mixture of alcohol (boiling point 78 °C) and water (boiling point 100 °C) be separated by simple distillation? Give a reason with the data, and suggest a better method.▾

Difference in boiling points:

\[100 - 78 = 22\,^{\circ}\text{C}\]

Simple distillation works well when the boiling points differ by at least about 25 °C. Here the difference is only 22 °C, which is less.

So both liquids would vaporise together to some extent, and the separation would not be good.

Better method: fractional distillation. It is used when the boiling points of the liquids are close (less than 25 °C apart), as in the separation of crude petroleum.

Answer
No, because the difference is only 22 °C. Fractional distillation should be used.
EP715 g of sugar is dissolved in 135 g of water. (i) Find the mass percentage of the solution. (ii) How much more sugar must be dissolved in this solution to make it 20 % m/m?▾

Given: mass of sugar = 15 g, mass of water = 135 g

(i)Mass percentage

Mass of solution = 15 + 135 = 150 g

\[\dfrac{15}{150} \times 100 = 10\%\ m/m\]
Ans.10 % m/m
(ii)Sugar to be added

Let the extra sugar be x g. The mass of water stays the same, so:

\[\dfrac{15 + x}{150 + x} = \dfrac{20}{100} = 0.2\]
\[15 + x = 0.2\,(150 + x) = 30 + 0.2x\]
\[0.8x = 15\] \[x = 18.75\text{ g}\]

Check: sugar = 33.75 g, solution = 168.75 g, and 33.75 ÷ 168.75 × 100 = 20%.

Ans.18.75 g
Common Questions

Frequently Asked Questions

A solution is only saturated at a specific temperature — solubility generally increases with temperature, so heating the solution raises its solubility limit, allowing it to dissolve more solute before becoming saturated again at the new, higher temperature. This is exactly the principle used in crystallization: dissolve as much solute as possible in hot solvent, then cool the solution so the solubility limit drops back down and the excess solute crystallizes out.
Start by identifying what kind of mixture it is and what property differs between its components. An insoluble solid in a liquid needs filtration (or centrifugation for very fine particles); a dissolved solid you want back needs evaporation or crystallization; two miscible liquids with different boiling points need simple distillation (points far apart) or fractional distillation (points close together); two immiscible liquids need a separating funnel; a solid that sublimes mixed with one that doesn't needs sublimation; and dissolved coloured substances that need separating from each other need chromatography.
Filtration works by passing a mixture through a filter paper with tiny pores — only particles smaller than the pores can pass through. In a suspension, the particles are large (over 1000 nm) and get trapped by the filter paper, while the liquid passes through. In a solution, the dissolved particles are far smaller than even the tiniest filter pores (under 1 nm), so they pass through the filter along with the solvent — meaning filtration cannot separate a true solution's solute from its solvent.
No — these are commonly confused, but they're different. A solution is a mixture, meaning its components (solute and solvent) keep their individual chemical identities, can be present in variable proportions, and can usually be separated back out by physical methods like evaporation. A compound is formed when elements chemically combine in a fixed ratio to form an entirely new substance with different properties, and can only be separated back into its elements by chemical methods, not physical ones.
The key difference is particle size: solutions have particles under 1 nm and never settle or scatter light; suspensions have particles over 1000 nm, settle over time, and can be filtered; colloids fall in between (1–1000 nm), don't settle, but do scatter light — the Tyndall effect.
Using the volume of the solvent instead of the volume of the whole solution. % m/v = (mass of solute in g ÷ volume of solution in mL) × 100. For example, 20 g of salt dissolved to make 250 mL of solution is (20 ÷ 250) × 100 = 8% m/v. Always check that mass is in grams and volume is in millilitres before dividing.
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