Journey Inside the Atom Class 9 NCERT Solutions (Chapter 8) | Boundless Maths
📗 Exploration · CBSE 2026-27 Unit IV · Matter and Its Composition ✨ Free — No Sign-up 54 Questions

Class 9 Science Chapter 8:
Journey Inside the Atom

Journey Inside the Atom, Class 9 Science Chapter 8: NCERT question answers for every Think It Over, Pause & Ponder, Think as a Scientist, What If, Inline Question, Revise Reflect Refine and Quest Continues question (CBSE 2026-27), with full working for every numerical. Use it with your Journey Inside the Atom Class 9 notes to check each answer.

This chapter follows the atom from Dalton's solid sphere to Thomson's plum pudding model, Rutherford's gold foil experiment and Bohr's shells, and these Class 9 Science Chapter 8 Journey Inside the Atom NCERT solutions explain why each model was replaced. They also work through atomic number and mass number, isotopes and isobars, and electron distribution in K, L, M, N shells for the first 20 elements, with every numerical shown step by step.

Last updated 20 October 2026 · Reviewed by Suchita Arora, 13+ years teaching CBSE Maths & Science

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Overview

What Chapter 8 Is Really About

Journey Inside the Atom takes the atom apart piece by piece — from Acharya Kanada's and Dalton's idea of an indivisible particle, through Thomson's plum pudding model, Rutherford's gold foil experiment and nuclear model, to Bohr's fixed energy shells. Along the way it introduces the electron, proton and neutron, and builds up to atomic number, mass number, isotopes and isobars. Every question is solved here, section by section, with full working for every numerical, as complete Class 9 Science Chapter 8 NCERT solutions with answers.

⚛️

From Dalton to Bohr

How each atomic model was built on — and eventually broke down against — new experimental evidence.

🔬

The Gold Foil Experiment

Why most alpha particles passed straight through gold foil, while a few bounced sharply back.

🧮

Atomic Number, Isotopes & Isobars

Working out protons, neutrons and electrons, and telling isotopes and isobars apart with numericals.

Section A

Think It Over (Chapter Opener)

3 Questions
T1Are atoms the smallest indivisible particles?▾

Dalton, Acharya Kanada and the Greek philosophers believed that atoms cannot be divided.

But in the late 19th century, scientists found that certain elements emit radiation (radioactivity). This showed that atoms are made of smaller particles.

In 1897, J. J. Thomson discovered the electron, a negatively charged particle that comes out of atoms.

Rutherford later discovered the nucleus and the proton, and Chadwick discovered the neutron.

Answer
No. Atoms are divisible. They are made of still smaller subatomic particles: electrons, protons and neutrons.
T2Why do electrons not fall into the nucleus even though they are attracted to protons in it?▾

In Rutherford's model, an electron moving in a circle keeps changing its direction, so it is accelerating and should lose energy and spiral into the nucleus.

Bohr solved this problem by proposing that electrons move only in fixed circular paths called stationary states (shells or energy levels).

While an electron stays in a fixed shell, its energy remains constant, so it does not lose energy.

An electron changes its shell only by absorbing or releasing a fixed amount of energy. It cannot exist in between two shells.

Answer
Electrons revolve in shells of fixed energy (stationary states) and do not lose energy while they stay in a shell. So they do not spiral into the nucleus.
T3Why did scientists keep modifying atomic models?▾

Each model could explain the experiments known at that time, but new experiments gave results that it could not explain.

Dalton's model (atom is indivisible) could not explain radioactivity and the discovery of the electron, so Thomson proposed his model.

Thomson's model could not explain the gold foil experiment, so Rutherford proposed the nuclear model.

Rutherford's model could not explain the stability of the atom, so Bohr proposed the model with fixed shells.

Even Bohr's model was later found to have limitations, and the quantum mechanical model followed.

Answer
Scientists modified the atomic models because new experimental evidence showed the limitations of the earlier models. Science moves forward one step at a time.
Section B

Pause and Ponder

18 Questions
P1Suppose you made up your own ‘atom’, as Thomson described, using clay for the positive charge and small beads for the electrons spread through it. What will happen if:(i)the positive charge on the clay is lesser than the total negative charge of the beads?(ii)by mistake, the clay itself carries a bit of negative charge? Would your model still represent a neutral atom?▾
(i)Positive charge less than the negative chargeNot neutral

The charge on the model is the sum of the positive charge of the clay and the negative charge of the beads.

Here the positive charge is less than the total negative charge.

So the net charge is negative.

Ans.The model carries a net negative charge, so it is not neutral.
(ii)Clay carrying a bit of negative chargeNot neutral

A bit of negative charge on the clay reduces its positive charge.

Then the total positive charge becomes less than the total negative charge of the beads.

So the net charge is negative again.

Ans.No, the model would not represent a neutral atom.
Answer
A neutral atom needs the total positive charge to be exactly equal to the total negative charge. In both cases this condition fails, so the model is not neutral.
P2Could an orange or a lemon, which also contain seeds inside soft pulp, be a good comparison? In what ways does it match Thomson’s idea and where does it fall short?▾

How it matches:

The soft pulp is spread throughout the fruit, like the positive charge spread throughout Thomson's atom.

The seeds are embedded in the pulp, like the electrons embedded in the positive sphere.

Where it falls short:

The pulp is not electrically charged, and the seeds do not carry any negative charge, so the fruit does not show how the charges balance.

The seeds are big and few, and they are placed in separate segments, whereas the electrons are tiny and spread through the whole atom.

The fruit has a peel and segments, which an atom does not have.

Answer
An orange or a lemon matches the idea of seeds (electrons) embedded in pulp (positive charge), but it does not show the charges or their balance, so it is only a rough model.
P3Why did Thomson conclude that electrons are present in all atoms?▾
−+High voltage power supplyCathode(–)Anode(+)Vacuum pumpwww.boundlessmaths.com
Fig. 8.1 — A line diagram of cathode ray tube

Thomson passed an electric current through gases at very low pressure in a cathode ray tube and observed cathode rays.

He found that the cathode rays are streams of negatively charged particles (electrons).

He also found that the nature of the cathode rays was independent of the material of the cathode and of the gas in the tube.

So the same particles came out from every kind of material, which means that electrons are present in the atoms of all elements.

Answer
The cathode rays were the same whatever the cathode material or the gas used, so Thomson concluded that electrons are a fundamental part of all atoms.
P4What do you think would happen if α-particles were replaced with negatively charged particles in Rutherford’s gold foil experiment?▾

The nucleus of a gold atom is positively charged.

A negatively charged particle is attracted by the positive nucleus, whereas an α-particle is repelled by it.

Most of the atom is empty space, so most of the negatively charged particles would still pass straight through the foil.

The few particles passing close to a nucleus would bend towards the nucleus, instead of being pushed away from it.

Answer
Most particles would still pass straight through, but those passing near a nucleus would be attracted and bent towards it, instead of being repelled as the α-particles were.
P5Rutherford found that a few α-particles bounced back sharply. How does this single surprising result completely rule out Thomson’s ‘plum pudding model’ of the atom?▾

In Thomson's model, the positive charge is spread evenly over the whole atom.

Such a spread-out positive charge can exert only a weak force on a fast α-particle, so the α-particle should pass straight through or bend only slightly.

To bounce an α-particle straight back, a very strong repulsive force is needed. This is possible only if the positive charge and the mass are concentrated in a very small region.

Thomson's model has no such region.

Answer
A few α-particles bouncing back shows that the positive charge is concentrated in a tiny, dense nucleus. Thomson's evenly spread positive sphere cannot explain this, so it is ruled out.
P6If you could ask Rutherford one question about his work, what would it be?▾

Sample question: How did you find that the nucleus is so small compared with the atom?

Answer (in Rutherford's words):

Most of the α-particles passed straight through the gold foil, so most of the atom must be empty space.

Only a very few α-particles were deflected through large angles, so the nucleus that deflects them must occupy only a tiny part of the atom.

From these observations, I calculated the diameter of the nucleus as about 10⁻¹⁵ m and that of the atom as about 10⁻¹⁰ m.

So the nucleus is about 10⁵ times smaller than the atom.

Answer
Any sensible question about his work is acceptable. For the sample question: the nucleus is about 10⁵ (one lakh) times smaller than the atom.
P7Assertion (A): Rutherford concluded that most of the mass of an atom is concentrated in a small region at the centre called the nucleus.
Reason (R): According to Thomson’s model, electrons are embedded in a uniformly distributed positive charge sphere.
Choose the correct option:
▾

Assertion (A): It is true. Rutherford concluded that the nucleus is dense and contains most of the mass of the atom.

Reason (R): It is also a true statement. Thomson's model had electrons embedded in a uniformly distributed positive sphere.

But Thomson's model had no nucleus. So R does not explain how Rutherford reached the conclusion in A.

Rutherford's conclusion came from the gold foil experiment, in which the results did not match Thomson's model.

Answer
Option (ii): Both A and R are true, but R is not the correct explanation of A.
P8Imagine you are a scientist who has discovered a new element. Name this element after yourself and justify that the symbol you have chosen follows the IUPAC rules.▾

Example: Suppose the scientist is a student named Aarav. The new element is named Aaravium and its symbol is Aa.

Checking the IUPAC rules:

1. The symbol is formed from the first letter or the first two letters of the name of the element. Here, it is the first two letters, A and a.

2. The first letter is written as a capital letter and the second letter as a small letter. So the symbol is Aa, not AA or aa.

3. The symbol has only two letters, like Al, Co and Ne.

Answer
Aaravium (Aa) follows the IUPAC rules. You can follow the same steps with your own name, using its first one or two letters, the first as a capital and the second as a small letter.
P9What problems could arise if every scientist used different symbols for the same element?▾

Scientists from different countries would not be able to understand each other's work.

The same element could be mistaken for different elements, and different elements could be mistaken for the same one.

Chemical formulae and equations would be confusing, and mistakes could be made in experiments and in industry.

Language barriers would increase, and the study of chemistry would become difficult.

Answer
There would be confusion and errors in communication. This is why internationally recognised symbols, approved by IUPAC, are used.
P10An atom with an atomic number of 26 has 56 nucleons. Find out its number of electrons, protons and neutrons.▾

Given: atomic number \(Z = 26\), number of nucleons = mass number \(A = 56\)

To find: number of electrons, protons and neutrons

Nucleons are the protons and neutrons in the nucleus, so the mass number \(A = 56\).

Number of protons = atomic number = 26

The atom is neutral, so the number of electrons = number of protons = 26

Mass number = number of protons + number of neutrons

\[\text{number of neutrons} = A - Z = 56 - 26 = 30\]
Answer
The atom has 26 electrons, 26 protons and 30 neutrons (it is iron).
P11The nucleus of an atom contains 20 protons. If its mass number is 41, find the number of neutrons in it.▾

Given: number of protons = 20, mass number \(A = 41\)

To find: number of neutrons

Mass number = number of protons + number of neutrons

\[\text{number of neutrons} = 41 - 20 = 21\]
Answer
The nucleus contains 21 neutrons.
P12An atom has 18 neutrons and an atomic number of 17. What is its mass number?▾

Given: number of neutrons = 18, atomic number \(Z = 17\)

To find: mass number

Atomic number = number of protons = 17

Mass number = number of protons + number of neutrons

\[A = 17 + 18 = 35\]
Answer
The mass number is 35 (it is chlorine, \({}^{35}_{17}\text{Cl}\)).
P13An atom ²³A has 11 electrons. Find the number of neutrons in it.▾

Given: mass number \(A = 23\), number of electrons = 11

To find: number of neutrons

The atom is neutral, so the number of protons = number of electrons = 11.

So the atomic number \(Z = 11\).

\[\text{number of neutrons} = A - Z = 23 - 11 = 12\]
Answer
The atom has 12 neutrons.
P14Identify the number of electrons in the outermost shell of the following elements:(i)\({}^{12}_{6}\text{C}\)(ii)\({}^{19}_{9}\text{F}\)(iii)\({}^{28}_{14}\text{Si}\)▾
(i)Carbon

Atomic number = 6, so the atom has 6 electrons.

The electrons fill the shells in the order K, L, M: K = 2, L = 4.

The electronic configuration is 2, 4.

Ans.4 electrons in the outermost (L) shell
(ii)Fluorine

Atomic number = 9, so the atom has 9 electrons.

K = 2, L = 7.

The electronic configuration is 2, 7.

Ans.7 electrons in the outermost (L) shell
(iii)Silicon

Atomic number = 14, so the atom has 14 electrons.

K = 2, L = 8, M = 4.

The electronic configuration is 2, 8, 4.

Ans.4 electrons in the outermost (M) shell
P15Write the electronic configuration of the elements having atomic numbers 12, 16 and 18.▾

The maximum number of electrons in a shell is \(2n^2\): K = 2, L = 8, M = 18. The outermost shell can hold at most 8 electrons.

The atom is neutral, so the number of electrons = atomic number. The electrons fill K first, then L, then M.

(i)Atomic number 12 (magnesium)

12 electrons: K = 2, L = 8, remaining = 12 − 2 − 8 = 2, so M = 2.

Ans.2, 8, 2
(ii)Atomic number 16 (sulfur)

16 electrons: K = 2, L = 8, remaining = 16 − 2 − 8 = 6, so M = 6.

Ans.2, 8, 6
(iii)Atomic number 18 (argon)

18 electrons: K = 2, L = 8, remaining = 18 − 2 − 8 = 8, so M = 8.

Ans.2, 8, 8
P16Solve this riddle: I am an atom with a mass number of 23 and 11 protons. I am a soft metal and react vigorously with water. Who am I and how many neutrons do I have? You can also create one such riddle.▾

Given: mass number \(A = 23\), number of protons = 11

To find: the element and its number of neutrons

Atomic number = number of protons = 11.

The element with atomic number 11 is sodium (Na). Sodium is a soft metal and it reacts vigorously with water.

\[\text{number of neutrons} = 23 - 11 = 12\]

A riddle of your own: I am an atom with a mass number of 35 and 17 protons. I am a yellow-green gas. Who am I and how many neutrons do I have?

Atomic number = 17, so I am chlorine (Cl). Number of neutrons = 35 − 17 = 18.

Answer
I am sodium (\({}^{23}_{11}\text{Na}\)) and I have 12 neutrons.
P17Two different atoms have 11 protons each, but one has 12 neutrons, and the other has 13 neutrons. How do their atomic numbers and mass numbers compare? Are they the same element or different elements?▾

Atomic number = number of protons = 11 for both atoms, so the atomic numbers are the same.

Mass number of the first atom = 11 + 12 = 23

Mass number of the second atom = 11 + 13 = 24

So the mass numbers are different.

The atomic number decides the identity of an element, so both atoms belong to the same element (sodium). They are isotopes.

Answer
Their atomic numbers are the same (11) and their mass numbers are different (23 and 24). They are atoms of the same element, i.e., isotopes.
P18If a bromine atom is available in the form of, say two isotopes, \({}^{79}_{35}\text{Br}\) (49.7%) and \({}^{81}_{35}\text{Br}\) (50.3%), calculate the average atomic mass of the bromine atom.▾

Given: isotope of mass 79 u: 49.7%; isotope of mass 81 u: 50.3%

To find: average atomic mass

The average atomic mass is the weighted average of the isotopic masses, taking their relative abundances into account.

\[\text{average atomic mass} = \dfrac{79 \times 49.7 + 81 \times 50.3}{100}\] \[= \dfrac{3926.3 + 4074.3}{100}\] \[= \dfrac{8000.6}{100} = 80.006 \approx 80.0\text{ u}\]
Answer
The average atomic mass of bromine is about 80 u (80.0 u).
Section C

Think as a Scientist

1 Question
TAS1Observe Fig. 8.4 of the gold foil experiment. Predict the observations you would expect if the gold foil in the experiment were made thicker. Also, draw a simple diagram to show the observations you expect.
Hint: Compare thin foil vs thick foil. How does the thickness affect the chances of hitting a nucleus?
▾

A thicker foil has more layers of gold atoms, so there are more nuclei in the path of the α-particles.

So the chance that an α-particle passes close to a nucleus, or hits it, increases.

Expected observations with the thicker foil:

1. Fewer α-particles pass straight through without deflection.

2. More α-particles are deflected, and some may be deflected more than once.

3. More α-particles bounce back.

Thin foil www.boundlessmaths.com
Thick foil www.boundlessmaths.com
Blue: passes straight through · Teal: deflected · Red: bounces back. The thick foil has more nuclei in the path, so fewer particles pass straight and more are scattered.
Answer
With a thicker foil, a smaller fraction of α-particles goes straight through, and larger fractions are deflected or bounced back, because the chance of meeting a nucleus is higher.
Section D

What If

1 Question
WI1What if an atom had no empty space? How would this have affected the size of various objects?▾

Rutherford found that the diameter of an atom is about 10⁻¹⁰ m and that of its nucleus is about 10⁻¹⁵ m.

Nearly all the mass of an atom is in the nucleus, and the rest of the atom is mostly empty space.

\[\dfrac{\text{diameter of atom}}{\text{diameter of nucleus}} = \dfrac{10^{-10}}{10^{-15}} = 10^{5}\]

If there were no empty space, each atom would shrink to about the size of its nucleus, i.e., about 10⁵ times smaller in diameter.

So the length of every object would become about 10⁵ times smaller.

For example, a person of height 1.5 m would become about

\[\dfrac{1.5\text{ m}}{10^{5}} = 1.5 \times 10^{-5}\text{ m} = 15\ \mu\text{m}\]

The same mass would be packed in a far smaller volume, so objects would be extremely dense.

Answer
All objects would become about 10⁵ times smaller in size (a person would be only about 15 µm tall), and they would be extremely dense.
Section E

Inline Questions from the Text

6 Questions
IN1Observe Fig. 8.10. How many neutrons and protons are present in a lithium atom, and what is its atomic number?▾

In Fig. 8.10, the nucleus of the lithium atom has 3 protons and 4 neutrons (Table 8.3), and 3 electrons move around it.

The atomic number is the number of protons in the nucleus.

3p 4n Lithium (Li): 2, 1 www.boundlessmaths.com
Lithium atom: 3 protons and 4 neutrons in the nucleus, 3 electrons in the K and L shells
\[Z = 3, \qquad A = 3 + 4 = 7\]
Answer
A lithium atom has 3 protons and 4 neutrons, and its atomic number is 3.
IN2All of these contain one proton each, whereas deuterium contains one neutron, and tritium contains two neutrons. Can you guess how many electrons each of these isotopes have?
(Isotopes of hydrogen: protium \({}^{1}_{1}\text{H}\), deuterium \({}^{2}_{1}\text{H}\) and tritium \({}^{3}_{1}\text{H}\))
▾
ProtiumDeuteriumTritiumwww.boundlessmaths.com
Fig. 8.12 — Schematic representation of isotopes of hydrogen

Each isotope of hydrogen has 1 proton.

Every atom is electrically neutral, so the number of electrons = the number of protons = 1.

IsotopeProtonsNeutronsElectrons
Protium \({}^{1}_{1}\text{H}\)101
Deuterium \({}^{2}_{1}\text{H}\)111
Tritium \({}^{3}_{1}\text{H}\)121
Answer
Each of the three isotopes (protium, deuterium and tritium) has 1 electron.
IN3In NH₃ (ammonia) and MgCl₂ (magnesium chloride), what will be the combining capacities of nitrogen and magnesium respectively?▾

The combining capacity of an element is the number of hydrogen or chlorine atoms with which one atom of the element combines.

(i)Nitrogen in NH₃

One nitrogen atom combines with 3 hydrogen atoms.

Ans.Combining capacity of nitrogen = 3
(ii)Magnesium in MgCl₂

One magnesium atom combines with 2 chlorine atoms.

Ans.Combining capacity of magnesium = 2
IN4Can you predict what happens to the atoms that already have eight electrons in their outermost shell (except the elements with one shell only, where only two electrons are possible)? Will they still try to lose or gain electrons?▾

Eight electrons in the outermost shell make a complete octet (two electrons in the case of helium).

An atom with a complete octet is stable and largely unreactive.

Such atoms have no need to lose, gain or share electrons.

For example, neon (2, 8) and argon (2, 8, 8) have complete octets. Their valency is zero.

Answer
No. Atoms with eight electrons in the outermost shell are already stable, so they do not try to lose or gain electrons. They are largely unreactive.
IN5Examine Table 8.4. Add one more column to it, and write down the common valency of each element.▾

Valency is the number of electrons gained, lost or shared to complete the octet.

If the valence electrons are fewer than 4, the atom loses them, so valency = number of valence electrons.

If the valence electrons are more than 4, the atom gains electrons, so valency = 8 − number of valence electrons.

If the shell is already complete (2 for helium or 8), the valency is 0. Carbon (4 valence electrons) shares 4 electrons, so its valency is 4.

ElementConfigurationValence e⁻Valency
Hydrogen (H)111
Helium (He)220
Lithium (Li)2, 111
Beryllium (Be)2, 222
Boron (B)2, 333
Carbon (C)2, 444
Nitrogen (N)2, 558 − 5 = 3
Oxygen (O)2, 668 − 6 = 2
Fluorine (F)2, 778 − 7 = 1
Neon (Ne)2, 880
Sodium (Na)2, 8, 111
Magnesium (Mg)2, 8, 222
Aluminium (Al)2, 8, 333
Silicon (Si)2, 8, 444
Phosphorus (P)2, 8, 558 − 5 = 3
Sulfur (S)2, 8, 668 − 6 = 2
Chlorine (Cl)2, 8, 778 − 7 = 1
Argon (Ar)2, 8, 880
Answer
The common valencies are: H 1, He 0, Li 1, Be 2, B 3, C 4, N 3, O 2, F 1, Ne 0, Na 1, Mg 2, Al 3, Si 4, P 3, S 2, Cl 1, Ar 0.
IN6Helium contains two protons in its nucleus and two electrons. In which way will the two electrons be arranged in its atomic shell?▾

The K shell (n = 1) can hold a maximum of \(2 \times 1^2 = 2\) electrons.

Electrons fill the shell closest to the nucleus first.

So both electrons of helium go into the K shell.

The K shell is then complete (a duplet), so helium is stable and unreactive.

2p 2n Helium (He): 2 www.boundlessmaths.com
Helium atom: 2 protons and 2 neutrons in the nucleus, both electrons in the K shell
Answer
Both electrons of helium are in the K shell. Its electronic configuration is 2.
Section F

Ready to Go Beyond

1 Question
RTG1Can you calculate how many atoms would be needed to make a sheet of paper that is 0.1 mm thick, like the one in your textbook?▾

Given: thickness of the sheet = 0.1 mm \(= 10^{-4}\) m; diameter of one atom \(\approx 10^{-10}\) m

To find: the number of atoms stacked one over the other to make the thickness

0.1 mm = 0.1 × 10⁻³ m = 10⁻⁴ m

Number of atoms = thickness of the sheet ÷ diameter of one atom

\[\text{number of atoms} \approx \dfrac{10^{-4}\text{ m}}{10^{-10}\text{ m}} = 10^{6}\]
Answer
About 10⁶ atoms (one million atoms) must be stacked one above the other to make a sheet 0.1 mm thick.
Section G

Revise, Reflect, Refine (Back Exercise)

15 Questions
Q1Choose the correct options and explain the reason for the correct and incorrect options in the context of Ernest Rutherford’s gold foil experiment:(i)The experiment clearly showed the existence of neutrons in the nucleus.(ii)The results disproved the plum pudding model and led to the idea of a nucleus at the centre of the atom.(iii)The large deflection of a few alpha particles indicated that most of the mass of the atom and positive charge are packed into a tiny centre.(iv)The way alpha particles were deflected showed that electrons move around the nucleus.▾
(i)Neutrons in the nucleusIncorrect

The experiment was done in 1911, and neutrons were discovered by Chadwick in 1932.

The scattering of α-particles gave no information about neutrons.

Ans.Incorrect
(ii)Plum pudding model disprovedCorrect

In the plum pudding model the positive charge is spread evenly, so all α-particles should have passed with little deflection.

A few α-particles were sharply deflected, which this model could not explain.

This led Rutherford to the idea of a small, dense nucleus at the centre.

Ans.Correct
(iii)Mass and positive charge in a tiny centreCorrect

Large deflections and bounce-backs of the positive α-particles need a strong repulsion from a heavy, positively charged centre.

Most α-particles went straight, so this centre must be very small.

Ans.Correct
(iv)Electrons move around the nucleusIncorrect

Electrons are very light and cannot deflect heavy α-particles noticeably.

The deflections came from the nucleus, so the experiment did not show how electrons move.

The planetary picture was Rutherford's proposal, not a result of the scattering.

Ans.Incorrect
Answer
Options (ii) and (iii) are correct. Options (i) and (iv) are incorrect.
Q2Which of the following statements are correct or incorrect according to the Bohr’s atomic model? Give a reason for each statement.(i)Electrons lose energy while moving in fixed orbits and slowly fall into the nucleus.(ii)Electrons can exist anywhere around the nucleus with no fixed energy.(iii)Electrons revolve around the nucleus in orbits of fixed energy without losing energy.(iv)Electrons can be found between energy levels as they move around the nucleus.▾
(i)Electrons lose energy and fall into the nucleusIncorrect

According to Bohr, an electron in a fixed orbit (stationary state) has constant energy and does not lose energy.

So it does not fall into the nucleus.

Ans.Incorrect
(ii)Electrons can exist anywhere with no fixed energyIncorrect

Electrons revolve only in certain allowed shells.

Each shell has a definite energy.

Ans.Incorrect
(iii)Electrons revolve in orbits of fixed energy without losing energyCorrect

This is Bohr's postulate of stationary states. The energy of an electron stays constant while it is in a shell.

Ans.Correct
(iv)Electrons can be found between energy levelsIncorrect

Electrons can revolve only in the allowed shells and not in between them.

An electron moves from one shell to another by absorbing or releasing a fixed amount of energy.

Ans.Incorrect
Answer
Only statement (iii) is correct. Statements (i), (ii) and (iv) are incorrect.
Q3The composition of the nuclei of three atomic species X, Y, and Z are given as follows.
XYZ
Number of protons181717
Number of neutrons191820
Explain the relation between the following:(i)Y and Z(ii)Z and X
▾

Atomic number = number of protons, and mass number = number of protons + number of neutrons.

XYZ
Atomic number (Z)181717
Mass number (A)18 + 19 = 3717 + 18 = 3517 + 20 = 37
(i)Y and Z

Y and Z have the same atomic number (17) but different mass numbers (35 and 37).

They are atoms of the same element (chlorine) with different numbers of neutrons.

Ans.Y and Z are isotopes.
(ii)Z and X

Z and X have different atomic numbers (17 and 18) but the same mass number (37).

They are atoms of different elements (chlorine and argon).

Ans.Z and X are isobars.
Q4What conclusion did Rutherford draw about the position and characteristics of the atom’s positively charged part based on the few alpha particles that bounced back or were deflected at large angles in the gold foil experiment?▾

Only a very few α-particles were deflected through large angles or bounced back, while most passed straight through.

A strong repulsion on a positive α-particle can come only from a heavy, concentrated, positive charge.

Conclusions of Rutherford:

1. Position: the positive charge is not spread throughout the atom. It is concentrated at the centre of the atom, in a region called the nucleus.

2. Size: the nucleus is extremely small, about 10⁵ times smaller than the atom.

3. Mass and charge: the nucleus is dense and contains all the positive charge and most of the mass of the atom.

Answer
The positive charge of the atom is concentrated in a tiny, dense central region, the nucleus, which contains most of the mass of the atom.
Q5Explain and arrange the following statements in the correct chronological order to show how atomic models have evolved over time.(i)Bohr’s model proposed that electrons move in fixed orbits around the nucleus, each with a definite energy.(ii)Thomson’s model depicted the atom as a ‘plum pudding’ with electrons embedded in a sphere of positive charge.(iii)Rutherford’s model proposed that atoms have a dense central nucleus.(iv)Dalton’s model described atoms as indivisible particles.▾
1st(iv) Dalton's model (1808)

Atoms are indivisible particles, the building blocks of matter.

Ans.Dalton
2nd(ii) Thomson's model

After the discovery of the electron in 1897, the atom was pictured as a ‘plum pudding’: electrons embedded in a sphere of positive charge.

Ans.Thomson
3rd(iii) Rutherford's model (1911)

The gold foil experiment led to the nuclear model, with a dense central nucleus.

Ans.Rutherford
4th(i) Bohr's model (1913)

Bohr explained the stability of the atom with electrons moving in fixed orbits of definite energy.

Ans.Bohr
Answer
The correct chronological order is (iv), (ii), (iii), (i).
Q6Electrons move around the nucleus in orbits. Why do they not fly away from the atom? Explain what keeps them attracted to the nucleus.▾

The nucleus contains protons and is positively charged. Electrons are negatively charged.

Unlike charges attract each other, so there is a force of electrical attraction between the nucleus and every electron.

This attractive force acts towards the nucleus. It keeps the electron moving in its circular path, in the same way as the Sun's attraction keeps the planets in their orbits.

So the electrons cannot fly away.

Answer
The electrostatic force of attraction between the negatively charged electrons and the positively charged nucleus keeps the electrons in their orbits.
Q7Assertion (A): The discovery of subatomic particles helped in understanding the atomic structure.
Reason (R): The number of electrons is equal to the number of protons in an atom.
Choose the correct option:
▾

Assertion (A): It is true. The discovery of the electron, the proton and the neutron helped scientists to build models of the atom.

Reason (R): It is also true. A neutral atom has equal numbers of electrons and protons.

But this fact only tells us why the atom is neutral. It does not explain why the discovery of the subatomic particles helped in understanding the structure.

Answer
Option (ii): Both A and R are true, but R is not the correct explanation of A.
Q8Magnesium is essential for many biological processes, including muscle contraction. For an atom of magnesium with a mass number of 24 and atomic number of 12, determine the number of(i)protons,(ii)neutrons,(iii)electrons,and also illustrate the arrangement of electrons in a magnesium atom.▾

Given: mass number \(A = 24\), atomic number \(Z = 12\)

(i)Protons

Number of protons = atomic number = 12

Ans.12 protons
(ii)Neutrons

Number of neutrons = mass number − atomic number

\[24 - 12 = 12\]
Ans.12 neutrons
(iii)Electrons

The atom is neutral, so the number of electrons = number of protons = 12

Ans.12 electrons

Arrangement of electrons:

K shell: 2 electrons, L shell: 8 electrons, M shell: 12 − 2 − 8 = 2 electrons.

12p 12n Magnesium (Mg): 2, 8, 2 www.boundlessmaths.com
Magnesium atom: 12 protons and 12 neutrons in the nucleus; K = 2, L = 8, M = 2
Answer
Magnesium has 12 protons, 12 neutrons and 12 electrons. Its electronic configuration is 2, 8, 2.
Q9Find the following information for the elements shown in Fig. 8.17:(i)Name of the element(ii)Symbol(iii)Total number of electrons(iv)Number of valence electrons(v)Valency of the element(vi)Number of protons(vii)Atomic number▾

Counting the electrons in each shell of Fig. 8.17:

The atom is neutral, so the number of protons = the number of electrons = the atomic number.

3+ (a) 2, 1 www.boundlessmaths.com
7+ (b) 2, 5 www.boundlessmaths.com
13+ (c) 2, 8, 3 www.boundlessmaths.com
9+ (d) 2, 7 www.boundlessmaths.com
Fig. 8.17 (redrawn): the number of electrons in each shell is counted from the figure
AtomK shellL shellM shellTotal electrons
(a)21–3
(b)25–7
(c)28313
(d)27–9
(i)Name of the element

The atomic number gives the element (Table 8.4): 3 is lithium, 7 is nitrogen, 13 is aluminium and 9 is fluorine.

Ans.(a) Lithium, (b) Nitrogen, (c) Aluminium, (d) Fluorine
(ii)Symbol

From Table 8.4:

Ans.(a) Li, (b) N, (c) Al, (d) F
(iii)Total number of electrons

Adding the electrons of all the shells:

(a) 2 + 1 = 3, (b) 2 + 5 = 7, (c) 2 + 8 + 3 = 13, (d) 2 + 7 = 9

Ans.(a) 3, (b) 7, (c) 13, (d) 9
(iv)Number of valence electrons

The valence electrons are the electrons in the outermost shell:

Ans.(a) 1, (b) 5, (c) 3, (d) 7
(v)Valency of the element

(a) 1 valence electron: loses 1 electron, valency 1

(b) 5 valence electrons: gains 8 − 5 = 3 electrons, valency 3

(c) 3 valence electrons: loses 3 electrons, valency 3

(d) 7 valence electrons: gains 8 − 7 = 1 electron, valency 1

Ans.(a) 1, (b) 3, (c) 3, (d) 1
(vi)Number of protons

Number of protons = number of electrons

Ans.(a) 3, (b) 7, (c) 13, (d) 9
(vii)Atomic number

Atomic number = number of protons

Ans.(a) 3, (b) 7, (c) 13, (d) 9
Q10Both Rutherford’s and Bohr’s models have electrons orbiting the nucleus. Why did Rutherford’s model fail to explain atomic stability, while Bohr’s model succeeded?▾

Rutherford's model:

An electron moving in a circular path keeps changing its direction, so it is accelerating.

An accelerating charged particle should lose energy continuously, so the electron should spiral inwards and fall into the nucleus.

Then atoms would collapse, but in reality atoms are stable. So the model failed to explain the stability of the atom.

Bohr's model:

Bohr proposed that electrons revolve only in certain fixed circular paths called stationary states (shells), each with a definite energy.

While an electron stays in a shell, its energy remains constant, so it does not lose energy and does not fall into the nucleus.

Answer
Rutherford's model predicted that orbiting electrons would lose energy and collapse into the nucleus. Bohr's model introduced stationary states, in which electrons do not lose energy, so atoms are stable.
Q11An atom 70X has 31 electrons. How many neutrons are there in its nucleus?▾

Given: mass number \(A = 70\), number of electrons = 31

To find: number of neutrons

The atom is neutral, so the number of protons = number of electrons = 31.

So the atomic number \(Z = 31\).

\[\text{number of neutrons} = A - Z = 70 - 31 = 39\]
Answer
The nucleus has 39 neutrons.
Q12An atom has 79 protons and a mass number of 197. Calculate(i)the number of neutrons, and(ii)the number of electrons.▾

Given: number of protons = 79, mass number \(A = 197\)

(i)Number of neutrons

Number of neutrons = mass number − number of protons

\[197 - 79 = 118\]
Ans.118 neutrons
(ii)Number of electrons

The atom is neutral, so the number of electrons = number of protons.

Ans.79 electrons
Q13Complete the Table 8.5:
Atomic numberMass numberNumber of neutronsNumber of protonsNumber of electronsName of the element
5–6–––
–14––7Nitrogen
–24–12––
15–16–––
–10–––
▾

Use: number of protons = atomic number = number of electrons, and mass number = protons + neutrons.

Row 1: \(Z = 5\), so protons = electrons = 5. Mass number = 5 + 6 = 11. The element with \(Z = 5\) is boron.

Row 2: electrons = 7, so protons = \(Z\) = 7. Neutrons = 14 − 7 = 7. The element is nitrogen.

Row 3: protons = 12, so \(Z = 12\) and electrons = 12. Neutrons = 24 − 12 = 12. The element with \(Z = 12\) is magnesium.

Row 4: \(Z = 15\), so protons = electrons = 15. Mass number = 15 + 16 = 31. The element with \(Z = 15\) is phosphorus.

Row 5: mass number 1 with 0 neutrons means protons = 1 − 0 = 1. So \(Z = 1\) and electrons = 1. The element is hydrogen.

Atomic numberMass numberNumber of neutronsNumber of protonsNumber of electronsName of the element
511655Boron
714777Nitrogen
1224121212Magnesium
1531161515Phosphorus
11011Hydrogen
Answer
Table 8.5 is completed as shown above.
Q14Aman was discussing the structure of atom with his classmates. During the discussion, he learnt that an element X has a mass number of 35 and contains 18 neutrons. Based on this information, answer the following questions:▾

Given: mass number \(A = 35\), number of neutrons = 18

Number of protons = mass number − number of neutrons = 35 − 18 = 17

(i)Number of electrons and protons

Number of protons = 35 − 18 = 17.

The atom is neutral, so the number of electrons = number of protons = 17.

Ans.17 protons and 17 electrons
(ii)Atomic number

Atomic number = number of protons

Ans.17
(iii)Identify the element X

The element with atomic number 17 is chlorine.

Ans.Chlorine (Cl)
(iv)Electronic configuration

17 electrons: K = 2, L = 8, M = 17 − 2 − 8 = 7.

Ans.2, 8, 7
(v)Valence electrons

The outermost (M) shell has 7 electrons.

Ans.7 valence electrons
(vi)Mass number if two neutrons are added

New number of neutrons = 18 + 2 = 20.

New mass number = 17 + 20 = 37.

Ans.37
(vii)Relation of X with the new atom

Both atoms have the same atomic number (17) but different mass numbers (35 and 37).

Ans.They are isotopes of chlorine
Q15In an atom, there are 12 protons and 12 neutrons in the nucleus. Now, imagine that all the electrons are replaced with some hypothetical particles that have the same charge as electrons but are 500 times heavier. What effect will this replacement have on the atom’s:(i)Atomic number(ii)Atomic mass(iii)Mass number(iv)Overall charge▾

Given: 12 protons, 12 neutrons; each electron is replaced by a particle of the same charge but 500 times heavier

(i)Atomic numberNo change

The atomic number is the number of protons in the nucleus.

The protons are not changed.

Ans.No change (it remains 12)
(ii)Atomic massIncreases

The mass of an electron is about \(\dfrac{1}{1840}\) u, which is negligible.

Each new particle has a mass of about \(500 \times \dfrac{1}{1840} \approx 0.27\) u.

\[12 \times 0.27 \approx 3.3\text{ u}\]

Atomic mass before ≈ 12 + 12 = 24 u, and after ≈ 24 + 3.3 ≈ 27.3 u.

Ans.It increases (from about 24 u to about 27 u)
(iii)Mass numberNo change

The mass number = number of protons + number of neutrons = 12 + 12 = 24.

Electrons are not counted in the mass number.

Ans.No change (it remains 24)
(iv)Overall chargeNo change

The new particles have the same charge as electrons, and their number is the same (12).

So the negative charge still balances the positive charge of 12 protons.

Ans.No change (the atom remains neutral)
Section H

The Journey Beyond and The Quest Continues

2 Questions
JB1Draw a bar graph showing the number of electrons in each energy level for any three elements.▾

Choose three elements: carbon (Z = 6), sodium (Z = 11) and chlorine (Z = 17).

Write the electronic configuration of each element:

ElementK shellL shellM shell
Carbon (C)240
Sodium (Na)281
Chlorine (Cl)287

Take the energy levels (K, L, M) on the x-axis and the number of electrons on the y-axis.

Scale: 1 division = 1 electron on the y-axis.

For each shell, draw one bar for each element, with the height equal to the number of electrons.

2 4 6 8 0 K shell 2 2 2 L shell 4 8 8 M shell 0 1 7 Energy level (shell) Number of electrons Carbon (C) Sodium (Na) Chlorine (Cl) www.boundlessmaths.com
Bar graph of the number of electrons in the K, L and M shells of carbon (2, 4), sodium (2, 8, 1) and chlorine (2, 8, 7)
Answer
The bar graph above shows the number of electrons in the K, L and M shells of carbon, sodium and chlorine.
QC1Is it possible to completely understand everything that happens inside an atom?▾

Our understanding of the atom has changed again and again: from Dalton's indivisible atom to the models of Thomson, Rutherford and Bohr.

Even Bohr's model was later found to be not entirely correct. Electrons do not follow well-defined paths like fixed Bohr orbits.

Today, we understand that electrons exist as ‘electron clouds’ around the nucleus. We can predict the regions where they are most likely to be, but not exactly where they are.

This quantum mechanical model will be learnt in higher grades, and the exploration of the atom is still going on.

Answer
Not completely, at least not yet. We can only predict the regions where electrons are most likely to be found, and new discoveries about the atom are still being made.
💡 Chapter 8's core idea, in one line

Each atomic model — Dalton's indivisible sphere, Thomson's plum pudding, Rutherford's tiny nucleus, Bohr's fixed energy shells — was built to explain what the previous model could not, and the atom's true structure of protons, neutrons and electrons, arranged as atomic number, mass number, isotopes and isobars, is the product of that century-long chain of revision.

Extra Practice

The Practice Continues

7 Questions

Seven extra questions in the style of the textbook's own activities and examples, for independent practice once you've gone through everything above. Attempt each one on paper first, then tap to check.

EP1An atom has atomic number 13 and mass number 27. Find(i)the number of protons, neutrons and electrons in it,(ii)its electronic configuration, and(iii)its valency.▾

Given: atomic number \(Z = 13\), mass number \(A = 27\)

(i)Protons, neutrons and electrons

Number of protons = atomic number = 13.

The atom is neutral, so the number of electrons = 13.

Number of neutrons = mass number − atomic number = 27 − 13 = 14.

Ans.13 protons, 14 neutrons and 13 electrons
(ii)Electronic configuration

K = 2, L = 8, M = 13 − 2 − 8 = 3.

Ans.2, 8, 3
(iii)Valency

The outermost shell has 3 electrons, which is fewer than 4, so the atom loses 3 electrons to get an octet.

Ans.3 (the element is aluminium)
EP2Two atoms X and Y both have atomic number 17. X has mass number 35 and Y has mass number 37.(i)What is the relation between X and Y?(ii)How many neutrons does each have?(iii)Will their chemical properties be the same? Give a reason.▾
(i)Relation between X and Y

They have the same atomic number (17) and different mass numbers (35 and 37).

Ans.X and Y are isotopes
(ii)Number of neutrons

Neutrons in X = 35 − 17 = 18.

Neutrons in Y = 37 − 17 = 20.

Ans.X has 18 neutrons and Y has 20 neutrons
(iii)Chemical propertiesSame

Chemical properties depend mainly on the number of valence electrons.

Both have 17 electrons with the same configuration 2, 8, 7.

Ans.Yes, they are the same
EP3Atom P has atomic number 20 and mass number 40. Atom Q has atomic number 18 and mass number 40.(i)What is the relation between P and Q?(ii)Find the number of neutrons in each.▾
(i)Relation between P and Q

They have different atomic numbers (20 and 18) and the same mass number (40).

Ans.P and Q are isobars
(ii)Number of neutrons

Neutrons in P = 40 − 20 = 20.

Neutrons in Q = 40 − 18 = 22.

Ans.P has 20 neutrons and Q has 22 neutrons
EP4Silicon occurs in nature as two isotopes: silicon-28 (92%) and silicon-30 (8%). Find the average atomic mass of silicon.▾

Given: isotope of mass 28 u: 92%; isotope of mass 30 u: 8%

To find: average atomic mass of silicon

\[\text{average atomic mass} = \dfrac{28 \times 92 + 30 \times 8}{100}\] \[= \dfrac{2576 + 240}{100}\] \[= 28.16\text{ u}\]
Answer
The average atomic mass of silicon is 28.16 u. It is very close to 28 u because most of the atoms are silicon-28.
EP5Using the electronic configurations of magnesium (Z = 12) and chlorine (Z = 17), explain why one atom of magnesium combines with two atoms of chlorine in MgCl₂.▾

Electronic configuration of magnesium = 2, 8, 2. It has 2 valence electrons, which is fewer than 4, so it loses 2 electrons to get an octet. Its valency is 2.

Electronic configuration of chlorine = 2, 8, 7. It has 7 valence electrons, so it needs 1 more electron to complete its octet. Its valency is 1.

One magnesium atom has 2 electrons to give, and one chlorine atom can take only 1 electron.

So 2 chlorine atoms are needed to take the 2 electrons given by one magnesium atom.

\[1\,\text{Mg} + 2\,\text{Cl} \rightarrow \text{MgCl}_2\]
Answer
Magnesium has a valency of 2 and chlorine has a valency of 1, so one magnesium atom combines with two chlorine atoms to form MgCl₂.
EP6A sample of an element consists of only two isotopes, of mass numbers 63 and 65. Its average atomic mass is 63.5 u. Find the percentage abundance of each isotope.▾

Given: isotopes of mass 63 u and 65 u; average atomic mass = 63.5 u

To find: percentage abundance of each isotope

Let the abundance of the isotope of mass 63 be \(x\)%. Then the abundance of the isotope of mass 65 is \((100 - x)\)%.

Average atomic mass = weighted average of the isotopic masses:

\[63 \times \dfrac{x}{100} + 65 \times \dfrac{100 - x}{100} = 63.5\] \[63x + 6500 - 65x = 6350\] \[6500 - 2x = 6350\] \[x = 75\]

So the abundance of the isotope of mass 65 = 100 − 75 = 25%.

Check: 63 × 0.75 + 65 × 0.25 = 47.25 + 16.25 = 63.5 u

Answer
The isotope of mass 63 is 75% and the isotope of mass 65 is 25%.
EP7A neutral atom has three shells. Its K and L shells are full and its M shell contains \(x\) electrons. It has 16 neutrons and a mass number of 31. Find(i)its atomic number,(ii)the value of \(x\),(iii)its valency, and(iv)the name of the element.▾

Given: mass number \(A = 31\), number of neutrons = 16; K shell = 2, L shell = 8

(i)Atomic number

Number of protons = mass number − number of neutrons = 31 − 16 = 15.

Atomic number = number of protons = 15.

Ans.15
(ii)Value of x

The atom is neutral, so the number of electrons = 15.

2 + 8 + \(x\) = 15, so \(x = 5\).

Ans.x = 5 (configuration 2, 8, 5)
(iii)Valency

The outermost shell has 5 electrons, so the atom gains 8 − 5 = 3 electrons to complete its octet.

Ans.3
(iv)Name of the element

The element with atomic number 15 is phosphorus (P).

Ans.Phosphorus
Common Questions

Frequently Asked Questions

An atom is electrically neutral because it contains equal numbers of protons (positive charge) and electrons (negative charge), while neutrons carry no charge at all. The positive charge of the protons in the nucleus exactly balances the negative charge of the surrounding electrons, so the atom as a whole has zero net charge, even though it's built entirely from charged (and one neutral) particles.
Atomic number (Z) is simply the number of protons in an atom's nucleus, and it defines which element the atom is. Mass number (A) is the total number of protons and neutrons combined. Since the number of neutrons can vary between atoms of the same element (giving isotopes), two atoms can share the same atomic number but have different mass numbers.
Chemical properties are determined almost entirely by the number and arrangement of electrons around an atom, especially the outermost (valence) electrons — and isotopes of the same element have identical electron configurations, since they share the same atomic number. The extra neutrons in a heavier isotope add mass but don't change how the atom bonds or reacts, so isotopes behave chemically the same, even though their physical properties like mass and density can differ.
This was Rutherford's key discovery from the gold foil experiment: most alpha particles passed straight through the gold foil undeflected, showing that atoms are mostly empty space, while a small number bounced back sharply, revealing that all of the atom's positive charge and almost all of its mass is concentrated in an extremely tiny, dense central nucleus. The electrons occupy a comparatively vast region of space around this nucleus, which is why atoms — despite feeling solid — are overwhelmingly empty at the subatomic scale.
Each atomic model — Dalton's, Thomson's, Rutherford's, and Bohr's — was revised because new experimental evidence revealed results the older model could not explain, such as the discovery of electrons, the gold foil scattering experiment, and the question of why atoms are stable. This step-by-step revision in light of new evidence is a hallmark of how science progresses.
Fill the shells in order K, L, M, N with the maximum 2n² electrons, but remember that for the first 20 elements the outermost shell never holds more than 8. So potassium (atomic number 19) is 2, 8, 8, 1 and not 2, 8, 9, and calcium (20) is 2, 8, 8, 2. Count the total to check that it equals the atomic number.
Keep Going

Continue to Chapter 9

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